18650型锂离子电池燃烧特性及火灾危险性评估

为评估18650型锂离子电池的火灾危险性,以3种不同品牌的商品三元18650型锂离子电池为研究对象,采用锥形量热仪在不同辐射热和荷电状态下对3种电池进行了燃烧试验,分析了电池的热释放参数、烟参数、毒性参数和质量损失参数。并在试验的基础上构建了锂离子电池火灾危险性综合评估指标体系,计算了这3种电池在辐射热35kW/m^2及品牌1的18650型锂离子电池在25 kW/m^2条件下的火灾危险指数。结果表明:电池的热参数和毒性参数随电池荷电状态(SOC)和辐射热增大而增大,满电状态下的品牌1电池在辐射热为50 kW/m^2、35 kW/m^2和25 kW/m^2时的热释放速率峰值分别为9.23 kW、8.64 kW和6.26 kW;生烟量随电池SOC和辐射热增大而减小;综合评估得出了3种电池的火灾危险性。     

海水对含水层沉积物中镭解吸的模拟实验

本研究采用莱州湾沿岸含水层中的沉积物,通过渗滤实验模拟镭的解吸过程。结果表明,在典型的地下水流速范围内(0.02~0.30 cm/min),镭同位素(223Ra、224Ra、226Ra)的解吸没有显著变化。在海水与淡水的混合过程中,解吸的镭比活度与水的盐度呈显著的线性正相关关系。当盐度超过海水盐度时(如S=80的卤水中),解吸的镭比活度则趋于最值平台。对比模拟估算的地下水中镭的比活度与莱州湾沿岸实测间隙水中镭的比活度,223Ra和224Ra的结果基本一致,而226Ra的实测结果较模拟估算结果偏小。可能由于含水层中226Ra经反复解吸后得不到母体核素及时补充所致。本研究将为更好地理解镭同位素在含水层中的地球化学行为提供科学依据,为合理地选择量化海底地下水排放(submarine groundwater discharge,SGD)模型的镭端元值提供新的参考视角。     

Co-composting of paper mill sludge and hardwood sawdust under two types of in-vessel processes

Recycling of organic residues by composting is becoming an acceptable practice in our society. Co-composting dewatered paper mill sludge (PMS) and hardwood sawdust, two readily available materials in Canada, was investigated using uncontrolled and controlled in-vessel processes. The composted materials were characterized for total C and N, water-soluble, acid-hydrolyzable, and non-hydrolyzable N, extractable lipids, and by Fourier Transform Infrared (FT-IR) spectrophotometry. In the controlled scale process, the loss of organic matter was approximately 65% higher than in the uncontrolled process. After undergoing initial fluctuations in N fractions during the first two days of composting, by the end of the process, concentrations of water-soluble N decreased while those of acid-hydrolyzable and nonhydrolyzable N increased in the controlled process, whereas in the uncontrolled process, water-soluble N increased, but N in the other two fractions decreased continuously, indicating that the biochemical transformations of organic matter were not completed. Data on extractable lipids and FT-IR spectra suggest that the compost produced from the controlled process was bio-stable after 14 days, while the uncontrolled process was not stabilized after 18 days. In addition, FT-IR data suggest the biological activity during composting centered mainly on the degradation of aliphatic structures while aromatic structures were preserved. The co-composting of the PMS and hardwood sawdust can be successfully achieved if aeration, moisture, and bio available C/N ratios are optimized to reduce losses of N.     

MS SQL SERVER复制技术在地震前兆数据集成中的应用

基于WINDOWS NT 网络操作系统的MS SQL SERVER复制环境，分析并探讨了SQL SERVER复制技术、 复制模块的参数设置及其在地震前兆数据集成中的应用。 通过实例说明了SQL SERVER复制技术在地震前兆数据集成中应用的可行性。 同时，对复制过程中常出现的事务日志空间问题进行了剖析，并提出了解决办法。 分析结果表明，应用SQL SERVER复制技术进行数据交换、 共享及应用是较为有效的，而且也是可行的。     

大气环境质量预测模型研究

为适应青岛和贵阳地区地形和大气流场复杂的特点,吸收高斯烟云模式和烟团模式的优点,建立高斯轨迹烟云模式,模式同时考虑静风条件下的扩散。应用青岛和贵阳的实测数据对模式的性能进行检验,结果证明,该模式可适用于地形和流场复杂的地区。该模式是环境决策支持系统的一部分。      

