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61.
R. Skinner P. Ineson W. K. Hicks H. E. Jones D. Sleep I. D. Leith L. J. Sheppard 《Water, Air, & Soil Pollution: Focus》2005,4(6):219-228
A field ammonia (NH3) release experiment and open top chambers containing moorland monoliths continuously fumigated with NH3 or sprayed with NH4Cl were used to assess the potential for using δ15N values in determining the area of influence around a point NH3 emission source. δ15N values are being increasingly used as environmental tracers and we tested the hypothesis that the δ15N signal from an NH3 emission source is observable in nearby vegetation. Using modified monitoring devices, atmospheric NH3 concentrations were found to decrease with distance from source, with δ15N values also reflecting this trend, producing a signal shift with changing concentration. Open top chamber studies of δ15N values of Calluna vulgaris (L.) Hull indicated a correlation with deposition treatments in current year shoots. Analysis of Calluna shoots from the NH3 release showed a similar trend of δ15N enrichment. Significant linear correlations between δ15N and percent N in plant material were found, both in the controlled conditions of the open top chambers and at the NH3 release site, illustrating the possible use of this technique in N deposition biomonitoring. 相似文献
62.
Zinc adsorption equilibria were measured in soils differing in pH but with similar textures and total zinc concentrations, using adsorption isotherm and isotopic exchange techniques. The results suggested that the equilibrium between solution and exchangeable zinc was strongly pH dependent and the active zinc species in adsorption was single charged (e.g. Zn(OH)(+)). The size of the exchangeable zinc pool was not strongly pH dependent. Similar results were obtained when zinc was added to the soils, either as Zn(NO(3))(2) or in sewage sludge. 相似文献
63.
The optimized BCR sequential extraction procedure (proposed by the Standards, Measurements and Testing Programme (SM&T) of
the European Union) was applied to seven topsoil samples from refuse dump sites for the determination of Cu, Zn, Ni, Pb and
Cd. The metals were partitioned into four operationally defined chemical fractions: acid extractable, reducible, oxidizable
and residual, and analysed using flame atomic absorption spectrophotometry, FAAS.
The results were compared with total metal concentrations obtained using HNO3, HClO4 and HF digestion procedures. Results for total metal analysis ranged from - 15.55 to 43.45 for Cu, 37.15 to 222.35 for Zn,
5.15 to 12.10 for Ni, 10.30 to 93.05 for Pb and 0.35 to 3.75 for Cd in μgg−1 dry weight. The results of the partitioning study showed that zinc prevailed in the more soluble fractions and was distributed
between the acid-extractable (32.4%) and the reducible (40.3%) fractions, whereas Pb was distributed mainly in the reducible
fraction. Copper and nickel were predominantly associated with the reducible and residual fractions - 53.4, 33.3 and 51.1,
24.1% respectively. The ranking of the four fractions for the partitioning of cadmium was: reducible > residual > oxidizable
> acid extractable. The percentage recovery for all metals when comparing total metal concentration with the fractional sum
of the optimized BCR procedure, were of the order: Zn(93%) > Pb(83%) > Cu(78) > Cd > (68%) > Ni(63%). 相似文献
64.
Performance of a low cost MBT prior to landfilling: study of the biological treatment of size reduced MSW without mechanical sorting 总被引:3,自引:0,他引:3
In France, the interest in Mechanical Biological Treatment (MBT) prior to landfilling is actually growing. In the absence of acceptance criteria for the waste to be landfilled, an alternative to the intensive, high-technology MBT can only find its place in the French context if it shows substantial benefits from an environmental, economic or operational point of view. This paper presents an experiment of low-cost MBT of size reduced MSW without material splitting. The performance of an experimental, pilot-scale mechanical and biological treatment process has been studied on 37.5 Mg of raw municipal solid waste. The mechanical process has been kept simple with only coarse shredding and no material recovery. The biological treatment, which was a low-cost forced aeration process, was monitored for 25 weeks. The biogas production potential of the waste was reduced by 90% to 19 NL kgDM(-1). The initial AT4 index of 82.9 mg O2 gDM(-1) decreased to 16.0 mg O2 gDM(-1). After 25 weeks of aerobic treatment, the dry mass loss reached 37%, while the mass of waste going to landfill was reduced by 28%. The average performances of the process were explained by the biological process itself, which was not optimal, and also by the characteristics of the input waste. The high particle size of the treated waste and the high content of slowly biodegradable matter (such as paper and cardboard) may both be significant drawbacks for the biological stabilisation of waste. 相似文献
65.
