Arsenic speciation in polychaetes (Annelida) and sediments from the intertidal mudflat of Sundarban mangrove wetland, India

This paper documents the concentration of total arsenic and individual arsenic species in four soft-bottom benthic polychaetes (Perenereis cultifera, Ganganereis sootai, Lumbrinereis notocirrata and Dendronereis arborifera) along with host sediments from Sundarban mangrove wetland, India. An additional six sites were considered exclusively for surface sediments for this purpose. Polychaetes were collected along with the host sediments and measured for their total arsenic content using inductively coupled plasma mass spectrometry. Arsenic concentrations in polychaete body tissues varied greatly, suggesting species-specific characteristics and inherent peculiarities in arsenic metabolism. Arsenic was generally present in polychaetes as arsenate (As^V ranges from 0.16 to 0.50 mg kg^?1) or arsenite (As^III ranges from 0.10 to 0.41 mg kg^?1) (30–53 % as inorganic As) and dimethylarsinic acid (DMA^V <1–25 %). Arsenobetaine (AB < 16 %), and PO₄-arsenoriboside (8–48 %) were also detected as minor constituents, whilst monomethylarsonic acid (MA^V) was not detected in any of the polychaetes. The highest total As (14.7 mg kg^?1 dry wt) was observed in the polychaete D. arborifera collected from the vicinity of a sewage outfall in which the majority of As was present as an uncharacterised compound (10.3 mg kg^?1 dry wt) eluted prior to AB. Host sediments ranged from 2.5 to 10.4 mg kg^?1 of total As. This work supports the importance of speciation analysis of As, because of the ubiquitous occurrence of this metalloid in the environment, and its variable toxicity depending on chemical form. It is also the first work to report the composition of As species in polychaetes from the Indian Sundarban wetlands.     

Role of arbuscular mycorrhizal fungi on the performance of floodplain Phragmites japonica under nutrient stress condition

A pot experiment was conducted to evaluate the potential effects of arbuscular mycorrhizal fungi (AMF) on growth, nutrient uptake, and inoculation effectiveness on Phragmites japonica. Spores of AMF strains (Gigaspora margarita Becker &; Hall) were collected from the commercial product ‘Serakinkon’. Four treatments, namely, natural soil (NS), natural soil inoculated by AM fungi, sterilised soil (SS) inoculated by AM fungi, and SS without AM fungi inoculation were selected to determine the effects of applied and indigenous AMF on P. japonica. The average colonisation level of P. japonica was 24–33%, whereas no colonisation was found in the SS. AMF colonisation increased the chlorophyll content (r?=?0.84, p?r?=?0.89, p?相似文献   

Bioaccumulation of heavy metals in flora and fauna of Hooghly estuary,east coast of India

Spectroscopic determinations of Fe, Zn, Mn, Cu, Co and Ni were carried out in 23 organisms including seaweeds, zooplankters, molluscs and fishes from Hooghly estuary at the confluence of Bay of Bengal. Seaweeds and gastropods were more efficient in accumulating levels while zooplankters bivalves and fishes showed intermediate levels. Analyses were performed on the sediment, water and on the individual dissected organs of a mussel, oyster and teleost fish. Bioaccumulation of Fe, Zn, Mn and Cu in the soft body parts (gills, mantle, liver etc.) of the three species showed a high degree of organ specificity in some cases. Major sources of the micropollutants include natural weathering, catchment runoff, urban and industrial discharges that may pose an ecological risk to the local estuarine ecosystem.     

Variations of bed elevations due to turbulence around submerged cylinder in sand beds

This paper presents the spatio-temporal variations in bed elevations and the near-bed turbulence statistics over the deformed bed generated around the submerged cylindrical piers embedded vertically on loose sediment bed at a constant flow discharge. Experiments were carried out in a laboratory flume for three blockage ratios in the range of 0.04–0.06 using three different sizes of submerged cylinders individually placed vertically at the centerline of the flume. Clear-water experimental conditions were maintained over the smooth sediment bed surface with a constant flow discharge (\(Q = 0.015\,{\rm m}^3/{\rm sec}\)), thereby giving three different cylinder Reynolds numbers \(Re_{D_c} = \frac{U_mD_c}{\nu }\) (=10200, 12750, 15300) away from the cylinder locations, where \(U_m\) is the maximum mean velocity, \(D_c\) is the cylinder diameter and \(\nu\) is the kinematic viscosity of fluid. Instantaneous sand bed elevations around the cylinders were recorded using a SeaTek 5MHz ultrasonic ranging system of net 24 transducers to estimate bed form migration, and the near-bed velocity data at transducer locations over the stable deformed bed around the pier-like structures were collected using down-looking three-dimensional (3D) Micro-acoustic Doppler velocimeter to estimate the bottom Reynolds shear stresses and the contributions of bursting events to the dominant shear stress component. The flow perturbation generated due to relatively lower flow blockage ratio favored to achieve the stable bed condition more rapidly than the others, and larger upstream scour-depth and deformed areas were noticed for greater flow blockage ratio due to larger cylinder diameter. For larger blockage ratio in the upstream of scour-hole near the bed, occurrences of probabilities of both boundary-ward interactions (Q1 and Q3) were the dominant; whereas in the downstream of the scoured region, occurrences of probabilities of second and third quadrant events (Q2 and Q4) were dominant. On the other hand, for the lower blockage ratio, quadrant (Q2) was dominant over Q4 in the downstream of scour-hole, and in the upstream of scour-hole, quadrant Q4 was the dominant.     

