Rapid and efficient removal of Ni2+ from aqueous solution by the one-pot synthesized EDTA-modified magnetic nanoparticles

A facile one-pot process has been proposed to prepare the novel ethylenediaminetetraacetic acid (EDTA)-modified magnetite nanoparticles (EDTA-MNPs). The bared Fe₃O₄ magnetite nanoparticles and EDTA-MNPs were characterized using FTIR spectroscopy, TEM, VSM, and X-ray diffraction. The application of the modified magnetite nanoparticles for metal ion uptake was studied using Ni²⁺ as a model. The adsorption was fast and the equilibrium was established within 5 min, and the adsorption kinetics of Ni²⁺ onto EDTA-MNPs followed the pseudo second-order chemisorption mechanism. Maximum adsorption capacity for Ni²⁺ reached as high as 41.3 mg/g at pH 6. The successive adsorption–desorption studies indicated that the EDTA-MNPs kept the adsorption and desorption efficiencies constant over ten cycles. Importantly, EDTA-MNPs were able to remove nearly 100 % of Ni²⁺ from real water.     

Impact assessment of human diet changes with rapid urbanization on regional nitrogen and phosphorus flows—a case study of the megacity Shanghai

Regional material flows are strongly influenced by human diets. To diagnose and prevent environmental problems that threaten urban sustainability, the impact of human diet changes with rapid urbanization on the regional nitrogen (N) and phosphorus (P) flows were quantitatively evaluated. A survey of day-to-day activities was conducted of 450 individuals surveyed (adults over 18 years old) in three representative areas (the central district, the new district, and the suburban/rural areas) of Shanghai, a megacity which has attracted worldwide attention. The lifestyle (eating habits, domestic sanitation, drainage facilities, etc.) pattern was determined and the potential N and P loads from human diets on the environment were calculated. The daily potential nitrogen and phosphorus loads from human diets was 19.36 g-N, 1.80 g-P in the central district, 16.48 g-N, 1.52 g-P in the new district, and 13.04 g-N, 1.20 g-P in the suburban/rural areas of Shanghai. Respondents in all three areas, especially those in the suburban/rural areas reported a preference for increasing the intake of animal-derived as well as processed foods, which means that the potential N and P load from human diets to the environment will increase further. In addition, most respondents consider industrial wastewater discharge as the main cause of eutrophication of waterbodies, though in recent years water pollution caused by domestic wastewater has increased rapidly, but this has received much less attention. Environment-friendly eating habits and improvements in the environmental awareness will be required.     

The influences of pH and ionic strength on the sorption of tylosin on goethite

As one of the widely used antibiotics in the world, the environmental risks of tylosin (TYL) received more and more attention. In order to assess its environmental fate and ecological effects accurately, it is necessary to understand the sorption properties of TYL on the soils/sediments. The sorption of TYL on goethite at different pH and ionic strength conditions were measured through a series of batch experiments and the sorption data of TYL were fitted by Freundlich and dual-mode sorption models. It was obvious that sorption was strongly dependent on pH and ionic strength. Sorption capacity of TYL increased as the pH increased and ionic strength decreased. The pH and ionic strength-dependent trends might be related with complexation between cationic/neutral TYL species and goethite. The sorption affinity of TYL on goethite decreased as ionic strength increased, which only occurred at higher TYL concentrations, suggested that inner complex might have dominated process at low concentrations and outer complex might occur at higher concentrations of TYL. Spectroscopic evidence indicated that tricarbonylamide and hydroxyl functional groups of TYL might be accounted for the sorption on mineral surfaces. The experimental data of TYL sorption could be fitted by surface complexation model (FITEQL), indicating that ≡FeOH with TYL interaction could be reasonably represented as a complex formation of a monoacid with discrete sites on goethite. The sorption mechanism of TYL might be related with surface complexation, electrostatic repulsion, and H-bounding on goethite. It should be noticed that the heterogeneous of sorption affinity of TYL on goethite at various environment to assess its environment risk.     

优化的甘蔗皮渣吸附居室甲醛

为了研究优化后的甘蔗皮渣吸附居室中的甲醛,本研究通过3种方法处理材料进行吸附甲醛对比,得出简便高效的碱热烫处理,并针对其热烫时间(X1)、pH值(X2)、水浴锅温度(X3)和水浴时间(X4)设置正交实验,得出热烫时间30 min、pH=11、水浴锅温度80℃、水浴时间2.5 h,甘蔗皮渣对甲醛吸附率可达27.91%。通过与活性炭、硅藻纯吸附效果比较,经F检验得出优化处理甘蔗皮渣与硅藻纯吸附效果相当,均极显著优于活性炭。电镜观测出优化甘蔗皮渣与活性炭、硅藻纯同具粗糙、皱褶、疏松多孔结构;傅里叶红外光谱分析出C≡C等基团在甲醛吸附中起主要作用。     

