Removal of the hazardous dye rhodamine B through photocatalytic and adsorption treatments

This paper reports on photocatalytic and adsorptive treatment of a hazardous xanthene dye, Rohdamine B, in wastewater. The photocatalytic degradation was carried out in the presence of the catalyst TiO(2) and the effects of pH, concentration of the dye, amount of TiO(2), temperature and electron acceptor H(2)O(2) on the degradation process were observed. It was found that photocatalytic degradation by TiO(2) is an effective, economical and faster mode of removing Rohdamine B from aqueous solutions. Attempts were also made to utilize activated carbon and rice husk as potential adsorbents to remove Rhodamine B from wastewater. The adsorption studies were carried out at 40, 50 and 60 degrees C, and the effects of pH, temperature, amount of adsorbents, concentration of adsorbate, etc., on the adsorption were measured. On the basis of adsorption data the Langmuir and Freundlich adsorption isotherm models were also confirmed. The adsorption isotherm constants thus obtained were employed to calculate thermodynamic parameters like Gibb's free energy, change in enthalpy and entropy. In order to observe the quality of wastewater COD measurements were also carried out before and after the treatments. A significant decrease in the COD values was observed, which clearly indicates that both photocatalytic and adsorption methods offer good potential to remove Rhodamine B from industrial effluents.     

Passive monitoring of nitrogen dioxide in urban air: a case study of Durban metropolis, South Africa

To devise and implement strategies to manage the quality of urban air, a metropolis needs air pollution data on which an air quality management plan can be formulated. Although air pollutants can come from several sources, many reports suggest that nitrogen dioxide from motor vehicle emissions is the major contributor to air pollution in cities. Since vehicles stop or move slowly through traffic intersections, concentrations of nitrogen dioxide (NO(2)) are expected to be relatively high at these sites. Inexpensive Ogawa passive samplers were placed at selected traffic intersections in the Durban Metropolis to trap the NO(2) which was then analysed by a sensitive laboratory-based method. The data obtained by this method was compared with data from sophisticated system comprising an active sampler cum on-line chemiluminescence detector. The sampling was done over a twelve month period to cover all seasons. Statistical analysis of the data showed that there was no significant difference between the means for the two methods. This study has established that an Ogawa passive sampler may be used as an economical and reliable collector for NO(2) in ambient air under varying climatic conditions. Further, the analysis method using a UV-Visible spectrophotometer was sensitive enough to detect NO(2) at the 10-20 ppb level. The cost of the method should be well within the budgets of most municipalities and it would motivate them to develop policies to alleviate traffic congestion.     

Assessment of bio-medical waste management in three apex government hospitals of Agra

Waste management practices in three apex government hospitals of Agra viz., Sarojini Naidu Medical College, Lady Lyall Maternity Hospital and District Hospital were studied during January 2004-January 2005. Data were collected with the help of (i) personal observations of the waste treatment and disposal practices and (ii) assessment of knowledge, attitude and practices of working personnel with the help of questionnaires. The results obtained indicated lack of knowledge and awareness regarding legislations on bio-medical waste management even among qualified hospital personnel. None of these hospitals were equipped with higher technological options e.g. incinerator autoclave, microwave and had no facilities to treat the liquid waste generated inside the hospital. It is concluded that generation and implementation of a waste management policy institutiona/organizational set up, training and motivation must be given paramount importance to meet the current needs and standards of bio-medical waste management in these hospitals.     

Nitrogen management in landfill leachate: Application of SHARON,ANAMMOX and combined SHARON–ANAMMOX process

In today’s context of waste management, landfilling of Municipal Solid Waste (MSW) is considered to be one of the standard practices worldwide. Leachate generated from municipal landfills has become a great threat to the surroundings as it contains high concentration of organics, ammonia and other toxic pollutants. Emphasis has to be placed on the removal of ammonia nitrogen in particular, derived from the nitrogen content of the MSW and it is a long term pollution problem in landfills which determines when the landfill can be considered stable. Several biological processes are available for the removal of ammonia but novel processes such as the Single Reactor System for High Activity Ammonia Removal over Nitrite (SHARON) and Anaerobic Ammonium Oxidation (ANAMMOX) process have great potential and several advantages over conventional processes. The combined SHARON–ANAMMOX process for municipal landfill leachate treatment is a new, innovative and significant approach that requires more research to identify and solve critical issues. This review addresses the operational parameters, microbiology, biochemistry and application of both the processes to remove ammonia from leachate.     