关键环境因子对海月水母浮浪幼虫附着变态的影响

海月水母的生活史包括底栖的螅状体世代和浮游的水母体世代。水母成体通过有性生殖释放精子和卵子,形成受精卵,受精卵随后经由浮浪幼虫变态发育成螅状体。浮浪幼虫经附着变态成为螅状体的阶段因在海底发生,不易观察,常被忽视。本文选取温度、盐度、光照3个关键环境因子,在实验室条件下开展了其对海月水母浮浪幼虫附着变态影响的研究。结果表明:（1）21 ℃为海月水母浮浪幼虫附着变态的最适宜温度,在此温度下浮浪幼虫附着所需时间最短（48 h）,温度过高（24 ℃）或者过低（12 ℃）都不利于浮浪幼虫附着;（2）在试验的盐度范围内（18～33）,盐度越低,浮浪幼虫附着率越高;（3）在试验所设置的光照范围内（0～300 Lux）,随着光强的增加,海月水母浮浪幼虫的附着率提高。本研究有助于人们了解海月水母的生活史,并为近岸水母暴发的防治提供数据参考。     

中国工业废水排放格局及其驱动因素

基于2005~2015年中国31个省（市、自治区）的环境统计数据,运用GIS空间分析方法和SARAR计量模型系统刻画了工业废水排放的时空格局演变与空间集聚特征,并进一步揭示其驱动因素及区域差异性。结果表明：（1）研究时段内,工业废水排放逐年减少,但废水排放总量不断上升,表明中国废水排放主导源已经发生替变;（2）中国工业废水排放量总体呈现“东南高、西北低”的省际格局特征,胡焕庸线可看作工业废水排放“热区”与“冷区”的分界线;（3）中国工业废水排放表现出明显的空间集聚特征,集聚趋势逐年加强;（4）SARAR模型估计结果显示,城镇化推进、第二产业发展、人口增长依次是中国工业废水排放的主要驱动因素。与全国相比,热区的SARAR模型估计结果与上述结论基本一致,但各驱动因素的影响效应略有不同     

Production of a refined biooil derived by fast pyrolysis of chicken manure with chemical and physical characteristics close to those of fossil fuels

The chemical and physical properties of raw biooils prevent their direct use in combustion engines. We processed raw pyrolytic biooil derived from chicken manure to yield a colorless refined biooil with diesel qualities. Chemical characterization of the refined biooil involved elemental and several spectroscopic analyses. The physical measurements employed were viscosity, density and heat of combustion. The elemental composition (% wt/wt) of the refined biooil was 82.7 % C, 15.3 % H, 0.2 % N and 1.8 % O, no S. Its viscosity was 0.006 Pa.s and a heat of combustion of 43 MJ kg^?1. The refined biooil fraction contains n-alkanes, ranging from n-C₁₄ to n-C₂₇, alkenes varying from C_10:1 to C_22:1, and long-chain alcohols. The refined biooil makes a good diesel fuel due to its chemical and physical properties.     

Separation and identification of heterocyclic nitrogen compounds in biooil derived by fast pyrolysis of chicken manure

N-heterocyclics were separated from a biooil, generated by the pyrolysis of chicken manures by column chromatography over neutral alumina and silica, and identified by Pyrolysis Field Ionization Mass Spectrometry (Py-FIMS) and Electrospray Ionization Mass Spectrometry (ESI-MS). Identities of chemical structures, whose presence was indicated by ESI-MS, were confirmed by comparing the Collision-Induced Dissociations (CID's) mass spectra of unknown and standards. The following seven base structures were identified: pyrazine, benzoquinoline, carbazole, phenylpyridine, indole, pyrazole and pyridine. Available hydrogens bonded to ring carbons and nitrogens on the seven N-heterocyclics were increasingly substituted by alkyl groups, mainly methylene groups (m/z 14) to yield mono-, di-, tri- methyl N-heterocyclics. In some instances, longer alkyl chains, such as ethyl, propyl, up to heptyl groups were the substituents.     

梦清园芦苇湿地根际微生物特性研究

本文通过对上海市梦清园芦苇湿地净化苏州河污染水体的示范工程采样分析，结果表明芦苇根际的微生物数量、酶的活性高于非根际的土壤。根际细菌、真菌和放线菌的数量均比非根际多，R／S平均值分别为70．3、9．5、2．9。相对于硝酸细菌而言亚硝酸细菌的根际效应较为明显，无论根际还是非根际的亚硝酸细菌数量均高于硝酸细菌的数量。根际细菌和硝化细菌数量随着水力停留时间增加而增加，而根际反硝化细菌数量则减少。菌剂和酶制剂的加入使得非根际泥样异养细菌、真菌、放线菌和亚硝酸细菌比对照组稍高，硝酸细菌和反硝化细菌则较少；而根际泥样中加菌剂和酶制剂组微生物数量比空白组高出1—2个数量级，在投加菌和酶制剂后酶活性无论在根际还是非根际都得到提高，高于对照组约5—6个酶活单位。