全文获取类型
收费全文 | 11379篇 |
免费 | 79篇 |
国内免费 | 86篇 |
专业分类
安全科学 | 283篇 |
废物处理 | 500篇 |
环保管理 | 1430篇 |
综合类 | 2479篇 |
基础理论 | 2563篇 |
环境理论 | 5篇 |
污染及防治 | 2980篇 |
评价与监测 | 687篇 |
社会与环境 | 562篇 |
灾害及防治 | 55篇 |
出版年
2022年 | 90篇 |
2021年 | 96篇 |
2019年 | 70篇 |
2018年 | 149篇 |
2017年 | 130篇 |
2016年 | 223篇 |
2015年 | 173篇 |
2014年 | 244篇 |
2013年 | 821篇 |
2012年 | 305篇 |
2011年 | 429篇 |
2010年 | 345篇 |
2009年 | 405篇 |
2008年 | 433篇 |
2007年 | 494篇 |
2006年 | 431篇 |
2005年 | 354篇 |
2004年 | 368篇 |
2003年 | 374篇 |
2002年 | 332篇 |
2001年 | 428篇 |
2000年 | 313篇 |
1999年 | 205篇 |
1998年 | 116篇 |
1997年 | 124篇 |
1996年 | 109篇 |
1995年 | 154篇 |
1994年 | 148篇 |
1993年 | 123篇 |
1992年 | 130篇 |
1991年 | 149篇 |
1990年 | 119篇 |
1989年 | 127篇 |
1988年 | 132篇 |
1987年 | 114篇 |
1986年 | 83篇 |
1985年 | 100篇 |
1984年 | 124篇 |
1983年 | 126篇 |
1982年 | 124篇 |
1981年 | 97篇 |
1980年 | 93篇 |
1979年 | 106篇 |
1978年 | 89篇 |
1977年 | 84篇 |
1976年 | 78篇 |
1975年 | 90篇 |
1974年 | 101篇 |
1967年 | 69篇 |
1965年 | 74篇 |
排序方式: 共有10000条查询结果,搜索用时 609 毫秒
571.
Jeffrey R. Brook Tom F. Dann 《Journal of the Air & Waste Management Association (1995)》2013,63(2):193-199
ABSTRACT At a variety of Canadian monitoring sites, carbonaceous compounds were estimated to account for an average of 50% of fine particle mass. These estimates were determined by subtracting the total fine particle mass associated with inorganic compounds from the total fine mass determined gravimetrically. This approach, which yields an upper limit estimate of the total amount of carbon-related mass was necessary since particulate carbon was not measured in the Canadian National Air Pollution Surveillance (NAPS) network. In this paper, total carbon estimates are evaluated against organic and elemental carbon measurements at locations in the Greater Vancouver area and Toronto. In addition, particle nitrate measurements at seven Canadian locations are used to determine the importance of nitrate relative to total mass and to examine the sampling artifacts due to the loss of particle nitrate from Teflon filters used in the NAPS di-chotomous samplers. Measurements of organic and elemental carbon indicated that the total carbon estimation approach provides representative estimates of the average contribution by carbonaceous material to the total fine and coarse mass. The average total carbon among all Vancouver area measurements (N = 225) was 4.28 μg m-3, while the estimated value was 4.34 μg m-3. There was a larger discrepancy between Toronto total carbon measurements (12.1 μg m-3) and estimates (8.8 μg m-3), which is attributed in part to sampling of particles above 10 mm in diameter. However, the R2 relating the measurements and estimates was about 0.71 for both areas. Linear regression slopes of 0.98 for Vancouver and 0.78 for Toronto (nonsignificant intercepts) indicate little bias in the Vancouver estimates, but a tendency for underestimation as the observed total carbon concentration increased in Toronto. Annually, nitrate was responsible for 17% and 12% of the fine mass in the Vancouver area and Ontario, respectively. In contrast, at two rural locations in southern Quebec and Nova Scotia, only 6% of fine mass was associated with nitrate. Due to filter losses, nitrate concentrations determined through the NAPS dichot sampling were much lower than actual concentrations (0.44 μg m-3 vs. 2.63 μg m-3). As a result of these losses (attributed mostly to loss during laboratory storage), previous total carbon estimates for the Canadian NAPS sites were likely to have been overestimated on average by about 10%. 相似文献
572.
Jitendra A. Joshi John A. Hogan Robert M. Cowan Peter F. Strom Melvin S. Finstein 《Journal of the Air & Waste Management Association (1995)》2013,63(9):1647-1654
ABSTRACT Gaseous NH3 removal was studied in laboratory-scale biofilters (14-L reactor volume) containing perlite inoculated with a nitrifying enrichment culture. These biofilters received 6 L/min of airflow with inlet NH3 concentrations of 20 or 50 ppm, and removed more than 99.99% of the NH3 for the period of operation (101, 102 days). Comparison between an active reactor and an autoclaved control indicated that NH3 removal resulted from nitrification directly, as well as from enhanced absorption resulting from acidity produced by nitrification. Spatial distribution studies (20 ppm only) after 8 days of operation showed that nearly 95% of the NH3 could be accounted for in the lower 25% of the biofilter matrix, proximate to the port of entry. Periodic analysis of the biofilter material (20 and 50 ppm) showed accumulation of the nitrification product NO3 - early in the operation, but later both NO2 - and NO3 - accumulated. Additionally, the N-mass balance accountability dropped from near 100% early in the experiments to ~95 and 75% for the 20- and 50-ppm biofilters, respectively. A partial contributing factor to this drop in mass balance accountability was the production of NO and N2O, which were detected in the biofilter exhaust. 相似文献
573.