Assessment of the interactive effects of ambient O3 and NPK levels on two tropical mustard varieties (Brassica campestris L.) using open-top chambers

Rising O(3) concentrations in agricultural areas have been identified as a significant threat to crop production in Asia including India. The present work reports the results of a field study conducted to assess the usefulness of higher than recommended NPK dose in modifying the physiological, growth, yield, and seed quality responses of two mustard (Brassica campestris L. var. Vardan and Aashirwad) varieties under ambient ozone level at a rural site of India, using open-top chambers. Twelve hourly mean O(3) concentrations ranged between 27.7 and 59.04 ppb during the growth period. Plants in nonfiltered chambers (NFCs) showed reductions in photosynthetic rate, stomatal conductance, and growth parameters compared to the plants in filtered chambers (FCs), but reductions were of lower magnitude at 1.5 times recommended dose of NPK (1.5 RNPK) compared to recommended (RNPK). Yield and seed quality reduced significantly in plants of NFCs compared to FCs at RNPK, but no significant differences were recorded at 1.5 RNPK. There were higher N uptake and N uptake efficiency of plants in FCs compared to NFCs. Nitrogen utilization efficiency increased in Vardan, but decreased in Aashirwad in NFCs compared to FCs suggesting higher capability of N acquisition and utilization under ambient O(3), which led to a less pronounced reduction in the yield of the former than the latter variety. The differential nitrogen utilization efficiency in these varieties may be potentially used as measure of sensitivity characteristics in breeding programs for yield improvement in mustard under the present trend of increase in O(3) concentrations.     

Membrane technology for water purification

Managing higher water demands is a grand challenge of the twenty-first century due to pollution and climate change that are decreasing the amount of drinkable water. There is therefore a need for improved techniques to purify contaminated waters. Nanotechnology provides materials of unprecedented properties, which can be used to clean water. This article reviews recent developments in nanotechnology for wastewater treatment using novel polymeric membrane materials. The use of polymeric membrane materials and polymer brushes are discussed.     

Forest sustainability and development in hills of Uttarakhand,India: Can they move together?

Forest cover is viewed as a resource for the nation as it provides ecosystem services. However, it becomes a burden and retards development for the people of the area, particularly the hills, where such forests flourish. Enactment of stringent laws over the past few decades has strictly prohibited tree felling in these areas, and it has become a deterrent in their growth process. While on one hand, the plains are abuzz with economic activity, on the other hand, the sparse population of the hills is compelled to bear the responsibility of maintaining ecological balance. In this context, the issue of development along with forest sustainability becomes important. Using the case study of the hills of Uttarakhand, India, the paper attempts to highlight the problems and the possible strategies that may be adopted to facilitate inclusive socioeconomic development of forest dwellers while ensuring conservation and enhancement of forest cover.     

Effect of experimental parameters on photocatalytic degradation efficiency of TiO2 nanoparticles synthesized by electrochemical method towards Rhodamine B dye solution under natural sunlight

Environmental Science and Pollution Research - In this study,?~?40 nm anatase TiO2 nanoparticles were successfully prepared by a simple electrochemical method by using succinic...     

Application of a system dynamics approach for assessment and mitigation of CO2 emissions from the cement industry

A system dynamics model based on the dynamic interactions among a number of system components is developed to estimate CO(2) emissions from the cement industry in India. The CO(2) emissions are projected to reach 396.89 million tonnes by the year 2020 if the existing cement making technological options are followed. Policy options of population growth stabilisation, energy conservation and structural management in cement manufacturing processes are incorporated for developing the CO(2) mitigation scenarios. A 42% reduction in the CO(2) emissions can be achieved in the year 2020 based on an integrated mitigation scenario. Indirect CO(2) emissions from the transport of raw materials to the cement plants and finished product to market are also estimated.