In August 2000 high concentrations of the dominant herbivorous copepod Calanus hyperboreus were detected in the Arctic Fram Strait, west of Spitsbergen, 1 m above the seafloor at 2,290 m water depth. Individuals from that layer were sampled by a hyper-benthic net attached to the frame of an epi-benthic sledge. For comparison, the vertical distribution of C. hyperboreus in the water column was studied simultaneously by a multiple opening/closing net haul from 2,250 m depth to the surface. Maximum abundance was found close to the surface with 6.6 and 10.0 ind. m?3 at 0–50 m and 50–100 m depth, respectively. However, the major fraction of the population (>40%) occurred between 1,000 and 1,500 m depth. In the deepest layer (2,000–2,250 m) abundance measured 2.2 ind. m?3 and was twice as high as between 100 and 1,000 m depth. In comparison to individuals from surface waters, copepods from the hyper-benthic layer were torpid and did not react to mechanical stimuli. Stage CV copepodids and females from the deep sample contained 4–10% less lipid and showed significantly reduced respiration rates of 0.24 and 0.26 ml O2 h?1 g?1 dry mass (DM) as compared to surface samples (0.49 and 0.43 ml O2 h?1 g?1 DM). All these observations indicate that the hyper-benthic part of the population had already started a dormant overwintering phase at great depth. Based on the lipid deposits and energy demands, the potential maximum duration of the non-feeding dormant phase was estimated at 76–110 days for females and at 98–137 days for CV copepodids, depending on what indispensable minimum lipid content was assumed. In any case, the estimated times could not meet the necessary requirements for a starvation period of >6 months until the next phytoplankton bloom in the following spring. The ecological implications of these results are discussed with respect to the life cycle and eco-physiological adaptations of C. hyperboreus to its high-Arctic habitat. 相似文献
66.
The use of colloid-enhanced ultrafiltration for boron removal from water is investigated. Biodegradable surfactant, 1,4-sorbitol
oleate, was applied to obtain micelles and high molecular weight chitosan to reinforce their stability. Two kind of membranes
were compared: neat porous polysulfone membrane and charged porous sulfonated polysylfone membrane; both with similar average
pore diameter of 5 nm. The studies revealed that two key factors affect the boron rejection: presence of surfactant in the
colloidal mixture and a repulsion effect of sulfone groups on the membrane surface. Both have a positive effect on boron
removal. 相似文献
67.
68.
