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71.
Cronin JP Agrawal A Adams L Tonazzi JC Brisson MJ White KT Marlow D Ashley K 《Journal of environmental monitoring : JEM》2008,10(8):955-960
Analytical methods for the determination of trace beryllium in soils are needed so that anthropogenic sources of this element can be distinguished from native (background) levels of beryllium. In this work, a collaborative interlaboratory evaluation of a new extraction and fluorescence-based procedure for determining beryllium in soil samples was carried out to fulfil method validation requirements for ASTM International voluntary consensus standard test methods. A Canadian reference material, CCRMP Till-1 soil, with a background beryllium concentration of 2.4 microg g(-1), was selected for study. This certified reference material (CRM) was spiked and homogenized with varying levels of beryllium oxide in order to give batches of material with beryllium concentrations of 4.36 +/- 0.69, 11.5 +/- 0.7, 124 +/- 7 and 246 +/- 16 microg g(-1) (+/- values are standard deviations). In the interlaboratory study (ILS), which was carried out in accordance with an applicable ASTM International standard practice (ASTM E691), samples of these spiked soils were subjected to extraction in dilute ammonium bifluoride at approximately 90 degrees C for 40 h. Fluorescence measurement of the extracted beryllium was carried out via detection using the high quantum yield fluorophore, hydroxybenzoquinoline sulfonate (HBQS). Interlaboratory precision estimates from six participating laboratories ranged from 0.048 to 0.103 (relative standard deviations) for the five different beryllium concentrations. Pooled bias estimates resulting from this ILS were between -0.049 and 0.177 for the various beryllium levels. These figures of merit support promulgation of the analytical procedure as an ASTM International standard test method. 相似文献
72.
Sewage sludge, also referred as biosolids, is a byproduct of sewage treatment processes. Land application of sewage sludge is one of the important disposal alternatives. Characteristics of sewage sludge depend upon the quality of sewage and type of treatment processes followed. Being rich in organic and inorganic plant nutrients, sewage sludge may substitute for fertilizer, but availability of potential toxic metals often restricts its uses. Sludge amendment to the soil modifies its physico-chemical and biological properties. Crop yield in adequately sludge-amended soil is generally more than that of well-fertilized controls. Bioavailability of metals increases in sludge amended soil at excessive rates of application for many years. Plants differ in their abilities to absorb sludge-derived metals from the soil. The purpose of this paper is to review the available information on various aspects of sewage sludge application on soil fertility and consequent effects on plant production to explore the possibility of exploiting this byproduct for agronomy and horticulture. 相似文献
73.
74.
Aneil F. Agrawal 《Behavioral ecology and sociobiology》2001,51(1):33-40
In some species, a female's mating preference can be influenced by the matings she observes. Mate copying occurs when a female alters her mating preference in favor of the type of males she has observed mating with other females. Here I present a model that explores the consequences of mate copying on the evolution of male traits. In contrast to previous work, I show that mate copying can have diverse evolutionary consequences. Mate copying can cause (positive or negative) directional selection on male traits or (positive or negative) frequency-dependent selection on male traits. The type of selection generated by mate copying depends on the details of how females are influenced by the matings that they observe. I discuss my results in relation to previous theoretical work that posits that mate copying can only hamper the spread of novel male traits. 相似文献
75.
Residual stress profile in a component is often considered as the critical characteristic as it directly affects the fatigue life of a machined component. This work presents an analytical model for the prediction of residual stresses in orthogonal machining of AISI4340 steel. The novelty of the model lies in the physics-based approach focusing on the nature of contact stresses in various machining zones and the effect of machining temperature. The model incorporates: (i) stresses in three contact regions viz. shear, tool-nose-work piece and tool flank and machined surface, (ii) machining temperature, (iii) strain, strain rate and temperature dependent work material properties, (iv) plastic stresses evaluation by two algorithms, S-J and hybrid, (v) relaxation procedure and (iv) cutting conditions. The model benchmarking shows (86–88%) agreement between the experimental and predicted residual stresses in the X- and Y-directions. On the machined surface, the tensile residual stresses decrease with an increase the edge radius and increase with an increase the cutting speed. However, below the surface, the compressive residual stresses increase with an increase the depth of cut. Further, it is observed that the proposed model with hybrid algorithm gives better results at a lower feed rate, whereas with the S-J algorithm, at a higher feed rate. 相似文献
76.
In view of the present increasing trends of anthropogenic emissions of carbon dioxide (CO2) and sulphur dioxide (SO2) throughout the world, the present study was aimed at investigating the long-term influence of elevated concentrations of CO2 and SO2, singly and in combination on the physiological and biochemical characteristics of two cultivars of wheat (Triticum aestivum L. cv. Malviya 234 and HP1209). For this purpose, the plants were grown in open top chambers under field conditions and were fumigated with 600 ppm CO2, 0.06 ppm SO2 and 600 ppm CO2 + 0.06 ppm SO2 separately for 8 h daily (0800-1600 h) from germination to grain maturity. The individual treatment of SO2 advers#ely affected both the cultivars of wheat by reducing protein and starch contents. The respiration rate, total soluble sugars and total phenolics, however, increased in response to SO2. Stimulation of photosynthesis rate and reduction in stomatal conductance and transpiration rate were observed under CO2 treatment. Concentrations of total soluble sugars, starch and total phenolics increased in response to CO2 and CO2 + SO2 treatments. In combined treatment, CO2 modified the plant response to SO2 in both the cultivars. Elevated CO2 increased the photosynthesis rate under combined treatment. Higher levels of starch and soluble sugars under combined treatment provided extra carbon for SO2 detoxification. The pattern of intraspecific response of wheat to different treatments was more or less similar, but the magnitude of response differed significantly. 相似文献
77.
