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211.
Catherine Mouneyrac Pierre-Emmanuel Buffet Laurence Poirier Aurore Zalouk-Vergnoux Marielle Guibbolini Christine Risso-de Faverney Douglas Gilliland Déborah Berhanu Agnieszka Dybowska Amélie Châtel Hanane Perrein-Ettajni Jin-Fen Pan Hélène Thomas-Guyon Paul Reip Eugénia Valsami-Jones 《Environmental science and pollution research international》2014,21(13):7899-7912
The objective of this paper is to synthesize results from seven published research papers employing different experimental approaches to evaluate the fate of metal-based nanoparticles (Ag NPs, Au NPs, CuO NPs, CdS NPs, ZnO NPs) in the marine environment and their effects on two marine endobenthic species, the bivalve Scrobicularia plana and the ragworm Hediste diversicolor. The experiments were carried out under laboratory (microcosms) conditions or under environmentally realistic conditions in outdoor mesocosms. Based on results from these seven papers, we addressed the following research questions: (1) How did the environment into which nanoparticles were released affect their physicochemical properties?, (2) How did the route of exposure (seawater, food, sediment) influence bioaccumulation and effects?, (3) Which biomarkers were the most responsive? and (4) Which tools were the most efficient to evaluate the fate and effects of NPs in the marine environment? The obtained results showed that metal‐based NPs in general were highly agglomerated/aggregated in seawater. DGT tools could be used to estimate the bioavailability of metals released from NPs under soluble form in the aquatic environment. Both metal forms (nanoparticulate, soluble) were generally bioaccumulated in both species. Among biochemical tools, GST and CAT were the most sensitive revealing the enhancement of anti-oxidant defenses in both species exposed to sub-lethal concentrations of metal-based NPs. Apoptosis and genotoxicity were frequently observed. 相似文献
212.
Albertinho B. de Carvalho Mina Kato Mariângela M. Rezende Pedro Afonso de P. Pereira Jaílson B. de Andrade 《Environmental science and pollution research international》2013,20(3):1565-1573
Studies have investigated the exposure levels of carbonyl compounds (CC) in the indoor and outdoor air of homes, vehicles, workplaces, urban and industrial areas, and rural sites. However, an investigation of these emissions and occupational exposure to CC in charcoal production facilities has not been previously conducted. The objective of this study was to measure the atmospheric concentrations of several CC to assess the exposure of workers of two charcoal plants located north of Salvador, Bahia, Brazil. Stationary and personal samples were collected using Sep-Pak® C18 cartridges that were coated with a 0.2 % acidic solution of 2,4-dinitrophenylhydrazine. The quantification of the resulting 2,4-dinitrophenylhydrazone derivatives was conducted using a high-performance liquid chromatography system with UV detection. In the personal samples, the concentrations of formaldehyde, acetaldehyde, propanone, furfural, and C4 isomers (n-butanal-isobutanal-butanone) ranged from 12 to 139, 38 to 165, 136 to 483, 39 to 114, and 63 to 132 μg?m?3, respectively. In the stationary samples, the concentrations of these CC ranged from 20 to 160, 111 to 284, 328 to 644, 70 to 163, and 100 to 176 μg?m?3, respectively. When compared to the occupational exposure limits for 8 h, the concentrations of formaldehyde were often greater than the levels recommended by the American National Institute for Occupational Safety and Health, which indicates a health risk for charcoal workers. These results are the first reported concerning the occupational exposure to CC in charcoal plants. 相似文献
213.
Influence of support material on the immobilization of biomass for the degradation of linear alkylbenzene sulfonate in anaerobic reactors 总被引:1,自引:0,他引:1
Lima de Oliveira L Silveira Duarte IC Sakamoto IK Amâncio Varesche MB 《Journal of environmental management》2009,90(2):1261-1268
Two horizontal-flow anaerobic immobilized biomass reactors (HAIB) were used to study the degradation of the LAS surfactant: one filled with charcoal (HAIB1) and the other with a mixed bed of expanded clay and polyurethane foam (HAIB2). The reactors were fed with synthetic substrate supplemented with 14 mg l(-1)of LAS, kept at 30+/-2 degrees C and operated with a hydraulic retention time (HRT) of 12h. The surfactant was quantified by HPLC. Spatial variation analyses were done to quantify organic matter and LAS consumption along the reactor length. The presence of the surfactant in the load did not affect the removal of organic matter (COD), which was close to 90% in both reactors for an influent COD of 550 mg l(-1). The results of a mass balance indicated that 28% of all LAS added to HAIB1 was removed by degradation. HAIB2 presented 27% degradation. Molecular biology techniques revealed microorganisms belonging the uncultured Holophaga sp., uncultured delta Proteobacterium, uncultured Verrucomicrobium sp., Bacteroides sp. and uncultured gamma Proteobacterium sp. The reactor with biomass immobilized on charcoal presented lower adsorption and a higher kinetic degradation coefficient. So, it was the most suitable support for LAS anaerobic treatment. 相似文献
214.
Diório Alexandre Díaz-Angulo Jennyfer Castellanos Reynel M. Gomes Ana I. Bergamasco Rosângela Vieira Marcelo Fernandes Dezotti Márcia Mueses Miguel Angel Machuca-Martinez Fiderman Vilar Vítor J. P. 《Environmental science and pollution research international》2022,29(28):42120-42129
Environmental Science and Pollution Research - This work aims to integrate several hydrogen peroxide (H2O2) activation mechanisms, photolysis (UVC irradiation), chemical electron transfer (TiO2-P25... 相似文献
215.
Vidovix Taynara Basso Januário Eduarda Freitas Diogo Araújo Micael Furioso Bergamasco Rosângela Vieira Angélica Marquetotti Salcedo 《Environmental science and pollution research international》2022,29(31):46813-46829
Environmental Science and Pollution Research - Triclosan (TCS) is widely used in the production of antibacterial products, being often found in wastewater. Therefore, this study developed new... 相似文献