Fluoride and health hazards: community perception in a fluorotic area of central Rajasthan (India): an arid environment 总被引:1,自引:0,他引:1
India is among the 23 nations around the globe where health problems occur due to excess ingestion of fluoride (>1.5 mg/l) by drinking water. In Rajasthan, 18 out of 32 districts are fluorotic and 11 million of the populations are at risk. An exploratory qualitative survey was conducted to describe perception of the community regarding fluoride and related health problems in Central Rajasthan. A study on distribution and health hazards by fluoride contaminate in groundwater was performed in 1,030 villages of Bhilwara district of Central Rajasthan. One thousand thirty water samples were collected and analyzed for fluoride concentration. Fluoride concentration in these villages varies from 0.2 to 13.0 mg/l. Seven hundred fifty-six (73.4%) villages have fluoride concentration above 1.0 mg/l. Sixty (5.83%) villages have fluoride concentration above 5.0 mg/l with maximum numbers (24, 19.5%) from Shahpura tehsil. A detailed fluorosis study was carried out in 41 villages out of 60 villages having fluoride above 5.0 mg/l in the study age, sex, and occupation data were also collected. Four thousand, two hundred fifty-two individuals above 5 years age were examined for the evidence of dental fluorosis, while 1998 individuals above 21 years were examined for the evidence of skeletal fluorosis. The overall prevalence of dental and skeletal fluorosis was found to be 3,270/4,252 (76.9%) and 949/1,998 (47.5%), respectively. Maximum of 23.9% (1,016) individuals have mild grade of Dean’s classification. Three hundred seventy-four (8.8%) individuals have severe type of dental fluorosis. The Dean’s Community Fluorosis Index for the studied area in total is 1.62. Maximum CFI 3.0 was recorded from Surajpura of Banera Tehsil. Five hundred sixty-six (28.3%) individuals have Grade I type of skeletal fluorosis while only 0.6% (12) individuals have Grade III skeletal fluorosis. In conclusion, the prevalence and severity of fluorosis increased with increasing fluoride concentration. It was interesting to note that in some villages, the prevalence and severity of fluorosis were highest in subjects belonging to the economically poor community. Similarly, male laborers showed highest prevalence of fluorosis. Prevalence and severity of fluorosis were observed higher in subjects using tobacco, bettle nuts, and alcoholic drinks. In contrast, subjects using citrus fruits and having good nutritional status showed low prevalence. 相似文献
69.
Polycyclic aromatic hydrocarbons in the bulk precipitation and surface waters of Northern Greece 总被引:15,自引:0,他引:15
Bulk (wet and dry) precipitation and surface water sampling was undertaken in the main plain of central Macedonia in Northern Greece. Fourteen polycyclic aromatic hydrocarbons (PAHs) included in the US EPA's priority pollutant list were analysed. The concentrations determined in bulk precipitation were in general within the range of values worldwide reported. Concentrations were highest in the cold months. Deposition fluxes of PAHs were of the same order of magnitude as reported data. The greatest values were found when high concentrations of PAHs in precipitation coincided with large precipitation amounts. The concentrations of PAHs in surface waters (main rivers, tributaries, ditches, etc) were in general lower than those in bulk precipitation, and among the lowest reported for European rivers, excepting Np and Ph. Bulk deposition and domestic effluents are suggested as being the main PAH sources into surface waters. 相似文献
70.
Means to improve the effect of in situ bioremediation of contaminated soil: an overview of novel approaches 总被引:16,自引:0,他引:16
Romantschuk M Sarand I Petänen T Peltola R Jonsson-Vihanne M Koivula T Yrjälä K Haahtela K 《Environmental pollution (Barking, Essex : 1987)》2000,107(2):179-185
Different aspects of bacterial degradation of organic contaminants in soil, and how to improve the efficiency and reproducibility is discussed in this review. Although bioremediation in principle includes the use of any type of organism in improving the condition of a contaminated site, most commonly bacteria are the degraders and other organisms, such as soil animals or plant roots, play a role in dissemination of bacteria and, indirectly, plasmids between bacteria, and in providing nutrients and co-substrates for the bacteria active in the degradation process. There are a number of different procedures that have been tested more-or-less successfully in attempts to improve reliability, cost efficiency and speed of bioremediation. The methods range from minimal intervention, such as mere monitoring of intrinsic bioremediation, through in situ introduction of nutrients and/or bacterial inocula or improvement of physico-chemical conditions, all the way to excavation followed by on site or ex situ composting in its different varieties. In the past the rule has been that more intervention (leading to higher costs) has been more reliable, but novel ideas are continuously tried out, both as a means to come up with new truly functional applications and also as a line of studies in basic soil microbial ecology. Both approaches generate valuable information needed when predicting outcome of remediation activities, evaluating environmental risks, deciding on cleaning-up approaches, etc. The emphasis of this review is to discuss some of the novel methods for which the value has not been clearly shown, but that in our view merit continued studies and efforts to make them work, separately or in combination. 相似文献