Sorption of polycyclic aromatic compounds to humic and fulvic acid HPLC column materials

Two different humic acids (HA) and a fulvic acid (FA) were chemically immobilized to a high performance liquid chromatography (HPLC) silica column material. The immobilization was performed by binding amino groups in HA/FA to the free aldehyde group in glutardialdehyde attached to the silica gel. The HPLC column materials were compared with a blank column material made by applying the same procedure but without immobilizing HA or FA. Also, a column was made by binding carbonyl groups in HA to amino groups attached to the silica gel. The humic substances were selected to secure appropriate variation of their structural features. The retention factors of 45 polycyclic aromatic compounds (PAC) to the four columns were determined by HPLC. The advantage of the technique is a large number of compounds can easily be studied. The binding procedure does not appear to cause a drastic selection between the HA molecules. The k' values obtained for the two Aldrich HA columns agree in general reasonably. The retention or sorption of the compounds increased with the size of the PAC and the number of lipophilic substituents, but decreased when polar substituents were present. The PAC retention was much stronger to the two HA columns than to the FA and blank column, both for hydrophobic polycyclic aromatic hydrocarbons (PAH) and the polar PAC. Other factors impacting the PAC binding may be specific interactions with HA and the ionic strength of the aqueous phase. The technique has been applied to do direct determinations of Koc.     

Heavy metal anomalies in lagoon sediments related to intensive agriculture in Altata-Ensenada del Pabellón coastal system (SE Gulf of California)

Heavy metal concentrations were examined in surface sediments from 79 sites within the Altata-Ensenada del Pabellon lagoon system. Data were normalized to separate natural from anthropogenic factors using aluminum and lithium as conservative elements and following two different discriminating criteria. For the normalization process, the natural metal concentrations were assumed to vary consistently with aluminum and lithium, unless the metal contents were of human origin. Strong linear correlations (P < .001) were observed between the conservative elements and the metals measured. According to Szefer's normalizing criteria, about 90% of the polluted sites, for at least one metal, occurred near agricultural discharge drains. In accordance with the Muller [Umschau 79 (1979) 778.] scale, this lagoon system is subject to pollutant effects only with regard to Pb (moderately to strongly polluted). It was concluded that either Al and Li could be useful to normalize granulometric variability in heavy metal studies of these lagoon sediments, and that Summers' normalization criterion proved more rigorous than Szefer's for these types of sediments.     

Lightning Fires in a Brazilian Savanna National Park: Rethinking Management Strategies

Fire occurrences and their sources were monitored in Emas National Park, Brazil (17°49′–18°28′S; 52°39′–53°10′W) from June 1995 to May 1999. The extent of burned area and weather conditions were registered. Forty-five fires were recorded and mapped on a GIS during this study. Four fires occurred in the dry winter season (June–August; 7,942 ha burned), all caused by humans; 10 fires occurred in the seasonally transitional months (May and September) (33,386 ha burned); 31 fires occurred in the wet season, of which 30 were caused by lightning inside the park (29,326 ha burned), and one started outside the park (866 ha burned). Wet season lightning fires started in the open vegetation (wet field or grassy savanna) at a flat plateau, an area that showed significantly higher fire incidence. On average, winter fires burned larger areas and spread more quickly, compared to lightning fires, and fire suppression was necessary to extinguish them. Most lightning fires were patchy and extinguished primarily by rain. Lightning fires in the wet season, previously considered unimportant episodes, were shown to be very frequent and probably represent the natural fire pattern in the region. Lightning fires should be regarded as ecologically beneficial, as they create natural barriers to the spread of winter fires. The present fire management in the park is based on the burning of preventive firebreaks in the dry season and exclusion of any other fire. This policy does not take advantage of the beneficial effects of the natural fire regime and may in fact reduce biodiversity. The results presented here stress the need for reevaluating present policies and management procedures concerning fire in cerrado conservation areas.     

对铁碳处理硝基酚废水的研究

铁碳降解水中难降解有机污染物的影响因素、最佳工艺参数及处理效果;初步探讨了氧化降解污染物的作用机理;通过分析污染物降解的中间产物,提出了污染物降解的可能途径.探讨了pH、铁碳用量、温度以及锰矿物的粒径等对处理效果的影响,在最佳的工艺条件下,CODCr的去除率达到95%以上,TOC测定表明：大部分硝基酚被氧化降解为H2O和CO2.对硝基酚的降解途径主要是微电解将对硝基酚还原为对氨基酚,对氨基酚在酸性条件下被软锰矿氧化为H2O和CO2做探索性研究.     

