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41.
Lakshmipathi Naik. Gomathi Devi Gantigaiah Krishnamurthy 《Journal of environmental science and health. Part. B》2013,48(7):553-561
Photocatalytic degradation of the herbicide, pendimethalin (PM) was investigated with BaTiO3/TiO2 UV light system in the presence of peroxide and persulphate species in aqueous medium. The nanoparticles of BaTiO3 and TiO2 were obtained by gel to crystallite conversion method. These photo catalysts are characterized by energy dispersive x-ray analysis (EDX), scanning electron microscope (SEM), x-ray diffraction (XRD), and Brunauer-Emmett-Teller (BET) adsorption isotherm and reflectance spectral studies. The quantum yields for TiO2 and BaTiO3 for the degradation reactions are 3.166 Einstein m?2 s?1 and 2.729 Einstein m?2 s?1 and catalytic efficiencies are 6.0444 × 10?7 mg?2h?1L2 and 5.403 × 10?7 mg?2h?1L2, respectively as calculated from experimental results. BaTiO3 exhibited comparable photocatalytic efficiency in the degradation of pendimethalin as the most widely used TiO2 photocatalyst. The persulphate played an important role in enhancing the rate of degradation of pendimethalin when compared to hydrogen peroxide. The degradation process of pendimethalin followed the first-order kinetics and it is in agreement with Langmuir-Hinshelwood model of surface mechanism. The reason for high stability of pendimethalin for UV-degradation even in the presence of catalyst and oxidizing agents were explored. The higher rate of degradation was observed in alkaline medium at pH 11. The degradation process was monitored by spectroscopic techniques such as ultra violet-visible (UV-Vis), infrared (IR) and gas chromatography mass spectroscopy (GC-MS). The major intermediate products identified were: N-propyl-2-nitro-6-amino-3, 4-xylidine, (2, 3-dimethyl-5-nitro-6-hydroxy amine) phenol and N-Propyl-3, 4-dimethyl-2, 6-dinitroaniline by GC-MS analysis and the probable reaction mechanism has been proposed based on these products. 相似文献
42.
J. Jai Devi Tarun Gupta Rajmal Jat S. N. Tripathi 《Environmental science and pollution research international》2013,20(3):1632-1648
Personal exposure measurement can serve as an effective tool to understand the effect of exposure to air pollutants. Alternatively, exposure assessment using pollutant concentrations in different microenvironments and accurate time–activity information for the subjects can provide good information regarding human integrated exposure. A panel of 18 healthy students of Indian Institute of Technology (IIT) Kanpur in the age group of 18 to 30 years participated in the personal exposure measurements for particulate matter, CO, NO2 and VOC during post-monsoon and pre-monsoon seasons. Overall, 432 h person exposure data was collected in this study. The major sources of particulate and gaseous co-pollutants were identified. These directly obtained personal exposure values were then compared to the indirectly estimated integrated exposure values. Personal and integrated exposures gave statistically similar results. Through this study, we have shown that integrated exposure values could closely estimate the personal exposure values for particulate matter that can significantly reduce time and cost involved in personal exposure studies. The lung parameters for all the subjects measured during the pre-monsoon and post-monsoon seasons showed statistically significant reduction during pre-monsoon. This was attributed to the high levels of coarse particles during pre-monsoon. 相似文献
43.
