Externalities, Market Power, and Resource Extraction

This article analyzes the effect of market power in the presence of dynamic and biological externalities. When several countries harvest fish in international waters the evolution of fish population is affected by their joint action, thus generating a biological and a dynamic externality. If there is trade, the market-clearing prices depend on the harvesting and consumption in all countries. Therefore, market-clearing prices also generate an externality. We find a subgame perfect Cournot–Nash equilibrium and study the conditions under which it may be efficient. We also analyze the role of different externalities in generating inefficiency.     

Influence of some abiotic environmental factors on acute toxicity of inorganic lead to Cyprinus carpio var communis (Linn.) and Catla catla (Ham.) in simulated toxic aquatic environment

With the increase of water hardness from 60 to 720?mg/L CaCO₃, total alkalinity from 32 to 376?mg/L CaCO_3, pH from 7.6 to 7.9 and chloride from 28 to 350?mg/L, 96?h LC₅₀ on the basis of total lead increased from 8.2 to 1291?mg/L for Cyprinus carpio and 5.3 to 865?mg/L for Catla catla, when soil sediments were included these values were further raised to 1356 and 874?mg/L, respectively. The dissolved lead LC₅₀ values in all the treatments of soil and water was consistent with fixed amount of dissolved lead (1.04–1.78?mg/L) being needed for median lethal toxicity. Total lead toxicity also decreased with increase in pH from 6.3 to 11.3. 96?h LC₅₀ values increased for common carp 15 to 631?mg/L and for catla, 8 to 355?mg/L. But dissolved lead toxicity was found to increase with the increase of pH from 6.3 to 11.3 for both common carp (LC₅₀, 3.53 to 0.24?mg/L) and catla (LC₅₀, 2.21 to 0.09?mg/L). Removal of dissolved Pb with increasing carbonate content, particulate matter and pH due to adsorption, precipitation or coprecipitation reaction, reduced the dissolved lead concentration and thus the total lead toxicity. Increase in toxicity of lead with increase of exposure time was the biological response of longer contact time and decrease in dissolved lead toxicity with decrease in pH was due to increase H⁺ ion competition.     

Earthworms,pesticides and sustainable agriculture: a review

The aim of this review is to generate awareness and understand the importance of earthworms in sustainable agriculture and effect of pesticides on their action. The natural resources are finite and highly prone to degradation by the misuse of land and mismanagement of soil. The world is in utter need of a healthy ecosystem that provides with fertile soil, clean water, food and other natural resources. Anthropogenic activities have led to an increased contamination of land. The intensification of industrial and agricultural practices chiefly the utilization of pesticides has in almost every way made our natural resources concave. Earthworms help in a number of tasks that support many ecosystem services that favor agrosystem sustainability but are degraded by exhaustive practices such as the use of pesticides. The present review assesses the response of earthworm toward the pesticides and also evaluates the relationship between earthworm activity and plant growth. We strictly need to refresh and rethink on the policies and norms devised by us on sustainable ecology. In an equivalent way, the natural resources should be utilized and further, essential ways for betterment of present and future livelihood should be sought.     

Chelant-aided enhancement of lead mobilization in residential soils

Chelation of metals is an important factor in enhancing solubility and hence, availability to plants to promote phytoremediation. We compared the effects of two chelants, namely, ethylenediaminetetraacetic acid (EDTA) and ethylenediaminedisuccinic acid (EDDS) in enhancing mobilized lead (Pb) in Pb-based paint contaminated residential soils collected from San Antonio, Texas and Baltimore, Maryland. Batch incubation studies were performed to investigate the effectiveness of the two chelants in enhancing mobilized Pb, at various concentrations and treatment durations. Over a period of 1 month, the mobilized Pb pool in the San Antonio study soils increased from 52 mg kg⁻¹ to 287 and 114 mg kg⁻¹ in the presence of 15 mM kg⁻¹ EDTA and EDDS, respectively. Stepwise linear regression analysis demonstrated that pH and organic matter content significantly affected the mobilized Pb fraction. The regression models explained a large percentage, from 83 to 99%, of the total variation in mobilized Pb concentrations.     

Effectiveness of urea in enhancing the extractability of 2,4,6-trinitrotoluene from chemically variant soils

One of the major challenges in developing an effective phytoremediation technology for 2,4,6-trinitrotoluene (TNT) contaminated soils is limited plant uptake resulting from low solubility of TNT. The effectiveness of urea as a solubilizing agent in increasing plant uptake of TNT in hydroponic systems has been documented. Our preliminary greenhouse experiments using urea were also very promising, but further characterization of the performance of urea in highly-complex soil-solution was necessary. The present study investigated the natural retention capacity of four chemically variant soils and optimized the factors influencing the effectiveness of urea in enhancing TNT solubility in the soil solutions. Results show that the extent of TNT sorption and desorption varies with the soil properties, and is mainly dependent on soil organic matter (SOM) content. Hysteretic desorption of TNT in all tested soils suggests irreversible sorption of TNT and indicates the need of using an extractant to increase the release of TNT in soil solutions. Urea significantly (p < 0.0001) enhanced TNT extraction from all soils, by increasing its solubility at the solid/liquid interface. Soil organic matter content and urea application rates showed significant effects, whereas pH did not exert any significant effect on urea catalysis of TNT extraction from soil. The optimum urea application rates (125 or 350 mg kg⁻¹) for maximizing TNT extraction were within the limits set by the agronomic fertilizer-N rates used for major agricultural crops. The data obtained from this batch study will facilitate the optimization of a chemically-catalyzed phytoremediation model for cleaning up TNT-contaminated soils.     