Effect of air pollution on peri-urban agriculture: a case study 总被引:10,自引:0,他引:10
Agrawal M Singh B Rajput M Marshall F Bell JN 《Environmental pollution (Barking, Essex : 1987)》2003,126(3):323-329
Peri-urban agriculture is vital for the urban populations of many developing countries. Increases in both industrialization and urbanization, and associated air pollution threaten urban food production and its quality. Six hour mean concentrations were monitored for SO(2), NO(2) and O(3) and plant responses were measured in terms of physiological characteristics, pigment, biomass and yield. Parameter reductions in mung bean (Vigna radiata), palak (Beta vulgaris), wheat (Triticum aestivum) and mustard (Brassica compestris) grown within the urban fringes of Varanasi, India correlated directly with the gaseous pollutants levels. The magnitude of response involved all three gaseous pollutants at peri-urban sites; O(3) had more influence at a rural site. The study concluded that air pollution in Varanasi could negatively influence crop yield. 相似文献
78.
Archana Agrawal Kamala Kanta Sahu Banshi Dhar Pandey 《Waste management & research》2004,22(4):240-247
Implementation of stricter environmental laws and economic reasons has forced all the metallurgical industries to go for eco-friendly technologies to produce metal and other related products. However, generation of wastes is an integral part of metallurgical industries. If the wastes/residues are hazardous in nature, they generally have to be treated or/and disposed of in safe and designated dumping sites. If these wastes/residues are non-hazardous in nature, then they may be suitable for use as secondary raw material to recover metals such as lead, copper etc., which are in growing demand all over the world. The processing of lead secondaries is important because of their relative high metal content, as well as the low energy and cost involved in recovering the metal. This paper mainly focuses on the current practices and recent trends in the secondary processing of lead. Various processes, particularly hydrometallurgical ones, already developed or in the development stages, are discussed. Attempts made by various Council of Scientific and Industrial Research (CSIR) Laboratories including the National Metallurgical Laboratory (NML) and industries such as Binani Zinc to develop eco-friendly processes for the recovery of lead from secondary raw materials are also described. 相似文献
79.
Nivedita Chaudhary Suruchi Singh S. B. Agrawal Madhoolika Agrawal 《Environmental monitoring and assessment》2013,185(9):7793-7807
Six Indian cultivars of Vigna radiata L. (HUM-1, HUM-2, HUM-6, HUM-23, HUM-24 and HUM-26) were exposed with ambient and elevated (ambient + 10 ppb ozone (O3) for 6 h?day?1) level of O3 in open top chambers. Ozone sensitivity was assessed by recording the magnitude of foliar visible injury and changes in various physiological parameters. All the six cultivars showed visible foliar symptoms due to O3, ranging 7.4 to 55.7 % injured leaf area. O3 significantly depressed total chlorophyll, photosynthetic rate (Ps), quantum yield (F v/F m) and total biomass although the extent of variation was cultivar specific. Cultivar HUM-1 showed maximum reduction in Ps and stomatal conductance. The fluorescence parameters also indicated maximum damage to PSII reaction centres of HUM-1. Injury percentage, chlorophyll loss, Ps, F v/F m and total biomass reduced least in HUM-23 depicting highest O3 resistance (R%). 相似文献
80.
Singh P Singh S Agrawal SB Agrawal M 《Environmental monitoring and assessment》2012,184(10):5863-5874
Rising O(3) concentrations in agricultural areas have been identified as a significant threat to crop production in Asia including India. The present work reports the results of a field study conducted to assess the usefulness of higher than recommended NPK dose in modifying the physiological, growth, yield, and seed quality responses of two mustard (Brassica campestris L. var. Vardan and Aashirwad) varieties under ambient ozone level at a rural site of India, using open-top chambers. Twelve hourly mean O(3) concentrations ranged between 27.7 and 59.04 ppb during the growth period. Plants in nonfiltered chambers (NFCs) showed reductions in photosynthetic rate, stomatal conductance, and growth parameters compared to the plants in filtered chambers (FCs), but reductions were of lower magnitude at 1.5 times recommended dose of NPK (1.5 RNPK) compared to recommended (RNPK). Yield and seed quality reduced significantly in plants of NFCs compared to FCs at RNPK, but no significant differences were recorded at 1.5 RNPK. There were higher N uptake and N uptake efficiency of plants in FCs compared to NFCs. Nitrogen utilization efficiency increased in Vardan, but decreased in Aashirwad in NFCs compared to FCs suggesting higher capability of N acquisition and utilization under ambient O(3), which led to a less pronounced reduction in the yield of the former than the latter variety. The differential nitrogen utilization efficiency in these varieties may be potentially used as measure of sensitivity characteristics in breeding programs for yield improvement in mustard under the present trend of increase in O(3) concentrations. 相似文献