Monitoring, modelling and environmental exposure assessment of industrial chemicals in the aquatic environment

Monitoring and laboratory data play integral roles alongside fate and exposure models in comprehensive risk assessments. The principle in the European Union Technical Guidance Documents for risk assessment is that measured data may take precedence over model results but only after they are judged to be of adequate reliability and to be representative of the particular environmental compartments to which they are applied. In practice, laboratory and field data are used to provide parameters for the models, while monitoring data are used to validate the models' predictions. Thus, comprehensive risk assessments require the integration of laboratory and monitoring data with the model predictions. However, this interplay is often overlooked. Discrepancies between the results of models and monitoring should be investigated in terms of the representativeness of both. Certainly, in the context of the EU risk assessment of existing chemicals, the specific requirements for monitoring data have not been adequately addressed. The resources required for environmental monitoring, both in terms of manpower and equipment, can be very significant. The design of monitoring programmes to optimise the use of resources and the use of models as a cost-effective alternative are increasing in importance. Generic considerations and criteria for the design of new monitoring programmes to generate representative quality data for the aquatic compartment are outlined and the criteria for the use of existing data are discussed. In particular, there is a need to improve the accessibility to data sets, to standardise the data sets, to promote communication and harmonisation of programmes and to incorporate the flexibility to change monitoring protocols to amend the chemicals under investigation in line with changing needs and priorities.     

Estimating separately personal exposure to ambient and nonambient particulate matter for epidemiology and risk assessment: why and how

This paper discusses the legal and scientific reasons for separating personal exposure to PM into ambient and nonambient components. It then demonstrates by several examples how well-established models and data typically obtained in exposure field studies can be used to estimate both individual and community average exposure to ambient-generated PM (ambient PM outdoors plus ambient PM that has infiltrated indoors), indoor-generated PM, and personal activity PM. Ambient concentrations are not highly correlated with personal exposure to nonambient PM or total PM but are highly correlated with personal exposure to ambient-generated PM. Therefore, ambient concentrations may be used in epidemiology as an appropriate surrogate for personal exposure to ambient-generated PM. Suggestions are offered as to how exposure to ambient-generated PM may be obtained and used in epidemiology and risk assessment.     

The Volta Lake and Declining Rainfall and Streamflows in the Volta River Basin

This paper looks at the rainfall and streamflow patterns over two distinct time periods, i.e., 1950–1970 and 1971–1991 within the two most prominent catchments in the Volta river system – White Volta and the Oti basins. The first period (1950–1970) represents relatively vegetated catchments and low population whilst the latter (1971–1990) represents intense land use practices resulting from increased population that have severely degraded the environment. These two catchments are among the most significant contributors to the Volta lake. The Volta lake, which was formed between 1962 and 1966 in Ghana and created primarily for hydroelectric power generation, will probably be one of the greatest man-made lakes for a long time. It produces 912MW of electricity at its maximum operating capacity. Recently, there have been declines in the lake levels resulting most probably from inadequate rainfall and/or runoff from the river catchments that feed the lake. Comparisons of runoffs for the two time periods show reductions in mean streamflows of 32.5% at Saboba on the Oti and 23.1% at Nawuni on the White Volta.     

Pilot‐scale evaluation using bioaugmentation to enhance PCE dissolution at dover AFB national test site

An Interstate Technology and Regulatory Council (ITRC) forum was recently held that focused on six case studies in which bioremediation of dense nonaqueous‐phase liquids (DNAPLs) was performed; the objective was to demonstrate that there is credible evidence for bioremediation as a viable environmental remediation technology. The first two case studies from the forum have been previously published; this third case study involves a pilot‐scale demonstration that investigated the effects of biological activity on enhancing dissolution of an emplaced tetrachloroethene (PCE) DNAPL source. It used a controlled‐release test cell with PCE as the primary DNAPL in a porous media groundwater system. Both laboratory tests and a field‐scale pilot test demonstrated that bioaugmentation can stimulate complete dechlorination to a nontoxic end product and that the mass flux from a source zone increases when biological dehalorespiration activity is enhanced through nutrient (electron donor) addition and bioaugmentation. All project goals were met. Important achievements include demonstrating the ability to degrade a PCE DNAPL source to ethene and obtaining significant information on the impacts to the microbial populations and corresponding isotope enrichments during biodegradation of a source area. © 2007 Wiley Periodicals, Inc.     

Emotional intelligence and individual performance: evidence of direct and moderated effects

We examined the direct and moderated effects of an ability‐based measure of emotional intelligence (MSCEIT© V2.0) on individual performance in a sample of business undergraduates. Controlling for general mental ability and personality, emotional intelligence explained unique incremental variance in performance ratings on only one of two measures of interpersonal effectiveness (public speaking effectiveness). However, the interaction of emotional intelligence with conscientiousness explained unique incremental variance both in public speaking and group behavior effectiveness, as well as academic performance (cumulative GPA). We conclude that the effects of emotional intelligence on performance are more indirect than direct in nature. Individuals must not only have emotional intelligence, but also must be motivated to use it. Copyright © 2006 John Wiley & Sons, Ltd.     

Place experience, gestalt, and the human–nature relationship

This paper explores some ways in which differing views about the human–nature relationship reflect and are reflected in people's experiences of the places and environments they encounter in their lives. I first describe how ideas of humans being “part of” versus “apart from” nature have appeared in discussions of environmental ethics and management, and suggest how these contrasting views might relate to people's actual experiences of the natural and human aspects of places. Using qualitative survey responses about outdoor places in the midwestern USA to illustrate ideas from phenomenological and gestalt psychology, I show how a sense of the human–nature relationship is conveyed in the gestalt qualities of places and how this may give rise to a feeling of moral responsibility toward nature. I conclude that the experience of human and natural aspects of real places points toward a dialectical view of the human–nature relationship, in which humans can be seen as simultaneously “part of” and “apart from” nature.