金沙江水电资源梯级开发及其经济发展研究

金沙江流域是我国13大水电基地中水能资源蕴涵量最大的地区，但开发率相对较低。在介绍金沙江流域丰富的水电资源及其开发现状的基础上，分析了加快金沙江水电开发的可能条件和重要意义；针对开发中存在的主要问题，根据市场经济原则和具体情况提出了对策和建议。     

巢湖流域蒸发量特征及变化趋势研究

巢湖作为安徽省境内的一个重要湖泊，对安徽省生态环境起到一定的影响作用。蒸发量是影响生态环境的重要因子，在很多方面是该区生态环境的一个反映。采用了统计学方法，对巢湖流域15个蒸发点20年（1981-2000年）的资料进行了分析，初步探讨了巢湖流域的蒸发量空间分布特征与地势、气温、风速、降水量等因子的关系，以及蒸发量在1年内的变化特征和年际变化趋势，试图说明研究时段内人类活动对区域蒸发量的影响。研究表明，由于地形等因素的影响，巢湖流域的蒸发量空间分布不均衡，在研究时段内蒸发量大体呈上升趋势。     

Pilot‐scale evaluation using bioaugmentation to enhance PCE dissolution at dover AFB national test site

An Interstate Technology and Regulatory Council (ITRC) forum was recently held that focused on six case studies in which bioremediation of dense nonaqueous‐phase liquids (DNAPLs) was performed; the objective was to demonstrate that there is credible evidence for bioremediation as a viable environmental remediation technology. The first two case studies from the forum have been previously published; this third case study involves a pilot‐scale demonstration that investigated the effects of biological activity on enhancing dissolution of an emplaced tetrachloroethene (PCE) DNAPL source. It used a controlled‐release test cell with PCE as the primary DNAPL in a porous media groundwater system. Both laboratory tests and a field‐scale pilot test demonstrated that bioaugmentation can stimulate complete dechlorination to a nontoxic end product and that the mass flux from a source zone increases when biological dehalorespiration activity is enhanced through nutrient (electron donor) addition and bioaugmentation. All project goals were met. Important achievements include demonstrating the ability to degrade a PCE DNAPL source to ethene and obtaining significant information on the impacts to the microbial populations and corresponding isotope enrichments during biodegradation of a source area. © 2007 Wiley Periodicals, Inc.     

减灾事业的发展和综合减灾

中国减灾事业的发展史可分3个阶段:第一阶段是新中国成立以前的几千年,减灾活动以赈灾为主,帝王“祭天求恕”,“防灾吏制”,安抚于民。清末民初1800至1949年间计发生巨灾25起,死亡4993万余人,总灾亡则近亿,年均灾亡60万人以上,这段惨痛的灾况记下了十分难得的灾情史,泣血于残野。新中国成立后,在“为人民服务”的思想指导下,为减轻灾害损失,逐步建立了气象、水利、农林、地震、海洋、地质等专业的灾害科技与减灾工程,政府并组织社会兼事抗灾、救灾、应急减灾,国家减灾实力快速增长,已取得突出减灾实效,这个阶段比第一阶段灾亡人数下降了90%以上,但年均灾亡人口仍有1.2万人左右。该阶段的工作特点是以单灾种纵向体系为主,不同灾类的监测、预报水平尚高低不一,这与成灾机理的难易程度和工作条件的强弱有关。21世纪初,随全球增温之势锐升,多类极端灾变遍及各洲,促使许多国家发动全社会人众共同探求“综合减灾”之路;我国政府已迅即开展全社会应急减灾行动,开启了“综合减灾”之先声,这是减灾事业步入第三阶段的先导。综合减灾应该是全社会相关部门和民众的统一行动。目前尚有3个问题需要弄清楚,一是多种自然灾害之间成灾机理相关性的研究,其对象是灾害群与灾害链;二是全社会减灾要素综合运作预案的优选;三是如何核算减灾投入与社会可持续发展之正、负效应关系。     

印度夏季风降水周期性研究

印度夏季风降水(ISMR)在南亚气候系统中是一个非常重要的内容,近年来对它的研究日益受到人们的重视。为了深入认识ISMR的变化特征,主要利用Scargle周期图和小波变换研究了1871-2004年间ISMR变化的周期性。结果表明,ISMR的周期性波动非常复杂,相应的周期参数具有明显的时变特征。文中还简单讨论了ISMR周期时变的可能原因。     

基于WSR的国有高新技术企业安全分析模型

针对我国国有高新技术企业在发展中面临的困难,指出对其安全问题研究,是一项复杂的系统工程。基于系统分析的WSR(物理-事理-人理)理论和方法,对影响高新技术企业的安全因素进行较为全面的分析,构建了国有高新技术企业安全因素WSR分析模型,为高新技术企业安全运营问题的系统研究提出了新的思路。