Evaluating the effectiveness of routine water quality monitoring in Miyun reservoir based on geostatistical analysis

This study used geographic information system techniques and geostatistics methods to evaluate the effectiveness of routine water quality monitoring in the western segment of the Miyun reservoir in Beijing. Methodologies as well as the sampling design are evaluated. The single-layer evaluation and three integrated evaluation methods including principal component analysis (PCA), ordinary kriging (OK)_Mean, and Mean_Layers were used to validate the effectiveness of evaluation methods, and the effectiveness of each sampling design was validated by comparing their errors. Results indicated that, while a single-layer evaluation only shows the trophic state of water at a specific level, an integrated evaluation synthetically analyzes and evaluates the trophic state of the entire water body. Furthermore, results of the integrated analysis show that a PCA method is more accurate and can represent the trophic state of the entire water body. The OK_Mean and Mean_Layers methods are only able to represent the mean level for trophic state of the entire water body but cannot reflect local trophic state and distribution details. Although methods used in the routine monitoring of Miyun reservoir have some similarities to the OK_Mean and Mean_Layers methods, their range of errors and uncertainty are greater because of a lack of detailed spatial continuous information. The analysis on the number of sampling points shows that, within a certain range of error, minor changes of sampling points will have no obvious impact on the monitoring results. For the routine monitoring of western Miyun reservoir, using only three to five sampling points for monitoring is inadequate. According to our analysis, it is more appropriate to use at least ten sampling points for monitoring these areas.     

高职《园林CAD》项目教学的实践应用

介绍了《园林CAD》课程的项目化教学思路,从课程对应岗位群、教学内容的项目化处理、教学设计等3个方面阐述了项目化教学的实践应用。教学实践表明,该方法有效增强了学生学习专业知识的目的性,实现了理论教学和实践教学更好的衔接,有效提高了学生的岗位能力,取得了较好的教学效果,为类似专业课程的教学提供了参考。     

柳江国家地质公园的科学价值与地质环境保护

秦皇岛柳江国家地质公园以地质遗迹资源丰富、地貌景观多样而闻名,具有重要的科学研究价值和旅游价值。然而地方政府为满足短期经济发展的需要,过度开发园区内的煤炭、水泥灰岩等矿产资源,致使一些珍贵的地质遗迹被破坏。为此,从政策、法规以及宣传教育层面对地质遗迹的保护提出一些建议。     

森林凋落物研究现状及我国西南喀斯特地区研究展望

近几十年来,我国西南喀斯特地区生态环境退化严重,石漠化面积迅速扩大,林地覆盖率急剧下降,成为制约我国西部大开发生态建设中不可回避的重要科学问题,严重影响了西南地区社会、经济的可持续发展。喀斯特地区土层薄且侵蚀严重,土壤中的有机碳和营养盐主要来自地表枯枝落叶层的分解及累积。在气候变暖、陆地生态系统土壤温度升高、土壤有机碳急速流失和土壤质量退化的背景下,分析不同林下凋落物量和降解动态以及土壤有机碳库积累差异,揭示西南喀斯特地区不同林地凋落物归还量及其对土壤碳库积累的贡献具有极其重要的意义,将为喀斯特地区林地恢复重建和石漠化遏制工作提供科研依据。     

Spatial distribution,temporal variation,and sources of heavy metal pollution in groundwater of a century-old nonferrous metal mining and smelting area in China

This study first presents the spatial distribution, temporal variation, and sources of heavy metal pollution in groundwater of a nonferrous metal mine area in China. Unconfined groundwater was polluted by Pb, Zn, As, and Cu, in order, while confined karst water in the mines showed pollution in the following sequence: Zn, Cd, Cu, Pb, and As. Pollution by Pb was widespread, while Zn, As, Cu, and Cd were found to be high in the north–central industrial region and to decrease gradually with distance from smelters and tailings. Vertically, more Pb, Zn, Cu, and Cd have accumulated in shallow Quaternary groundwater, while more As have migrated into the deeper fracture groundwater in the local discharge area. Zn, Cd, and Cu concentrations in groundwater along the riverside diminished owing to reduced wastewater drainage since 1977, while samples in the confluence area were found to have increasing contents of Pb, Zn, As, Cu, and Cd since industrialization began in the 1990s. Sources of heavy metals in groundwater were of anthropogenic origin except for Cr. Pb originated primarily from airborne volatile particulates, wastewater, and waste residues and deposited continuously, while Zn, Cd, and Cu were derived from the wastewater of smelters and leakage of tailings, which corresponded to the related soil and surface residue researches. Elevated As values around factories might be the result of chemical reactions. Flow patterns in different hydrogeological units and adsorption capability of from Quaternary sediments restricted their cross-border diffusion.     