Sharma KK Dubey JK Deka SC Chandrasekaran S Kalpana Gupta P Kumar A Vandana Devi MJ Singh B Baruah AA Kennedy JS Sharma ID Patyal SK Nath A 《Chemosphere》2007,68(4):790-796
Spiromesifen (Oberon) is a new insecticide and miticide of chemical class ketoenol active against white flies (Bemisia spp., Trialeuroides spp.) and spider mites (Tetranychus and Panonychus spp.). Due to its potential significance in insect resistance management, it is important to establish its behaviour on crop and environment. In the present study, the degradation/dissipation of spiromesifen on tea crop under tropical environmental conditions was studied and its DT(50) (t(1/2)), and DT(90) (time to reduce to 90% of the initial value) were estimated. Spiromesifen was sprayed on tea crop after first rain flush at four different locations @ 96 and 192ga.i.ha(-1). Samples of tea leaves were drawn at 0, 1, 3, 5, 7, 10, 15, 21 and 30 days after treatment and that of soil at 10 days after treatment and at harvest from 0 to 15 and 15 to 30cm layers. After crude extraction of tea leaves for spiromesifen residues with acetone:water, the contents were partitioned with cyclohexane:ethyl acetate and cleaned up on Florosil column. Soil residues were also extracted similarly. Quantification of residues was done on GC-MS in Selected Ion Monitoring (SIM) mode in mass range 271-274m/z. The LOQ of this method was found to be 0.05microgg(-1) while LOD being 0.015microgg(-1). The DT(50) of spiromesifen when applied at recommended doses in tea leaves was found to be 5.0-8.5 days. Ninety-nine percent degradation was found to occur within 33-57 days after application. In soil, no residues of spiromesifen were detectable 10 days after treatment. 相似文献
44.
The present study was carried out to evaluate the in vitro antioxidant properties and protective effects of silymarin (milk thistle) in human erythrocyte haemolysates against benzo(a)pyrene [B(a)P], a potent carcinogenic chemical. Protective effect of silymarin was assessed in vitro by monitoring the antioxidant enzymes and malondialdehyde in three groups of haemolysates-(I) vehicle control (II) B(a)P incubated group and (III) B(a)P co incubated with silymarin. The effects of silymarin on lipid peroxidation (LPO) and antioxidant enzymes [superoxide dismutase; SOD, catalase; CAT, glutathione peroxidase; GPx, glutathione reductase; GR and glutathione-S-transferases; GST] were assessed on haemolysates. It was observed that specific activity of antioxidant enzymes were significantly decreased and the malondialdehyde levels were elevated when haemolysates were incubated with B(a)P. The protective effect of silymarin is elucidated by the significant reversal of the antioxidant enzymes and reduction in the levels of malondialdehyde. In addition, haemolysates were incubated with B(a)P for 45 min and the B(a)P metabolite, 3-hydroxy benzo(a)pyrene (3-OH-B(a)P) was detected using HPLC. An increased level of the metabolite was detected in group II. Whereas, when haemolysates were co-incubated with silymarin, the reactive metabolite 3-OH-B(a)P was not detectable which further confirms the protective role of silymarin. Generation of 3-OH-B(a)P in group II implicates the possibility of reactive oxygen species (O2- and H2O2) production in haemolysates during cytochrome P4501A1 (CYP1A1) mediated Phase-I-metabolism. Hence, we incubated the haemolysates with exogenous reactive oxygen species H2O2 and assessed the protective role of silymarin against H2O2. From the results of our study, it was suggested that silymarin possess substantial protective effect and free radical scavenging mechanism against environmental contaminants induced oxidative stress damages. 相似文献
45.
Satyavathi Chinni Ritindra N. Khan V. Uma Devi Prabhakara Rao Yallaprgada 《Chemistry and Ecology》2013,29(3):157-170
Lead tolerance in Penaeus indicus post-larvae (PL) was studied in relation to the water variables: salinity, temperature and pH. the LC50 for 96 hrs was 7.22 ppm at ambient conditions of salinity (20%o), temperature (29°C) and pH (7.2). the post-larvae were found to be sensitive to salinity variations with a significant (P < 0.05) low LC50 values at lower (2%o) and higher (29%o) ranges. Though a decrease in LC50 value was observed both at higher (45°C) and lower (10°C) temperatures, it was significantly (P < 0.05) low only at higher temperature indicating more toxicity. the LC50 values also showed a significant (P < 0.05) decrease in acidic (pH 2.8) and alkaline (pH 11.0) conditions. the data indicate that lead toxicity increases in the PL of P. indicus with variations in the water variables. 相似文献
46.
