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251.
Čizmić Mirta Babić Sandra Kaštelan-Macan Marija 《Environmental science and pollution research international》2017,24(25):20521-20539
Environmental Science and Pollution Research - In this work, a multi-class analytical method for determination of 22 frequently used pharmaceuticals was developed and validated. Analytes were from... 相似文献
252.
Forecasting the Probability of Future Groundwater Levels Declining Below Specified Low Thresholds in the Conterminous U.S.
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Robert W. Dudley Glenn A. Hodgkins Jesse E. Dickinson 《Journal of the American Water Resources Association》2017,53(6):1424-1436
We present a logistic regression approach for forecasting the probability of future groundwater levels declining or maintaining below specific groundwater‐level thresholds. We tested our approach on 102 groundwater wells in different climatic regions and aquifers of the United States that are part of the U.S. Geological Survey Groundwater Climate Response Network. We evaluated the importance of current groundwater levels, precipitation, streamflow, seasonal variability, Palmer Drought Severity Index, and atmosphere/ocean indices for developing the logistic regression equations. Several diagnostics of model fit were used to evaluate the regression equations, including testing of autocorrelation of residuals, goodness‐of‐fit metrics, and bootstrap validation testing. The probabilistic predictions were most successful at wells with high persistence (low month‐to‐month variability) in their groundwater records and at wells where the groundwater level remained below the defined low threshold for sustained periods (generally three months or longer). The model fit was weakest at wells with strong seasonal variability in levels and with shorter duration low‐threshold events. We identified challenges in deriving probabilistic‐forecasting models and possible approaches for addressing those challenges. 相似文献
253.
Sandra Fatorić Ricard Morén-Alegret Rhiannon Jane Niven George Tan 《The Environmentalist》2017,37(3):276-288
Climate change impacts are no longer just a future issue for communities in the Mediterranean climate regions. This comparative study offers insights on climate change risk perceptions and attitudes among environmental, economic and social stakeholders in coastal areas in northeastern Spain and South Australia, as well as compares interviewed stakeholders’ risk perceptions with available documentary data and participant observation. Using a community risk assessment approach, the results show that some stakeholders perceive that climate change is already and/or may further continue to affect their employment, mostly in a predominantly negative way. Interestingly, some other interviewed stakeholders consider that climate change creates opportunities through new and additional areas of work. The findings also suggest that climate change may influence relocation of coastal residential populations in both case studies, which is likely to be an acceptable option among the stakeholders. This acceptance can be linked to the fact that in both areas there is a significant percentage of resident population with migrant background. This study calls for a need to understand better the personal experience of climate change in industrialized countries, as well as to consider coastal relocation in the integrated coastal planning and other territorial and population policies. 相似文献
254.
Timothy J. Barrett Sandra M. Brasfield Leslie C. Carroll Meghan A. Doyle Michael R. van den Heuvel Kelly R. Munkittrick 《Environmental monitoring and assessment》2015,187(5):305
Small-bodied fishes are more commonly being used in environmental effects monitoring (EEM) studies. There is a lack of understanding of the biological characteristics of many small-bodied species, which hinders study designs for monitoring studies. For example, 72 % of fish population surveys in Canada’s EEM program for pulp and paper mills that used small-bodied fishes were conducted outside of the reproductive period of the species. This resulted in an inadequate assessment of the EEM program’s primary effect endpoint (reproduction) for these studies. The present study examined seasonal changes in liver size, gonad size, and condition in seven freshwater and estuarine small-bodied fishes in Atlantic Canada. These data were used to examine differences in reproductive strategies and patterns of energy storage among species. Female gonadal recrudescence in all seven species began primarily in the 2-month period in the spring before spawning. Male gonadal development was concurrent with females in five species; however, gonadal recrudescence began in the fall in male three-spined stickleback (Gasterosteus aculeatus) and slimy sculpin (Cottus cognatus). The spawning period for each species was estimated from the decline in relative ovary size after its seasonal maximum value in spring. The duration of the spawning period reflected the reproductive strategy (single vs multiple spawning) of the species. Optimal sampling periods to assess reproductive impacts in each species were determined based on seasonal changes in ovary size and were identified to be during the prespawning period when gonads are developing and variability in relative gonad size is at a minimum. 相似文献
255.