CLUE-S模型对村镇土地利用变化的模拟与精度评价

利用航片、IKONOS和Quickbird影像得到研究区3期（1991、2001和2009年）土地利用历史数据,运用CLUE S模型,基于1991、2001年的土地利用数据对2009年土地利用格局进行模拟预测,并将模拟结果与2009年真实土地利用数据进行比较。类型水平上,选择ROC曲线统计和偏离度指数分别对各地类的Logistic回归拟合精度和CLUE S模型模拟精度进行评价;景观水平上,采用景观指数和Kappa指数系列方法,从综合预测能力、景观格局、数量和空间位置等方面对CLUE S模型的模拟精度进行全面评估。结果表明:①CLUE S模型对各土地利用类型的模拟精度均较高,各地类的Logistic回归的拟合精度随着模拟分辨率的提高而逐渐增加;②随着模拟时间的缩短,CLUE S模型对整体景观格局的模拟精度提高;③该模型对土地利用数量的模拟精度明显优于其对空间位置的模拟精度。总体而言,CLUE S模型在村镇尺度的模拟效果良好,预测精度较高,但在空间位置和景观格局精度方面还有待提高     

雅砻江流域湿地景观格局变化分析

应用ArcGIS软件,对雅砻江流域湿地1986和2000年遥感数据进行解译、矢量化处理,用Apack软件进行湿地景观格局指数计算,研究了近15 a雅砻江流域景观空间格局特征及其变化。结果表明：（1）近15 a雅砻江流域湿地景观面积减少,减少量为49404 hm2,占2000年湿地总面积的0506%;（2）两个时期内湿地斑块密度保持不变,湿地景观的聚集度都很高,均在099以上,湿地景观集中分布,破碎化水平低;（3）雅砻江流域湿地景观的多样性指数水平和均匀度水平较低,而且两指数在两个个时期内没有发生太大的变化,且各类湿地景观比例差异相对较大,沼泽湿地景观控制的程度较高;（4）雅砻江流域的5类湿地景观分布质心基本上未发生变化,但总体格局分布质心向南偏移001°,再向西偏移023°,整体上向西南方向偏移了2532 km     

A survey-based evaluation of community-based co-management of forest resources: a case study of Baishuijiang National Natural Reserve in China

Community-based co-management (CBCM) mechanisms for forest management have matured through the development of new economic analysis and common property theory. However, while many local CBCM mechanisms have been initiated in Chinese Natural Reserves, there are few objective, data-based evaluations of whether these mechanisms improve forest conservation and local livelihoods. This research uses Baishuijiang National Natural Reserve (BNNR) as a study case to evaluate China’s current CBCM mechanisms. The evaluation is based mainly on three criteria: efficiency, equality and sustainability of project operation. Survey data indicate that local CBCM mechanisms provide a wide-participation platform for local villagers, associated administration managers, research institutions and NGOs to join in forest resource protection work while improving local livelihood. CBCM projects have also facilitated a reduction in forest resource dependency, the improvement of household income and encouragement of local people to participate in forest resource protection. Our analysis suggests that most CBCM organizations have made progress in efficiency, equity and sustainability. However, further study should focus on how to deal with the lingering problems of inequity in responsibility and rights among CBCM committee members, poor distribution of benefits, insufficient program-design and management expertise, faulty information dissemination, and insufficient capital investment.     

地震救援行动的影响因素分析

从探讨救援行动的概念和响应过程出发,在分析国内外相关资料的基础上,结合我国的实际情况,分析了影响地震救援行动的方面和因素,以及它们对救援行动可能产生的影响,以期为地震救援的理论和实践提供有益的补充。     

基于汶川8.0级强震记录的近场地震动特征分析

在汶川8.0级大地震中,国家数字强震动台网布设在龙门山断裂带及其周围地区的50多个台站获得了大于100 Gal的加速度记录。选取其中断层附近11个台站的加速度记录,分别进行了地震反应谱分析和基于正交化HHT法的能量分布特征分析,通过对竖向与水平向加速度峰值比、竖向与水平向加速度反应谱比值,以及能量分布和峰值系数的分析与比较,探讨了汶川地震的近场地震动特征。     

自然灾害社会脆弱性评估研究——以上海市为例

基于投影寻踪聚类模型(PPC),结合基于实数编码的加速遗传算法(RAGA),对上海市进行了自然灾害社会脆弱性评估的尝试。结果表明:①灾害社会脆弱性最高的为崇明县,其次为宝山区和金山区;②灾害社会脆弱性最低的是黄埔区,其次是徐汇区和静安区;③总体而言,灾害脆弱性较低的地区集中于上海城市中心区,而城市边缘区的社会脆弱性一般较高。