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排序方式: 共有234条查询结果,搜索用时 31 毫秒
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CuFe-SSZ-13 catalyst showed excellent performance in the selective catalytic reduction of NOx with NH3 (NH3-SCR) for diesel engine exhaust purification. To investigate the effect of preparation methods on NH3-SCR performance, Fe was loaded into one-pot synthesized Cu-SSZ-13 catalysts through solid-state ion-exchange (SSIE), homogeneous deposition precipitation (HDP) and liquid ion-exchange (IE), respectively. Three CuFe-SSZ-13 catalysts showed similar SO2 resistance, which was better than that of Cu-SSZ-13. The improvement was attributed to the protection of Fe species. Hydrothermal stability of three CuFe-SSZ-13 catalysts was significantly different, which was attributed to the state of active species caused by different preparation methods. Compared with the other two catalysts, more active species existed inside the zeolite pores of CuFe-SSZ-13SSIE. During hydrothermal aging, the aggregation of these active species in the pores caused the collapse of catalyst structure, ultimately leading to the deactivation of CuFe-SSZ-13SSIE. In contrast, Fe species was dispersed better on the surface over CuFe-SSZ-13IE, enhancing the hydrothermal stability of catalysts. Consequently, Fe loading effectively improved the resistance of SO2 and H2O over Cu-SSZ-13. For CuFe-SSZ-13, large amounts of active species located inside the zeolite pores are not beneficial for the hydrothermal stability. 相似文献
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Huihui Han Hengfeng Miao Yajing Zhang Minfeng Lu Zhenxing Huang Wenquan Ruan Huihui Han Hengfeng Miao Yajing Zhang Minfeng Lu Zhenxing Huang Wenquan Ruan 《环境科学学报(英文版)》2018,30(3):335-346
Disinfection byproduct(DBP)precursors in wastewater during the reversed anaerobic–anoxic–oxic(A~2/O)process,as well as their molecular weight(MW)and polarity-based fractions,were characterized with UV scanning,fluorescence excitation emission matrix,Fourier transform infrared and nuclear magnetic resonance spectroscopy.Their DBP formation potentials(DBPFPs)after chlorination were further tested.Results indicated that the reversed A~2/O process could not only effectively remove the dissolved organic carbon(DOC)and dissolved total nitrogen in the wastewater,but also affect the MW distribution and hydrophilic–hydrophobic properties of dissolved organic matter(DOM).The accumulation of low MW and hydrophobic(HPO)DOM was possibly due to the formation of soluble microbial product-like(SMP-like)matters in the reversed A~2/O treatment,especially in the anoxic and aerobic processes.Moreover,DOM in the wastewater displayed a high carbonaceous disinfection byproduct formation potential(C-DBPFP)in the fractions of MW100 k Da and MW5 k Da,and revealed an increasing tendency of nitrogenous disinfection byproduct formation potential(N-DBPFP)with decrease of MW.For polarity-based fractions,the HPO fraction of wastewater showed significantly higher C-DBPFP and N-DBPFP than hydrophilic and transphilic fractions.Therefore,although the reversed A~2/O process could remove most DBP precursors by DOC reduction,it led to the enhancement of DBPFP with the formation and accumulation of low MW and HPO DOM.In addition,strong correlations between C-DBPFPs and SUVA,and between N-DBPFPs and DON/DOC,were observed in the wastewater,which might be helpful for DBPFP prediction in wastewater and reclaimed water chlorination. 相似文献
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Tao Wang Zhenxing Huang Wenquan Ruan Mingxing Zhao Youlian Shao Hengfeng Miao 《环境科学学报(英文版)》2018,30(2):227-234
In this study, a full-scale internal circulation(IC) reactor coupled with an external circulation system was developed to treat high-strength leachate from a municipal solid waste(MSW)incineration plant, in which anaerobic sludge granulation was intensively investigated. Results showed that the IC reactor achieved excellent treatment performance under high organic loading rates(OLR) of 21.06–25.16 kg chemical oxygen demand(COD)/(m3? day). The COD removal efficiency and biogas yield respectively reached 89.4%–93.4% and 0.42–0.50 m3/kg COD.The formation of extracellular polymeric substances(EPS) was closely associated with sludge granulation. Protein was the dominant component in sludge EPS, and its content was remarkably increased from 21.6 to 99.7 mg/g Volatile Suspended Solid(VSS) during the reactor operation. The sludge Zeta potential and hydrophobicity positively correlated with the protein/polysaccharide ratio in EPS, and they were respectively increased from-26.2 m V and 30.35% to-10.6 m V and 78.67%, which was beneficial to microbial aggregation. Three-dimensional fluorescence spectroscopy(3 D-EEM) and Fourier transform infrared spectroscopy(FT-IR)analysis further indicated the importance of protein-like EPS substances in the sludge granulation. Moreover, it was also found that the secondary structures of EPS proteins varied during the reactor operation. 相似文献
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A novel technology of two-step fast microwave-assisted pyrolysis(f MAP) of corn stover for bio-oil production was investigated in the presence of microwave absorbent(Si C) and HZSM-5catalyst. Effects of f MAP temperature and catalyst-to-biomass ratio on bio-oil yield and chemical components were examined. The results showed that this technology, employing microwave, microwave absorbent and HZSM-5 catalyst, was effective and promising for biomass fast pyrolysis. The f MAP temperature of 500°C was considered the optimum condition for maximum yield and best quality of bio-oil. Besides, the bio-oil yield decreased linearly and the chemical components in bio-oil were improved sequentially with the increase of catalyst-to-biomass ratio from 1:100 to 1:20. The elemental compositions of bio-char were also determined. Additionally, compared to one-step f MAP process, two-step f MAP could promote the bio-oil quality with a smaller catalyst-to-biomass ratio. 相似文献
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降低湿法脱硫系统GGH差压的方法与实践 总被引:1,自引:0,他引:1
针对台州发电厂脱硫系统在投运初期出现GGH差压高现象,首先简要介绍了湿法脱硫系统的GGH工作原理,结合脱硫系统的运行经验和相关试验进行原因分析和探索归纳得出降低GGH差压的几种方法和对策,并论证了对策实施后的效果,使脱硫系统运行达到最佳的经济性和稳定性。这些控制方法和参数对脱硫系统的正常运行,保证SO2浓度的达标排放将起到积极的作用,可为火电厂湿法脱硫系统高效运行提供理论基础和实践依据。 相似文献
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Schumacher Aécio G. Gomes Guilherme J. C. Schneider Denise S. G. Pires Patrício J. M. Gomes Ruan G. S. 《Journal of Material Cycles and Waste Management》2022,24(6):2555-2568
Journal of Material Cycles and Waste Management - The use of industrial byproducts as replacement of natural aggregates has been extensively investigated to design eco-friendly roads. One of the... 相似文献