Gary F. Evans Ross V. Highsmith Linda S. Sheldon Jack C. Suggs Ronald W. Williams Roy B. Zweidinger 《Journal of the Air & Waste Management Association (1995)》2013,63(11):1887-1896
ABSTRACT Two collaborative studies have been conducted by the U.S. Environmental Protection Agency (EPA) National Exposure Research Laboratory (NERL) and National Health and Environmental Effects Research Laboratory to determine personal exposures and physiological responses to par-ticulate matter (PM) of elderly persons living in a retirement facility in Fresno, CA. Measurements of PM and other criteria air pollutants were made inside selected individual residences within the retirement facility and at a central outdoor site on the premises. In addition, personal PM exposure monitoring was conducted for a subset of the participants, and ambient PM monitoring data were available for comparison from the NERL PM research monitoring platform in central Fresno. Both a winter (February 1-28, 1999) and a spring (April 19-May 16, 1999) study were completed so that seasonal effects could be 相似文献
574.
Jon M. Heuss Dennis F. Kahlbaum George T. Wolff 《Journal of the Air & Waste Management Association (1995)》2013,63(7):772-788
Abstract A national analysis of weekday/weekend ozone (O3) differences demonstrates significant variation across the country. Weekend 1-hr or 8-hr maximum O3 varies from 15% lower than weekday levels to 30% higher. The weekend O3 increases are primarily found in and around large coastal cities in California and large cities in the Midwest and Northeast Corridor. Both the average and the 95th percentile of the daily 1-hr and 8-hr maxima exhibit the same general pattern. Many sites that have elevated O3 also have higher O3 on weekends even though traffic and O3 precursor levels are substantially reduced on weekends. Detailed studies of this phenomenon indicate that the primary cause of the higher O3 on weekends is the reduction in oxides of nitrogen (NOx) emissions on weekends in a volatile organic compound (VOC)-limited chemical regime. In contrast, the lower O3 on weekends in other locations is probably a result of NOx reductions in a NOx-limited regime. The NOx reduction explanation is supported by a wide range of ambient analyses and several photochemical modeling studies. Changes in the timing and location of emissions and meteorological factors play smaller roles in weekend O3 behavior. Weekday/weekend temperature differences do not explain the weekend effect but may modify it. 相似文献
575.
L.-W. Antony Chen Judith C. Chow Bruce G. Doddridge Russell R. Dickerson William F. Ryan Peter K. Mueller 《Journal of the Air & Waste Management Association (1995)》2013,63(8):946-956
Abstract Observations of the mass and chemical composition of particles less than 2.5 μm in aerodynamic diameter (PM2.5), light extinction, and meteorology in the urban Baltimore-Washington corridor during July 1999 and July 2000 are presented and analyzed to study summertime haze formation in the mid-Atlantic region. The mass fraction of ammoniated sulfate (SO4 2-) and carbonaceous material in PM2.5 were each ~50% for cleaner air (PM2.5 < 10 μg/m3) but changed to ~60% and ~20%, respectively, for more polluted air (PM2.5 > 30 μg/m3). This signifies the role of SO4 2- in haze formation. Comparisons of data from this study with the Interagency Monitoring of Protected Visual Environments network suggest that SO4 2? is more regional than carbonaceous material and originates in part from upwind source regions. The light extinction coefficient is well correlated to PM2.5 mass plus water associated with inorganic salt, leading to a mass extinction efficiency of 7.6 ± 1.7 m2/g for hydrated aerosol. The most serious haze episode occurring between July 15 and 19, 1999, was characterized by westerly transport and recirculation slowing removal of pollutants. At the peak of this episode, 1-hr PM2.5 concentration reached ~45 μg/m3, visual range dropped to ~5 km, and aerosol water likely contributed to ~40% of the light extinction coefficient. 相似文献
576.
D. Bruce Henschel Roy C. Fortmann Nancy F. Roache Xiaoyu Liu 《Journal of the Air & Waste Management Association (1995)》2013,63(5):708-717
ABSTRACT A laboratory thermal desorption apparatus was used to measure emissions from a number of nominally identical photocopier toners—manufactured to meet the specifications of one specific model copier—when these toners were heated to fuser temperature (180-200 °C). The objective was to assess how potential volatile organic compound (VOC) emissions from the toner for a given copier can vary, depending upon the production run and the supplier. Tests were performed on a series of toner (and associated raw polymer feedstock) samples obtained directly from a toner manufacturer, representing two production runs using a nonvented extrusion process, and on toner cartridges purchased from two local retailers, representing three different production lots (histories unknown). The results showed that the retailer toners consistently had up to 350% higher emissions of some major compounds (expressed as |ig of compound emit-ted/g of toner), and up to 100% lower emissions of others, relative to the manufacturer toners (p ≤ 0.01). The manufacturer toners from one production run had emissions of certain compounds, and of total VOCs, that were modestly higher (13-18%) than those from the other run (p ≤ 0.01). The emission differences between the retailer and manufacturer toners are probably due to differences 相似文献
577.