Toby J. Hibbitts Martin J. Whiting Devi M. Stuart-Fox 《Behavioral ecology and sociobiology》2007,61(8):1169-1176
Many species possess multiple sexually dimorphic traits, which incorporate different sensory modalities (e.g., acoustic, olfactory
and visual), although their relative roles in sexual selection and in determining reproductive success are still poorly understood
for most taxa. We assessed the role of multiple male traits, including one acoustic (dominant call frequency) and one visual
(yellow throat patch) trait, in residency advertisement, contest behavior, and breeding success in barking geckos (Ptenopus garrulus garrulus). We show that male barking geckos maintain largely exclusive home ranges, with a trend for larger males to maintain larger
home ranges. We also show that larger males have a lower dominant calling frequency. When aggressive behavior was elicited
in the field using a recorded call of average frequency, resident males with low frequency calls were more likely to respond
aggressively and charge the speaker compared to males with high frequency calls. However, body size and small relative throat
patch size, rather than call frequency, were the best predictors of overall aggressiveness. Body size was also the best predictor
of whether males bred. We suggest that call frequency in this crepuscular species constitutes an effective long-range signal
of body size, used by males for remote rival assessment and to advertise home range boundaries in low-light environments. 相似文献
47.
M.S. Abbassy H.Z. Ibrahim MM. Abu El‐Amayem 《Journal of environmental science and health. Part. B》2013,48(2):255-267
Abstract A study was conducted from summer 1995 to summer 1997 to assess the seasonal occurrence of pesticide residues and other organic contaminants, polychlorinated biphenyls (PCBs), in water at the estuaries of Rosetta and Damiatta branches of the Nile river. The results indicated that organochlorine compounds (OCs) including HCB, lindane, p,p‘‐DDE, p,p‘DDD, p,p‘‐DDT, aroclor 1254 and aroclor 1260 were present in all the water samples at concentration levels ranging between 0.195–0.240, 0.286–0.352, 0.035–0.067, 0.019–0.033, 0.024–0.031, 0.390–0.70 and 0.166–0.330 μg/l, respectively. The levels of these compounds were higher in water of Damiatta branch than those found in water of Rosetta branch. Aldrin, dieldrin and endrin were not detected in all water samples. Only 4 compounds from 36 organophosphorus insecticides, fungicides and s‐triazine herbicides tested were detected in water samples collected during summer and autumn seasons from Rosetta branch. The concentration levels of these detected compounds, dimethoate, malathion, captan, and ametryne, ranged from 0.011 to 0.340 μg/l, respectively. Similar compounds during the same seasons as found in water of Rosetta branch were also detected in water of Damiatta branch except ametryne. The levels of the detected compounds (dimethoate, malathion and captan) ranged between 0.030 and 0.330 μg/l. The levels of detected organophosphorus insecticides, fungicides and s‐triazine herbicides were in the order: dimethoate > malathion > captan > ametryne. 相似文献
48.
49.
Recreation and Radial Growth of Pine Forests of the Natural Monument “Lake Turgoyak”, Southern Urals
Kukarskih V. V. Devi N. M. Bubnov M. O. Agafonov L. I. 《Russian Journal of Ecology》2022,53(3):169-180
Russian Journal of Ecology - The study presents results of the influence of recreational impact on the radial growth of Scots pine (Pinus sylvestris L.) in old-growth stands at the sites with the V... 相似文献
50.
Suren N. Kulshreshtha Devi D. Tewari 《Journal of the American Water Resources Association》1991,27(2):227-236
ABSTRACT: Water abundance has led most North American societies to use water freely without priorizing its use. As water scarcity becomes reality in the southern part of Saskatchewan, planners and managers of water require information about the value of water in irrigation, as well as in alternative uses. In this study, the value of water to the producer in irrigation is developed both for the short and long run. The basis of this imputation is a derived demand function for water using linear programming. Water demand was bound to be inelastic at lower prices, and highly elastic at higher prices. The short-run value of water varied between $0.44 and $127.82 (1986 dollars) per acre-foot for different levels of product prices. However, the long-run value was estimated between zero and $1.59 per acre-foot of water. 相似文献