Changes in mineralogical and leaching properties of converter steel slag resulting from accelerated carbonation at low CO2 pressure

Steel slag can be applied as substitute for natural aggregates in construction applications. The material imposes a high pH (typically 12.5) and low redox potential (Eh), which may lead to environmental problems in specific application scenarios. The aim of this study is to investigate the potential of accelerated steel slag carbonation, at relatively low pCO₂ pressure (0.2 bar), to improve the environmental pH and the leaching properties of steel slag, with specific focus on the leaching of vanadium. Carbonation experiments are performed in laboratory columns with steel slag under water-saturated and -unsaturated conditions and temperatures between 5 and 90 °C. Two types of steel slag are tested; free lime containing (K3) slag and K1 slag with a very low free lime content. The fresh and carbonated slag samples are investigated using a combination of leaching experiments, geochemical modelling of leaching mechanisms and microscopic/mineralogical analysis, in order to identify the major processes that control the slag pH and resulting V leaching. The major changes in the amount of sequestered CO₂ and the resulting pH reduction occurred within 24 h, the free lime containing slag (K3-slag) being more prone to carbonation than the slag with lower free lime content (K1-slag). While carbonation at these conditions was found to occur predominantly at the surface of the slag grains, the formation of cracks was observed in carbonated K3 slag, suggesting that free lime in the interior of slag grains had also reacted. The pH of the K3 slag (originally pH ± 12.5) was reduced by about 1.5 units, while the K1 slag showed a smaller decrease in pH from about 11.7 to 11.1. However, the pH reduction after carbonation of the K3 slag was observed to lead to an increased V-leaching. Vanadium leaching from the K1 slag resulted in levels above the limit values of the Dutch Soil Quality Decree, for both the untreated and carbonated slag. V-leaching from the carbonated K3 slag remained below these limit values at the relatively high pH that remained after carbonation. The V-bearing di-Ca silicate (C2S) phase has been identified as the major source of the V-leaching. It is shown that the dissolution of this mineral is limited in fresh steel slag, but strongly enhanced by carbonation, which causes the observed enhanced release of V from the K3 slag. The obtained insights in the mineral transformation reactions and their effect on pH and V-leaching provide guidance for further improvement of an accelerated carbonation technology.     

My land? Your land? Scotland?—understanding sectoral similarities and differences in Scottish land use visions

Understanding agreement and differences between land use visions forms a first step for assessing and comparing alternative pathways towards a sustainable future. This study presents an analysis of 20 semi-structured interviews with representatives of the principal land use sectors in Scotland. The aim was to understand what, in their ideal vision, they would want rural Scotland to look like in 2050. Inductive content analysis was used to identify similarities and differences amongst interviewees. There was general agreement on the following: the importance of the environment; the wish for more partnerships, dialogue and collaboration; the desire for society to be more engaged and aware about land use; and a strong need for short-, medium- and long-term policies helping to achieve these goals. The most notable differences relate to land ownership and governance. The outcomes form a basis for further facilitated discussions, emphasising common ground and exploring where, how and to what degree land use sectors can prepare and plan in the light of uncertainties posed by Brexit and climate change. The method was effective for understanding commonalities and differences between stakeholder groups and is transferable to other countries or regions.

     

Mapping epistemic cultures and learning potential of participants in citizen science projects

The ever‐widening scope and range of global change and interconnected systemic risks arising from people–environment relationships (social‐ecological risks) appears to be increasing concern among, and involvement of, citizens in an increasingly diversified number of citizen science projects responding to these risks. We examined the relationship between epistemic cultures in citizen science projects and learning potential related to matters of concern. We then developed a typology of purposes and a citizen science epistemic‐cultures heuristic and mapped 56 projects in southern Africa using this framework. The purpose typology represents the range of knowledge‐production purposes, ranging from laboratory science to social learning, whereas the epistemic‐cultures typology is a relational representation of scientist and citizen participation and their approach to knowledge production. Results showed an iterative relationship between matters of fact and matters of concern across the projects; the nexus of citizens’ engagement in knowledge‐production activities varied. The knowledge‐production purposes informed and shaped the epistemic cultures of all the sampled citizen science projects, which in turn influenced the potential for learning within each project. Through a historical review of 3 phases in a long‐term river health‐monitoring project, we found that it is possible to evolve the learning curve of citizen science projects. This evolution involved the development of scientific water monitoring tools, the parallel development of pedagogic practices supporting monitoring activities, and situated engagement around matters of concern within social activism leading to learning‐led change. We conclude that such evolutionary processes serve to increase potential for learning and are necessary if citizen science is to contribute to wider restructuring of the epistemic culture of science under conditions of expanding social‐ecological risk.     

Recovery of plant species richness during long-term fertilization of a species-rich grassland

Nutrient enrichment of habitats (eutrophication) is considered to be one of the main causes of plant diversity decline worldwide. Several experiments have shown a rapid loss of species in the first years after fertilization started. However, little is known about changes in species richness in the long term. Here, we use a 50-year-old field experiment with a range of fertilization treatments in grasslands that were mown twice each year in the center of The Netherlands. We show that species richness in all plots initially declined but started to recover after approximately 25 years of continued fertilization. This was also true for the heavily fertilized treatment (NPK). In NPK-fertilized plots, the decline was strongest and associated with a strong divergence of plant trait composition from the control, reflecting a shift to a plant community adapted to nutrient-rich conditions. During the subsequent period of increase in species richness, the trait composition remained stable. These results show that plant species richness can, at least partially, recover after an initial diversity decline caused by fertilization.     

Analyzing alternative bio-waste feedstocks for potential biodiesel production using time domain (TD)-NMR

Production of biodiesel is currently limited due to lack of economically beneficial feedstocks. Suitability of municipal wastewater sludge and olive mill waste as feedstocks for biodiesel production was evaluated. The various bio-waste sources were analyzed for their oil content and fatty acid composition using conventional analyses complemented with time domain (TD)-NMR analysis. TD-NMR, a rapid non-destructive method newly applied in this field, yielded good correlations with conventional methods. Overall biodiesel yields obtained by TD-NMR analysis were 7.05% and 9.18% (dry wt) for olive mill pomace and liquid wastes, and 11.92%, 7.07%, and 4.65% (dry wt) for primary, secondary, and anaerobically stabilized sludge, respectively. Fatty acid analysis indicated fundamental suitability of these agro-industrial waste resources for biodiesel production. Evaluation of bio-waste materials by TD-NMR revealed the potential of this tool to identify waste-oil sources cost effectively and quickly, supporting expansion of a sustainable biodiesel industry in Israel and other regions.     

LCA comparison of windrow composting of yard wastes with use as alternative daily cover (ADC)

This study compared the environmental impacts of composting yard wastes in windrows with using them in place of soil as alternative daily cover (ADC) in landfills. The Life Cycle Assessment was made using the SimaPro LCA software and showed that the ADC scenario is more beneficial for the environment than windrow composting. ADC use is also a less costly means of disposal of yard wastes. This finding applies only in cases where there are sanitary landfills in the area that are equipped with gas collection systems and can use yard wastes as alternative daily cover. Otherwise, the environmentally preferable method for disposal of source-separated yard wastes is composting rather than landfilling.