生物催化氧化法脱除H2S的试验研究

针对H₂S污染的严峻形势，构建了包括催化再生装置和生物滴滤器的生物催化氧化装置。该装置以沸石为填料，以氧化亚铁硫杆菌为脱硫菌种，通过微生物和Fe³⁺的双重氧化作用高效脱除H₂S。试验确定了装置的适宜喷淋量和沸石的最佳粒径。在温度为30℃，进气量为0.25 m³/h，进气H₂S浓度为2500mg/m³，喷淋量为1000mL/h，喷淋液的pH值为1.97、Fe³⁺浓度为0.05 mol/L的条件下，出气H₂S浓度足以达到GB14554-93规定的一级厂界标准值。试验证明，生物催化氧化法是一种新型高效的脱硫技术，应进一步开展中试研究。     

Response of non-point source pollutant loads to climate change in the Shitoukoumen reservoir catchment

The impacts of climate change on streamflow and non-point source pollutant loads in the Shitoukoumen reservoir catchment are predicted by combining a general circulation model (HadCM3) with the Soil and Water Assessment Tool (SWAT) hydrological model. A statistical downscaling model was used to generate future local scenarios of meteorological variables such as temperature and precipitation. Then, the downscaled meteorological variables were used as input to the SWAT hydrological model calibrated and validated with observations, and the corresponding changes of future streamflow and non-point source pollutant loads in Shitoukoumen reservoir catchment were simulated and analyzed. Results show that daily temperature increases in three future periods (2010–2039, 2040–2069, and 2070–2099) relative to a baseline of 1961–1990, and the rate of increase is 0.63°C per decade. Annual precipitation also shows an apparent increase of 11 mm per decade. The calibration and validation results showed that the SWAT model was able to simulate well the streamflow and non-point source pollutant loads, with a coefficient of determination of 0.7 and a Nash–Sutcliffe efficiency of about 0.7 for both the calibration and validation periods. The future climate change has a significant impact on streamflow and non-point source pollutant loads. The annual streamflow shows a fluctuating upward trend from 2010 to 2099, with an increase rate of 1.1 m³ s⁻¹ per decade, and a significant upward trend in summer, with an increase rate of 1.32 m³ s⁻¹ per decade. The increase in summer contributes the most to the increase of annual load compared with other seasons. The annual NH₄⁺-N load into Shitoukoumen reservoir shows a significant downward trend with a decrease rate of 40.6 t per decade. The annual TP load shows an insignificant increasing trend, and its change rate is 3.77 t per decade. The results of this analysis provide a scientific basis for effective support of decision makers and strategies of adaptation to climate change.     

Evaluating the effectiveness of routine water quality monitoring in Miyun reservoir based on geostatistical analysis

This study used geographic information system techniques and geostatistics methods to evaluate the effectiveness of routine water quality monitoring in the western segment of the Miyun reservoir in Beijing. Methodologies as well as the sampling design are evaluated. The single-layer evaluation and three integrated evaluation methods including principal component analysis (PCA), ordinary kriging (OK)_Mean, and Mean_Layers were used to validate the effectiveness of evaluation methods, and the effectiveness of each sampling design was validated by comparing their errors. Results indicated that, while a single-layer evaluation only shows the trophic state of water at a specific level, an integrated evaluation synthetically analyzes and evaluates the trophic state of the entire water body. Furthermore, results of the integrated analysis show that a PCA method is more accurate and can represent the trophic state of the entire water body. The OK_Mean and Mean_Layers methods are only able to represent the mean level for trophic state of the entire water body but cannot reflect local trophic state and distribution details. Although methods used in the routine monitoring of Miyun reservoir have some similarities to the OK_Mean and Mean_Layers methods, their range of errors and uncertainty are greater because of a lack of detailed spatial continuous information. The analysis on the number of sampling points shows that, within a certain range of error, minor changes of sampling points will have no obvious impact on the monitoring results. For the routine monitoring of western Miyun reservoir, using only three to five sampling points for monitoring is inadequate. According to our analysis, it is more appropriate to use at least ten sampling points for monitoring these areas.     

单边界、双边界二分式条件价值评估方法的比较——以北京市空气污染对健康危害问卷调查为例

 以北京市空气污染健康危害经济评价为例,采用目前国际上推荐的条件价值评估最适合的二分式问卷格式,探索条件价值评估最大支付意愿引导技术在我国应用的适用性.结果表明,单边界问卷格式和双边界问卷格式估计平均最大支付意愿分别为739.57,652.33元/年,两问卷格式估计平均最大支付意愿的95%置信区间分别为656.49～845.34,604.04～707.01元/年.双边界问卷格式与单边界问卷格式相比能够获得被调查者支付意愿的更多信息,从而缩小估计的置信区间,提高最大支付意愿的估计精度.     

粉尘捕集用滤膜的性能实验结果

本文介绍了粉尘捕集用滤膜的性能、捕集原理、选择方法和滤膜的捕集效率、阻力的实验结果。     

土壤中石油类的测定方法

采用四氯化碳提取硅酸镁吸附非分散红外法测定土壤中石油类,该方法操作步骤简单,分析时间较短,测定方法回收率在９１～９６％之间,方法的精密度满足监测分析的要求。     

浅议环境监理员的威信及其形成机制

论述了环境监理员的工作威信源于法权作用力和自然影响力。指出环保行政主管部门乃至社会各界应用环境监理营造一个良好的氛围，以增强法权作用力；环境监理人员要不断加强自身修养，以提高自然影响力。     

上覆富水砂层地铁隧道掌子面变形特征数值试验研究∗

为研究地铁隧道在上覆富水砂层下的变形特征，以典型上覆富水砂层隧道—青岛地铁 2 号线啤—苗区间为工程研究背景，采用 FLAC 3D 数值模拟软件对不同富水砂层厚度与隔水层厚度工况下隧道掌子面位移、塑性区变化特征进行了研究分析。研究结果表明：隔水层厚度是影响掌子面是否发生涌水涌砂的主控因素，在开挖过程中应时刻注意富水砂层距离隧道顶板的安全距离，临界隔水层的厚度为 3 m。同时，当隔水层厚度越大、富水砂层厚度越小时，掌子面变形就会越小。以临界工况为研究对象，通过分析开挖过程中隧道拱顶—拱腰—掌子面应力和位移变形规律，引入了位移释放系数和应力释放率两参数来揭示围岩与掌子面在隧道开挖过程中的影响关系。通过进一步拟合掌子面失稳破坏预测方程，得到了掌子面变形释放率拐点先于同一断面围岩径向变形且发生在开挖到目标断面之前的重要结论，因此在实际隧道开挖过程中应将掌子面的变形作为首选敏感监测指标。研究结果可为该不良地质条件下隧道掌子面稳定性和预加固时机选择提供一定的理论指导。     

Linking land degradation and restoration to ecosystem services balance by identifying landscape drivers: insights from the globally largest loess deposit area

Environmental Science and Pollution Research - Land degradation is one of the most serious environmental challenges that profoundly affects ecosystem services (ESs), which further threaten...     

Open Pore Morphology Evolution in Poly(butylene succinate)/Chitin Nanocrystal Nanocomposite Foams

Journal of Polymers and the Environment - In recent decades, biodegradable polymeric open-porous foams have been engaging increasing interests owing to their biodegradability, porosity and...