Threatened access, risk of eviction and forest degradation: case study of sustainability problem in a remote rural region in India

Degradation of common pool resource (CPR) in developing countries has often been traced to high rate attached by poor people in discounting future flow of benefits, market failure, pressure on carrying capacity or sometimes property right failure. However, the concept of poorly enforced property right and particularly risk of eviction as a measure of insecurity of land tenure has not been adequately examined in the context of degradation of CPR. A game theoretic framework is developed where degradation of forest grazing land is explained in terms of changes in perceived risk of eviction from the encroached land. Logit regression is applied to empirically analyse the impact of perceived fear of reduced access and other variables on the state of degradation. For this purpose, a sample of seven villages is considered in tribal dominated region in West Bengal, India. It is observed that apart from a number of socio-economic variables like poverty, mutual trust and other incomes, perceived fear of eviction (represented as a dummy variable) arising from insecurity of forest land tenure, has a significant impact on forest degradation status in the study region.     

Effect of amendments on the extractability, retention and plant uptake of metals on a sewage-irrigated soil

Laboratory and greenhouse experiments were conducted to evaluate the effects of farmyard manure (FYM), CaCO(3) and single superphosphate (SSP) on retention and availability of Zn, Cu and Ni in sewage-irrigated soil. We also assessed the suitability of 0.05M EDTA for predicting the effectiveness of these amendments in reducing the phytoavailability of metals. Results indicated that EDTA could successfully predict the phytoavailability of Zn and Ni in amended soil, whereas it failed in case of Cu. By and large, application of CaCO(3), either alone or in combination with FYM had a positive effect on the retention of Zn, Cu and Ni in soil. Application of CaCO(3) alone or in combination with FYM was equally effective in reducing the Zn content in lettuce, whereas sole application of CaCO(3) significantly reduced Ni content. However, only SSP was found to be effective in reducing the Cu content in lettuce.     

An Improved Rating System for Assessing Surface Water Contamination Potential from MSW Landfills

Leachate emission from uncontrolled municipal solid waste landfills (referred to as waste sites in the present study) is a major threat to the environment and living beings in its vicinity. Surface water contamination potential resulting from leachate may be used as one of the criteria for prioritization of sites for remediation purposes. The existing hazard rating systems that prioritize waste sites considering surface water contamination potential as one of the criteria are mainly suited for the developed countries where these were developed initially. In developing countries like India, the set of conditions differ from those in developed countries, and therefore the existing systems may not be suitable for developing countries. Thus in the present study, an improved system is proposed to assess surface water contamination potential from MSW sites. The system is based on the concept of Source, Pathway and Receptor. The proposed system employs parameters derived from the review of existing rating systems and selects their best and worst values based on literature review, design standards and field conditions. The importance weights of the system parameters have been decided based on expert judgment using Delphi technique. Sensitivity analysis of the system shows that the improved system is more sensitive than the existing systems for the site conditions encountered in developing countries. Monte Carlo analysis of the proposed system confirms the spread of the scores obtained from the system over the full scale of 0–1000. The improved system is compared with existing systems by applying it to waste sites from metropolitan cities of India and performing clustering analysis on the rating scores. The clustering analysis shows that the rating scores from the improved system are less clustered as compared to the scores from the existing systems. This demonstrates that the improved system makes a better tool to distinctly prioritize the waste sites for remediation purpose.     

Predicting bioavailability of metals from sludge-amended soils

We attempted to develop a protocol for fixing the maximum permissible limit of sludge in agricultural lands based on transfer of metals from sludge-amended soils to human food chain. For this purpose, spinach was grown as a test crop on acid and alkaline soils with graded doses of sludge (0, 1.12, 2.24, 4.48, 8.96, 17.9, 35.8, 71.6, 142 and 285 g kg^?1 of soil) in a pot experiment. Biomass yield of spinach was increased due to sludge application in both acid and alkaline soils. Among the chemical extractants, EDTA extracted the highest amount of metals from sludge-amended soil followed by diethylenetriaminepentaacetic acid (DTPA) and CaCl₂. Elevated levels of Zn, Cu, Fe, Mn, Ni, Cd and Pb in spinach were observed due to sludge application over control. Application of sludge was more effective in increasing metal content in spinach grown on acid soil than alkaline soil. Solubility-free ion activity model as a function of pH, organic carbon and extractable metal was far more effective in predicting metal uptake by spinach grown on sludge-amended soils as compared to that of chemical extractants. Risk in terms of hazard quotient (HQ) for intake of metals through consumption of spinach by humans grown on sludge-treated soils was computed for different metals separately. In a 90-day pot experiment, safe rates of sludge application were worked out as 4.48 and 71.6 g kg^?1 for acid and alkaline soils, respectively.     

Second International Conference on “Recent Trends in Environment and Sustainable Development” (RTESD 2019)

Environmental Science and Pollution Research -