578.
Petreas M Nelson D Brown FR Goldberg D Hurley S Reynolds P 《Environment international》2011,37(1):190-197
We measured major PBDEs and PCBs in breast adipose tissues of California women participating in a breast cancer study in the late 1990s. Samples were analyzed using gas chromatography with electron impact ionization and tandem mass spectrometry detection. The congener profile observed was: BDE47>BDE99>BDE153>BDE100>BDE154 and PCB153>PCB180>PCB138>PCB118. Whereas high correlations were observed within each chemical class, very weak correlations appeared between classes, pointing to different exposure pathways. Weak negative associations were observed for PBDE congeners and age. Our PBDE data are among the highest reported, exceeding data from the National Health and Nutrition Examination Survey and consistent with the high use of PBDEs in California. These data may be helpful in establishing a baseline for PBDE body burdens to gauge changes over time as a result of restrictions in the use of PBDE formulations. 相似文献
579.
Thomas PJ Mineau P Shore RF Champoux L Martin PA Wilson LK Fitzgerald G Elliott JE 《Environment international》2011,37(5):914-920
Second-generation anticoagulant rodenticides (SGARs) are widely used to control rodent pests but exposure and poisonings occur in non-target species, such as birds of prey. Liver residues are often analysed to detect exposure in birds found dead but their use to assess toxicity of SGARs is problematic. We analysed published data on hepatic rodenticide residues and associated symptoms of anticoagulant poisoning from 270 birds of prey using logistic regression to estimate the probability of toxicosis associated with different liver SGAR residues. We also evaluated exposure to SGARs on a national level in Canada by analysing 196 livers from great horned owls (Bubo virginianus) and red-tailed hawks (Buteo jamaicensis) found dead at locations across the country. Analysis of a broader sample of raptor species from Quebec also helped define the taxonomic breadth of contamination. Calculated probability curves suggest significant species differences in sensitivity to SGARs and significant likelihood of toxicosis below previously suggested concentrations of concern (<0.1mg/kg). Analysis of birds from Quebec showed that a broad range of raptor species are exposed to SGARs, indicating that generalised terrestrial food chains could be contaminated in the vicinity of the sampled areas. Of the two species for which we had samples from across Canada, great horned owls are exposed to SGARs to a greater extent than red-tailed hawks and the liver residue levels were also higher. Using our probability estimates of effect, we estimate that a minimum of 11% of the sampled great horned owl population is at risk of being directly killed by SGARs. This is the first time the potential mortality impact of SGARs on a raptor population has been estimated. 相似文献
580.
The Syracuse, NY, AUDIT (Assessment of Urban Dwellings for Indoor Toxics) study was designed to quantify asthma agent levels in the inner-city homes of a birth cohort whose mothers had a diagnosis of asthma. Risk of exposure to particulate matter (PM), particle number and tobacco smoke was assessed in 103 infants' homes. Repeat measurements were made in 44% of the homes. Infants also were examined on a quarterly basis during the first year of life to monitor their respiratory health and urine cotinine levels. Overall geometric mean (GM) values for PM(2.5) of 21.2 μg/m(3) and for PM(10) of 31.8 μg/m(3) were recorded in homes at visit 1. GM values for PM(2.5) and PM(10) in smoking homes were higher at 26.3 and 37.7 μg/m(3), while values in non-smoking homes were 12.7 and 21.2 μg/m(3) respectively. Fifty-four percent of mothers (55/103) smoked at some point in pregnancy (39% smoked throughout pregnancy). Environmental tobacco smoke (ETS) exposure occurred in 68% of homes during the infants' first year. Significant to this study was the size- and time-resolved monitoring of PM at 140 home visits and the classification of PM count data. PM number counts ranged from continuously low levels (little indoor activity) to continuously high counts (constant indoor activity), and recorded apparent instances of prolonged repeated cigarette smoking. Wheezing in the first year of life was recorded for 38% of the infants (39/103). Adjusted logistic regression modeling demonstrated that elevated levels of indoor PM(2.5) (≥ 15 μg/m(3)) were a significant risk factor for infant wheezing after controlling for infant gender, mothers' age and education level, season of home visit and presence of carpeting (OR 4.21; 95% CI 1.36-13.03; p=0.013). An elevated level of the nicotine metabolite cotinine in infant urine also was associated with infant wheezing after adjusting for infant gender, mothers' age and education level (OR 5.10; 95% CI 0.96-27.24; p=0.057). ETS exposure was pervasive in the AUDIT cohort and a risk for developing infants in this urban population. 相似文献