A contact sex pheromone component of the emerald ash borer Agrilus planipennis Fairmaire (Coleoptera: Buprestidae)

Analyses of the elytral hydrocarbons from male and female emerald ash borer, Agrilus planipennis Fairmaire, that were freshly emerged vs. sexually mature (>10 days old) revealed a female-specific compound, 9-methyl-pentacosane (9-Me-C₂₅), only present in sexually mature females. This material was synthesized by the Wittig reaction of 2-decanone with (n-hexadecyl)-triphenylphosphonium bromide followed by catalytic reduction to yield racemic 9-Me C₂₅, which matched the natural compound by gas chromatography/mass spectrometry (retention time and EI mass spectrum). In field bioassays with freeze-killed sexually mature A. planipennis females, feral males spent significantly more time in contact and attempting copulation with unwashed females than with females that had been washed in n-hexane to remove the cuticular lipids. Hexane-washed females to which 9-Me-C₂₅ had been reapplied elicited similar contact time and percentage of time attempting copulation as unwashed females, indicating that 9-methyl-pentacosane is a contact sex pheromone component of A. planipennis. This is the first contact sex pheromone identified in the Buprestidae.     

Common operations failure modes in the process industries

The Abnormal Situation Management^® (ASM^®) Consortium (This research study was sponsored by the Abnormal Situation Management (ASM) Consortium. ASM^® and Abnormal Situation Management^® are registered trademarks of Honeywell International, Inc.) funded a study to investigate common failure modes and root causes associated with operations practices. The study team analyzed 20 public and 12 private incident reports using the TapRoot^® methodology to identify root causes. These root causes were mapped to operations practice failures. This paper describes the top ten operations failure modes identified in the analysis. Specific recommendations include how to analyze plant incident reports to better understand the sources of systemic failures and improve plant operating practices.     

Use of inert C&D materials for seawall foundation: quality control measures

The technical viability of using inert construction and demolition (C&D) materials for the construction of seawall and breakwater foundations has been established by laboratory testing of the materials, numerical analysis of foundation stability, and a pilot field-scale engineering performance evaluation. However, quality control measures are still required so that only suitable materials are used for seawall and breakwater foundation construction. The development of different quality control measures for different site conditions is presented in this paper. The rationale, practicality, and implementation of these quality control measures are also discussed.     

Impact of the use of waste on trace element concentrations in cement and concrete.

The results of model calculations carried out to identify and quantify the input pathways of trace elements into cement and concrete and to estimate the extent to which trace element concentrations in cement may change due to waste utilization are presented. As expected, primary raw materials represented the most important input pathway for trace elements into cement, but the contribution from wastes was not negligible. The use of waste led to a slight increase of the concentrations of cadmium, antimony and zinc in cement. For cobalt, lead and vanadium, this increase was less distinct and for all other trace elements considered, the effect of the use of wastes on trace element concentrations in cement could not be demonstrated clearly. The trace element content of concrete was governed by the aggregates for most elements considered. However, for arsenic, cadmium, lead and zinc, both cement and the additive coal fly ash contributed noticeably to the total trace element concentration in the concrete.     

On the role of entropy in water quality modelling

The use of the entropy principle in phenomenological water quality models is not only necessary, but also of great advantage. A deterministic ecosystem model must obey the 2nd law of thermodynamics. Gibb's equation is a constraint additional to the balances of mass, energy and momentum. The entropy principle supports the unified treatment of physical, chemical and biological processes in water bodies, offers stability criteria and controls the further development of the aquatic ecosystems. Thermodynamic criteria also allow the determination of the bifurcation points of the model equations. Especially near these points the state and structure of the ecosystem can be strongly changed by fluctuations of the variables and parameters of the ecosystem.Results of the thermodynamic theory of selforganizing systems (Glansdorff and Prigogine, 1971; Nicolis and Prigogine, 1977) are of very great importance for water quality modelling. Furthermore, the entropy principle bridges the phenomenological, stochastic and cybernetic approaches to water quality modelling.While the paper deals with general aspects of the role of entropy in water quality modelling, the basic system of equations, taking the entropy principle into account, can be found in a previous paper (Mauersberger, 1978).