Habitat type-based bioaccumulation and risk assessment of metal and As contamination in earthworms, beetles and woodlice

The present study investigated the contribution of environmental factors to the accumulation of As, Cd, Cu, Pb and Zn in earthworms, beetles and woodlice, and framed within an exposure assessment of the European hedgehog. Soil and invertebrate samples were collected in three distinct habitat types. Results showed habitat-specific differences in soil and invertebrate metal concentrations and bioaccumulation factors when normalized to soil metal concentration. Further multiple regression analysis showed residual variability (habitat differences) in bioaccumulation that could not be fully explained by differences in soil metal contamination, pH or organic carbon (OC). Therefore, the study demonstrated that in bioaccumulation studies involving terrestrial invertebrates or in risk assessment of metals, it is not sufficient to differentiate habitat types on general soil characteristics such as pH and/or OC alone. Furthermore, simple generic soil risk assessments for Cd and Cu showed that risk characterization was more accurate when performed in a habitat-specific way.     

Longevity of rodenticide bait pellets in a tropical environment following a rat eradication program

Invasive rodents (primarily Rattus spp.) are responsible for loss of biodiversity in island ecosystems worldwide. Large-scale rodenticide applications are typically used to eradicate rats and restore ecological communities. In tropical ecosystems, environmental conditions rapidly degrade baits and competition for baits by non-target animals can result in eradication failure. Our objective was to evaluate persistence of rodenticide baits during a rat eradication program on Palmyra Atoll; a remote tropical atoll with intense competition for resources by land crabs. Following aerial application, bait condition was monitored in four terrestrial environments and in the canopy foliage of coconut palms. Ten circular PVC hoops were fixed in place in each of Palmyra’s four primary terrestrial habitats and five rodenticide pellets were placed in each hoop. Five coconut palms were selected in three distinct regions of the atoll. One rodenticide pellet was placed on each of five palm fronds in each coconut palm. Fresh baits were placed in all monitoring locations after each broadcast bait application. Bait condition and survival was monitored for 7 days after the first bait application and 6 days after second application. Bait survival curves differed between applications at most monitoring sites, suggesting a decrease in overall rat activity as a result of rodenticide treatment. One terrestrial site showed near 100 % bait survival after both applications, likely due to low localized rat and crab densities. Median days to pellet disappearance were one and two days for the first and second application, respectively. Differences in survival curves were not detected in canopy sites between bait applications. Median days to pellet disappearance in canopy sites were 2 and 4 days for the first and second application, respectively. Frequent rainfall likely contributed to rapid degradation of bait pellets in coconut palm fronds.     

Predicting Pressure Loss for Pulse Jet Filters

The analysis of pressure loss characteristics for pulse jet filters suggests that the relationship between dust adhesion to the fabric and the opposing force generated by pulse jet action plays a major role in dust removal. Hence, fabric cleanability is examined in terms of the adhesion-cohesion forces bonding the dust to the fabric vs. the intensity and frequency of the dust dislodgement forces produced by the high energy air pulses. The effect of jet size and location, jet air volume, and the intensity (pressure) and duration of the jet pulses is related to operating pressure loss.

The mechanics of energy transfer from the jet pulse to the dustladen fabric are explored in terms of jet pressure, solenoid valve action, the ratio of delivered pulse air volume to bag (tube) volume, and the elastic and flex properties of the felt bags. Effective and actual fabric dust holdings before and after cleaning are discussed with respect to steady-state dust deposition and removal rates, and operating pressure losses. Finally, predictive equations are proposed for estimating pressure loss over a broad range of design and operating parameters.     

Fluoride Emissions and Forest Growth

Abstract

The October 1995 court decision allowing Ethyl Corporation to offer methylcyclopentadienyl manganese tricarbonyl (MMT) for sale to refiners for introduction into unleaded gasoline as an octane enhancer is likely to result in increased fine (PM_2.5) manganese (Mn) concentrations in ambient air. Concern exists regarding possible health effects. In this paper, recent fine Mn concentrations in three monitoring networks and one U.S. Environmental Protection Agency (EPA) study of personal exposure are analyzed. One network consists mainly of rural sites in national parks in the United States, a second consists mainly of urban sites in California, and the third consists mainly of urban sites in Canada where MMT has been used for a number of years. During the late 1980s and early 1990s, mean ambient concentrations ranged from 1 ng/m³ in the mostly rural network to 3 ng/m³ in the mostly urban California network to 12 ng/m³ in the MMT-impacted Canadian network. Several lines of evidence suggested that some of the fine Mn observed in the United States during the 1986-1992 period was contributed by automobiles using leaded gasoline, for which MMT was a registered fuel additive. However, the near-disappearance of leaded gasoline has resulted in a very small portion of fine Mn being attributed to automobiles in the years since 1992.A source apportionment analysis suggested that crustal contributions to ambient fine Mn are on the order of 1-2 ng/m³ in both the United States and Canada.     

Variations in some environmental characteristics including C and N stable isotopic composition of suspended organic matter in the Mandovi estuary

Chemical and isotopic (??¹³C and ??¹⁵N) investigation of the Mandovi estuary along the Indian west coast affected strongly by the seasonal monsoon cycle was carried out. The Mandovi estuary is a major waterway for Goa and extensively used for transportation of iron and manganese ore. In addition, with large population centers as well as agricultural fields located on its shores, the estuary is assumed to have been influenced by human activities. Measurements of chemical and isotopic parameters made in the lower part of the estuary during the southwest (SW) monsoon and post-monsoon seasons reveal distinct changes, and it is observed that despite considerable enrichment of macronutrients during the SW monsoon, productivity of the estuary (phytoplankton biomass), as inferred from the chlorophyll-a content, is not as high as expected. This is due to occurrences of high turbidity and cloud cover that limits photosynthetic productivity. The isotopic characterization (C and N isotopes) of suspended organic matter produced/transported during the monsoon and post-monsoon seasons of year 2007 provides a baseline dataset for future isotopic studies in such type of tropical estuaries.     

Effect of interior door position on room-to-room differences in residential pollutant concentrations after short-term releases

Residential interior door positions influence the pollutant concentrations that result from short-term indoor sources, such as cigarettes, candles, and incense. To elucidate this influence, we reviewed past studies and conducted new experiments in three residences: a single-story 714 m³ ranch-style house, a 510 m³ two-story split-level house, and a 200 m³ two-story house. During the experiments, we released sulfur hexafluoride or carbon monoxide tracer gas over short periods (≤30 min) and measured concentrations in the source room and at least one other (receptor) room for various interior door opening positions. We found that closing a door between rooms effectively prevented transport of air pollutants, reducing the average concentration in the receptor room relative to the source room by 57–100% over exposure periods of 1–8 h. When intervening doors were partially or fully open, the reduction in average concentrations ranged from 3% to 99%, varying as a function of door opening width and the distance between source and receptor rooms.     

The meaning and ethics of sustainability

Some have argued that the meaning of sustainability varies according to context, forcing us to be as explicit as possible when defining our terms. An argument is offered that disputes this conclusion by maintaining that it is not the meaning of sustainability that changes with respect to context, but rather our understanding of the context itself. This is frequently apparent in contradictions that arise when conceiving each context in terms of sustainability. If this argument is correct, then we should be concerned not with the “meaning” of sustainability but rather the implications of sustainability as they affect the status quo. And in order to do this we must be prepared to answer the question: Why is sustainability desirable? This approach is illustrated through a preliminary conceptual and ethical analysis of ecologically sustainable development.