Sofia Thorsson Björn Holmer Andreas Andjelic Jenny Lindén Sandra Cimerman Lars Barregard 《Environmental monitoring and assessment》2014,186(7):4479-4492
A majority of households in developing countries rely on biomass fuel for cooking, typically burned in open fires or simple stoves. The incomplete combustion of these fuels causes adverse health effects such as respiratory diseases, especially among women and children. However, quantitative data on pollution levels and on associated diseases are limited. We examined cooking habits and self-reported health in 31 households with outdoor open wood fires in Ouagadougou, Burkina Faso, using structured interviews. In eight households, carbon monoxide (CO) was measured using passive sampling. In addition, meteorology and ambient CO concentrations were assessed. The average CO concentration during cooking was 4.3 ppm, with a maximum of 65.3 ppm and minimum of 0.3 ppm (1-min values). A clear daily pattern was observed, with relatively low concentrations during the day and high during the evening, occasionally exceeding the World Health Organization 1- and 8-h guidelines when the air stabilised. On average, CO concentrations were 43 % higher in kitchens located in closed yards than in those located in open yards, showing that fireplace location affected the levels. Eye irritation and coughing among women and children were reported by 30 % of the households. Based on previously reported relations between CO concentrations and fine particles (<2.5 μm), the exposure to biomass smoke appears to be high enough to pose a considerable health risk among women and children in households with outdoor open wood fires. The results suggest that burning should be limited between sunset and dawn and in areas with limited ventilation to reduce pollutions levels. 相似文献
256.
257.
Edward R. Long R. Scott Carr James M. Biedenbach Sandra Weakland Valerie Partridge Margaret Dutch 《Environmental monitoring and assessment》2013,185(1):755-775
Data from toxicity tests of the pore water extracted from Puget Sound sediments were compiled from surveys conducted from 1997 to 2009. Tests were performed on 664 samples collected throughout all of the eight monitoring regions in the Sound, an area encompassing 2,294.1 km2. Tests were performed with the gametes of the Pacific purple sea urchin, Strongylocentrotus purpuratus, to measure percent fertilization success as an indicator of relative sediment quality. Data were evaluated to determine the incidence, degree of response, geographic patterns, spatial extent, and temporal changes in toxicity. This is the first survey of this kind and magnitude in Puget Sound. In the initial round of surveys of the eight regions, 40 of 381 samples were toxic for an incidence of 10.5 %. Stations classified as toxic represented an estimated total of 107.1 km2, equivalent to 4.7 % of the total area. Percent sea urchin fertilization ranged from >100 % of the nontoxic, negative controls to 0 %. Toxicity was most prevalent and pervasive in the industrialized harbors and lowest in the deep basins. Conditions were intermediate in deep-water passages, urban bays, and rural bays. A second round of testing in four regions and three selected urban bays was completed 5–10 years following the first round. The incidence and spatial extent of toxicity decreased in two of the regions and two of the bays and increased in the other two regions and the third bay; however, only the latter change was statistically significant. Both the incidence and spatial extent of toxicity were lower in the Sound than in most other US estuaries and marine bays. 相似文献
258.