Encapsulation of bioactive compounds using nanoemulsions

Roughly one-third of the food produced in the world for human consumption every year, approximately 1.3 billion tonnes, gets lost or wasted, according to the Food and Agriculture Organization (FAO). There is therefore an urgent need for new methods to preserve food. Encapsulation using nanoemulsions is a powerful technique for the protection of food-grade ingredients including vitamins, lipids, antioxidants and antimicrobial agents. In general, nanoemulsion systems demonstrate superior characteristics over conventional emulsions. This is due to their smaller droplet size, transparent optical properties, higher physical stability against droplet destabilization factors and improved bioavailability of the entrapped active ingredients. In general, nanoemulsions have been prepared with different sizes of droplets. However, a droplet size higher than 200 nm is generally preferred for food applications. Here we review nanoemulsion compositions, types of active ingredients, applications in different types of food systems, toxicological and safety aspects, and future directions.     

Odour from municipal solid waste (MSW) landfills: a study on the analysis of perception

The objective of this work was to develop a relationship between odour intensity and odour concentration by using data collected from various sensitive areas of the municipal solid waste (MSW) landfill site. A number of well-known psychophysical models (e.g., Weber-Fechner law, Steven's power law, Beidler's and Laffort's models) have been discussed that can successfully relate the perceived intensity with the odour concentration. Respective parameters for each of the models were estimated by the nonlinear Levenburg-Marquardt parameter estimation method. The overall performance of the model was tested statistically against sets of data from the olfactometry analysis. The model based on the Weber-Fechner law was ranked 1 in case of five out of nine samples and it has been found more representative of the less intense odour samples. The model based on Laffort's equation has represented the intensity-concentration relationship better with extremely low uncertainties on both parameters k1 and k2 for comparatively more intense odour samples.     

Optimization of process parameters using response surface methodology for bioconversion of activated sludge by Penicillium corylophilum

The optimization of process parameters for the bioconversion of activated sludge by Penicillium corylophilum was investigated using response surface methodology （RSM）. The three parameters namely temperature of 33℃, agitation of 150 r/min, and pH of 5 were chosen as center point from the previous study of fungal treatment. The experimental data on chemical oxygen demand （COD） removal （%） were fitted into a quadratic polynomial model using multiple regression analysis. The optimum process conditions were determined by analyzing response surface three-dimensional surface plot and contour plot and by solving the regression model equation with Design Expert software. Box-Behnken design technique under RSM was used to optimize their interactions, which showed that an incubation temperature of 32.5℃, agitation of 105 r/min, and pH of 5.5 were the best conditions. Under these conditions, the maximum predicted yield of COD removal was 98.43%. These optimum conditions were used to evaluate the trail experiment, and the maximum yield of COD removal was recorded as 98.5%.     

Quantification of Extinction Risk: IUCN's System for Classifying Threatened Species

Abstract: The International Union for Conservation of Nature (IUCN) Red List of Threatened Species was increasingly used during the 1980s to assess the conservation status of species for policy and planning purposes. This use stimulated the development of a new set of quantitative criteria for listing species in the categories of threat: critically endangered, endangered, and vulnerable. These criteria, which were intended to be applicable to all species except microorganisms, were part of a broader system for classifying threatened species and were fully implemented by IUCN in 2000. The system and the criteria have been widely used by conservation practitioners and scientists and now underpin one indicator being used to assess the Convention on Biological Diversity 2010 biodiversity target. We describe the process and the technical background to the IUCN Red List system. The criteria refer to fundamental biological processes underlying population decline and extinction. But given major differences between species, the threatening processes affecting them, and the paucity of knowledge relating to most species, the IUCN system had to be both broad and flexible to be applicable to the majority of described species. The system was designed to measure the symptoms of extinction risk, and uses 5 independent criteria relating to aspects of population loss and decline of range size. A species is assigned to a threat category if it meets the quantitative threshold for at least one criterion. The criteria and the accompanying rules and guidelines used by IUCN are intended to increase the consistency, transparency, and validity of its categorization system, but it necessitates some compromises that affect the applicability of the system and the species lists that result. In particular, choices were made over the assessment of uncertainty, poorly known species, depleted species, population decline, restricted ranges, and rarity; all of these affect the way red lists should be viewed and used. Processes related to priority setting and the development of national red lists need to take account of some assumptions in the formulation of the criteria.