Hexavalent chromium is frequently found in industrial effluents as a result of the industrial applications of this compound and its anti-corrosive features. However, hexavalent chromium is extremely toxic, and its discharge in water is regulated, with a maximum limit of 0.1 mg/L in accordance with legislation established by CONAMA-Brazil (no. 397, April 3, 2008). To achieve lower discharge values, it is necessary to reduce from Cr(VI) to Cr(III), which is less toxic, and an economic alternative involves biological removal of this compound. Residence time distributions (RTDs) were measured to evaluate the behavior of actual biofilter operation conditions in a biofilter flow. The medium residence time distributions used were 8 and 24 h (recommended by the legislation). To optimize this process, a central composite design was used, considering the initial chromium concentration and pH as the independent variables and the removal of hexavalent chromium as the response. The boundary curves and surface response showed optimal behavior at 3.94 mg/L [Cr(0)] and a pH of 6.2. The removal process of hexavalent chromium is mathematically described by the Michaelis-Menten kinetic model. This model appropriately represents the variation of chromium concentration along the bioreactor. 相似文献
Gorgonian species may contribute to the three-dimensional seascape in soft bottom-gravel areas, but the information on their
biology and ecology is very scarce. The biometry and secondary production of the Mediterranean soft bottom-gravel passive
suspension feeder Leptogorgia sarmentosa (Cnidaria: Octocorallia) was studied using photographic monitoring of the primary branches from May 1998 to September 2000.
The primary branches observed had a high density of polyps (2.2 ± 0.2 SD polyps mm−1) and a high organic matter content (63.2 ± 9.1 SD %). During the two-year sampling period, there was a net negative growth
in 90% of the gorgonian population. The mean loss during the 27-month period was −2.9 ± 0.9 SD cm per branch (5.7 mg C branch−1). However, considering only the initial and final diameters and maximum height in the 27 months elapsed time, the gorgonians
showed positive growth, which meant that photographic sampling of single branches was a more appropriate method for gorgonian
secondary production monitoring. A water mass anomaly detected in 1999 in the north-western Mediterranean Sea may have been
the cause of the net negative growth in L. sarmentosa in the studied area. Partial mortality due to different factors, such as strong currents, predation, disease, etc., could
be a common strategy in sessile colonial benthic populations that would facilitate their maintenance even during very stressful
circumstances. 相似文献
A number of significant developments towards the management of psychosocial risks have been achieved at the policy level in the European Union (EU) since the introduction of the 1989 European Commission Council Framework Directive 89/391/EEC on Safety and Health of Workers at Work on which a new EU risk prevention culture has since been established, combining legislation, social dialogue, best practices and building partnerships. However, it has been widely acknowledged that initiatives aiming to promote workers’ health have not had the impact anticipated both by experts and policy makers and the main reason for this has been the gap that exists between policy and practice. This paper discusses the findings from the PRIMA-EF project, a policy-orientated project, which focussed on the development of a European framework for psychosocial risk management at the workplace. In particular, the paper presents the results of an EU stakeholder survey and interviews with EU policy level experts to assess their awareness, understanding and evaluation of the impact of policy initiatives for psychosocial risk management. 相似文献
Octocorals are an important part of many ecosystems as they add three-dimensional complexity to the benthos and thereby increase biodiversity. The Mediterranean red coral (Corallium rubrum, L. 1758) is a longevous octocoral that is harvested commercially, yet natural and anthropogenic influences on its population size structure are little understood. This study found that some harvested red coral populations had a significantly different size structure when compared to populations at the nearby Marine Protected Area (MPA) of Medas Islands at the Spanish Costa Brava (NW Mediterranean). Eighty-nine percent of the red corals in the harvested Costa Brava area are less than 10 years old and 96% of all colonies have not yet grown more than second-order branches. The size/age distribution of the harvested population is notably skewed towards younger and smaller colonies. Thus, although red coral is still abundant, its population structure is strongly distorted by harvesting. The results confirm that MPAs are useful to distinguish between anthropogenic and natural influences on population structure. However, 14 years of protection appears to be an insufficient recovery time for a longevous octocoral population such as red coral. 相似文献
Objective: The objective of this study was to obtain information about the current knowledge and habits of parents who transport children in cars in Brazil.
Methods: A cross-sectional survey was conducted using specifically designed self-report questionnaires to parents of children attending a private pediatric office in a town in southwest Brazil. Data were collected regarding children's age, gender, height, and weight and possession of an automobile child restraint system (CRS), its type, frequency and adequacy of use, and reasons for not possessing or not using the devices. Parents were asked whether their cars were equipped with airbags and about the use of the restraints in seats with airbags.
Results: We interviewed parents of 293 children transported in cars who met the criteria for use of a CRS. Children were younger than 1 year in 15.3% of the cases, between 1 and 4 years in 38.6%, and older than 4 in 46.1%. Cars were equipped with CRS in 78.5% of the cases, but in only 58% of the cases was the device proper for child's age and adequately installed in the seat. Among owners of the devices, 84.3% reported that they always used it. Reasons for infrequency were forgetting the device at home or in another car (6.4%), the child disliking the device (3.2%), or the false impression that the child was grown enough not to use it (3.2%)l 87.1% did not justify why they did not always use the CRS. Considering type of CRS, correct installation of the seat, and frequency of use, only 44.4% of children under 1 year, 69.9% of those 1 to 4 years, and 52.6% over age 4 were protected. Only 28.6% of the parents knew that children should never be positioned in a seat with active airbags.
Conclusion: Considering appropriateness for age, correctness of installation (in the back seat in the correct orientation), and frequency of use, only 50.85% (149/293) of the children were reported as always protected with a CRS. Children between 1 and 4 years were more likely to always use a CRS in this Brazilian survey. We were also able to identify an important gap in the knowledge about airbags among parents. Further efforts are needed to correct those distortions. 相似文献
In recent times, environmental safety has been on priority in the development of new materials leading to a recycling and
reuse approach to conserve the materials resources. This has resulted in more focus on the application of natural materials
such as lignocellulosic fibers. This paper presents the characterization of continuous and aligned jute fabrics obtained from
new and used sacks as well as the preparation and characterization of their composites incorporated into recycled polyethylene
or as isolated pieces up to 40 wt%. These environmentally friendly composites were subjected to bend test and the fracture
surface analyzed by SEM. The fabric from new sacks showed greater damage tolerance than that from the used sacks. The flexural
stress increased steadily with increasing used fabric content up to 30 wt%, which is explained using fractographic studies
on ruptured specimens. Used jute fabric composites are found to be viable alternative materials for low strength conventional
materials based on cost–performance comparison with conventional materials. 相似文献