Analysis of the Structure-Properties Relationships of Different Multiphase Systems Based on Plasticized Poly(Lactic Acid) 总被引:2,自引:0,他引:2
Cécile Courgneau Sandra Domenek Alain Guinault Luc Avérous Violette Ducruet 《Journal of Polymers and the Environment》2011,19(2):362-371
Poly(lactic acid) is one of the most promising biobased and biodegradable polymers for food packaging, an application which
requires good mechanical and barrier properties. In order to improve the mechanical properties, in particular the flexibility,
PLA plasticization is required. However, plasticization induces generally a decrease in the barrier properties. Acetyl tributyl
citrate (ATBC) and poly(ethylene glycol) 300 (PEG), highly recommended as plasticizers for PLA, were added up to 17 wt% in
P(D,L)LA. In the case of PEG, a phase separation was observed for plasticizer contents higher than 5 wt%. Contrary to PEG,
the Tg decrease due to ATBC addition, modelled with Fox’s law, and the absence of phase separation, up to 17 wt% of plasticizer,
confirm the miscibility of PLA and ATBC. Contents equal or higher than 13 wt% of ATBC yielded a substantial improvement of
the elongation at break, becoming higher than 300%. The effect of PLA plasticization on the barrier properties was assessed
by different molecules, with increasing interaction with the formulated material, such as helium, an inert gas, and oxygen
and water vapour. In comparison to the neat sample, barrier properties against helium were maintained when PLA was plasticized
with up to 17 wt% of ATBC. The oxygen permeability coefficient and the water vapour transmission rate doubled for mixtures
with 17 wt% ATBC in PLA, but increased five-fold in the PEG plasticized samples. This result is most likely caused by increased
solubility of oxygen and water in the PEG phase due to their mutual miscibility. To conclude, ATBC increases efficiently the
elongation at break of PLA while maintaining the permeability coefficient of helium and keeping the barrier properties against
oxygen and water vapour in the same order of magnitude. 相似文献
259.
Foster WG Gregorovich S Morrison KM Atkinson SA Kubwabo C Stewart B Teo K 《Chemosphere》2011,84(10):1301-1309
Polybrominated diphenyl ethers (PBDEs), widely used as flame retardants in commercial products, have become ubiquitous environmental contaminants. Although adult human exposure to PBDEs is well documented, developmental exposure is less well characterized. The objectives of this study were to measure maternal and fetal exposure to nine PBDE congeners and to investigate potential associations with birth weight. PBDE congeners were quantified in maternal serum at 24-28 weeks of pregnancy, delivery, and umbilical cord serum (UCS) by gas chromatography-mass spectrometry (GC/MS/MS). Complete blood sample sets were obtained from 97 pregnant women (mean age 33.1 ± 0.5 years). PBDE-28, -47 and -99 were quantified in all samples tested and PBDE-47 was the most abundant congener measured in both maternal (mid-pregnancy and delivery samples geometric mean = 26.9 and 26.9, respectively) and UCS (GM = 56.0 ng g−1 lipid). The UCS concentration for all congeners with the exception of PBDE-153 was higher vs. maternal delivery samples (p < 0.001). Only the UCS concentration of PBDE-17 and -99 were significantly associated (β = −49.860, p = 0.032, and β = −3.645, p = 0.05) with birth weight. However, after adjustment for potential confounders only the association between PBDE-99 and birth weight remained significant (β = −3.951 and p = 0.016). We conclude that: the fetus is exposed to PBDEs from at least the second trimester of pregnancy onward; PBDE congeners are higher in UCS compared to maternal serum samples collected at delivery; and that developmental PBDE exposure is potentially associated with lower birth weight. 相似文献
260.
Leat EH Bourgeon S Borgå K Strøm H Hanssen SA Gabrielsen GW Petersen A Olafsdottir K Magnusdottir E Fisk AT Ellis S Bustnes JO Furness RW 《Environmental pollution (Barking, Essex : 1987)》2011,159(5):1222-1228
Concentrations of POPs in Great skua eggs from Shetland are among the highest in North Atlantic seabirds, with up to 11,600 μg/kg (ww) DDE and up to 17,900 μg/kg ww ∑PCB. Concentrations of legacy POPs were significantly lower in 2008 than 1980. Decreases were greatest for least persistent compounds. Median ∑PBDEs increased from 99 μg/kg ww in 1980 to 173 μg/kg ww in 2008. There were changes in Great skua breeding season diet, with more adult Herring and Mackerel and less Sandeel. These changes increase exposure to POPs, since Herring and Mackerel accumulate more POPs than Sandeels. In both years, eggs with higher δ15N had higher POP concentrations. In 1980, birds feeding more on demersal discard fish from trawl fisheries and less on Sandeels, had higher POP levels in eggs. In 2008, individuals feeding more on Herring and Mackerel, and less on discards, had higher POP levels in eggs. 相似文献