三效催化转化器催化剂硫中毒机理

在一种详细的表面反应机理中加入了包含贵金属催化剂与助催化剂的硫中毒基元反应,建立了新的三效催化转化器催化反应机理。利用该机理进行了稳态工况数值模拟,得到了各排气污染物起燃温度与转化效率随尾气中SO2浓度的变化情况。采用灰色关联分析了SO2浓度与各排气组分转化效率的关联度,结果表明,SO2浓度对C3H6与NOx转化效率影响最大。对三效催化转化器的催化剂活性设计具有重要的参考价值,并对其工况设计及优化提供了指导。     

活性染料K-2BP、KN-B和KN-R在椰壳活性炭上的脱色性能

开展椰壳活性炭对活性染料K-2BP、KN-B和KN-R的吸附脱色研究。发现K-2BP、KN-B和KN-R在该型活性炭上的吸附脱色率均随初始pH值的降低、温度的升高、染料初始浓度的降低、活性炭用量的增加以及NaCl盐度的增加而增加。在pH=7和T=25℃下,K-2BP、KN-B和KN-R在活性炭上的等温吸附规律符合Langmuir模型方程,最大饱和吸附量Qmax分别为263.15、256.41和250 mg/g,吸附自由能△G298 K分别为-10.632、-3.783和-2.805 kJ/mol;该条件下K-2BP、KN-B和KN-R的动力学吸附规律均符合准一级动力学吸附方程。等温吸附研究和吸附动力学研究均表明,相同条件下3种活性染料在该型活性炭上的吸附效果由高到低的顺序为:K-2BP>KN-B>KN-R。     

Day-to-Day Particulate Exposures and Health Changes in Los Angeles Area Residents with Severe Lung Disease

ABSTRACT

We measured particulate matter (PM_2.5 and PM₁₀) exposures, home temperature, arterial blood oxygen saturation, blood pressure, and lung function in 30 volunteer Los Angeles area residents during four-day intervals. Continuous Holter electrocardiograms were recorded in a subgroup on the first two days. Subjects recorded symptoms and time-activity patterns in diaries during monitoring, and during a reference period one week earlier/later. All subjects had severe chronic obstructive pulmonary disease. PM₁₀ (24-hr mean) at monitoring stations near subjects’ homes averaged 33 μg/m³, and ranged from 9 to 84 μpg/m³. In longitudinal analyses, day-to-day changes in PM_2.5 and PM₁₀ outside subjects’ homes significantly tracked concurrent station PM10 (r² = 0.22 and 0.44, respectively). Indoor and personal concentrations were less related to station readings (r² ≤ 0.1), but tracked each other (r² ≥ 0.4). In-home temperatures tracked outdoor temperatures more for lows (r² = 0.27) than for highs (r² = 0.10). These longitudinal relationships of subject-oriented and station PM measurements were generally similar to cross-sectional relationships observed previously in similar subjects. Among health measurements, only blood pressure showed reasonably consistent unfavorable longitudinal associations with particulates, more with station or outdoor PM than with indoor or personal PM.     

云南普洱地区中学生认知与响应地震灾害特点的初步研究——以2007宁洱6.4级地震灾害为例

2007年云南宁洱6.4级地震发生4个月后,以该次地震不同烈度区内的4所中学的学生为调查对象,借助问卷调查的方式分析了当地中学生在认知与响应地震灾害方面的一些特点,得出了以下初步结论:年级越高的学生对地震灾害知识的掌握情况越好.地震烈度越高的地区,学生目前对地震灾害知识的认知程度越高,对问卷中震时和震后表现的回答越积极、合理.对地震灾害的认知和响应没有明显的性别差异,民族差异只在灾时自救互救行为方面较为明显.学生的认知程度与其响应行为具有较为显著的正相关性,即认知程度好则响应行为更加积极、合理.媒体和学校教育共同构成了当地学生认知地震灾害及学习基本减灾技能的两大主要途径.在此基础上提出了一些加强对该地区中学生进行针对性减灾教育的建议.     

Theoretical study on the degradation reaction of octachlorinated dibenzo-p-dioxin with atomic oxygen O(3P) in dielectric barrier discharge reactor

Dielectric barrier discharges （DBD） have been used in the degradation of dioxins due to the large number of excimers and free radicals produced in discharge process. In this article, the density functional theory （DFT） is used to study the degradation mechanism of octachlorinated dibenzo-p-dioxin （OCDD） with the atomic oxygen O（3P） in DBD reactor. The reactants, intermediates, transition states and products are optimized at the MPWB1K/6- 31 ＋ G（d,p） level. The vibrational frequencies have been calculated at the same level. The reaction pathways and mechanisms are analyzed in detail. The effect of removing the chlorine atom on environment also has been discussed.