试论矿山环评中的生态恢复评价问题

矿山生态恢复是矿山环保对策中的一项技术较强的措施之一，它既有防治水土流失的功能，又有降解有毒污染的功能，并能产生较好的经济效益。但没有科学依据而盲目进行生态恢复，就有可能对环境和人类带来风险，为减少风险，在矿山开发前的环境影响评价中，就应对生态恢复这一措施进行评价，提出合理的恢复模式，为决策部门提供科学依据。     

多沙大河的扩散示踪研究

污染物在水体中的扩散规律研究已引起越来越多人的关注。通过现场扩散示踪实验求得扩散系数，进而对污染物的扩散规律予以定量描述，是一种可靠易行的方法。对黄河托克托至河曲段的实际研究表明，以Ｃｒ２Ｏ或Ｆ－为示踪剂，运用Ｔａｙｌｏｒ模型进行多沙大河的污染物扩散规律研究可以取得满意的结果。同时，利用现场示踪实验结果与经验公式的结合可以预测不同情况下的纵向扩散系数，从而得出污染物的允许排放量，这将有利于污染物在水体中行为的深入研究。     

Odor compounds from different sources of landfill: characterization and source identification

This study investigated the odor compounds from different areas in a landfill site, which included the municipal solid waste (MSW)-related area, the leachate-related area and the sludge-related area. Nine sampling points were placed and 35 types of odorous substances were measured and quantified from these grabbed samples. The results showed that the main odorous substances emitted from landfill site were styrene, toluene, xylene, acetone, methanol, n-butanone, n-butylaldehyde, acetic acid, dimethyl sulfide, dimethyl disulfide and ammonia. In the MSW-related area, the highest concentrations of oxygenated compounds were observed at the gas extraction wells (GW), while sulfur compounds were rare. Ammonia in the sludge-related area was very abundant. Sludge discharge area (SD1) and sludge disposal work place (SD2) were representative points of pre- and post-drying, in which the characterizations of the emitted odorous gas were different. After chemical drying, the concentration of ammonia increased, whereas those of volatile fatty acids and sulfur compounds decreased. In the leachate-related area, relatively low concentrations of all those odorants were detected in leachate storage pool (LS), which may be due to the enclosure operation of the leachate storage pool. Using principal components analysis and cluster analysis, GW, SD1 and SD2 were distinguished from the other sampling points. The typical odorants in GW were acetaldehyde, ethyl benzene, xylene, methylamine and dimethyl formamide. The typical odorants in SD1 were methyl mercaptan, valeric acid and isovaleric acid, while those in SD2 were carbon disulfide, acetone, 3-pentanone, methanol and trimethylamine. The typical odorants in other sampling points were hydrogen sulfide, n-butylaldehyde and acetic acid.     

Transformation of carbon tetrachloride by bisulfide treated goethite, hematite, magnetite, and kaolinite

This study investigated the transformation of carbon tetrachloride (CT) by goethite, hematite, magnetite, and kaolinite treated with bisulfide to form coatings of iron monosulfide (FeS) and other Fe(II) species. These coatings contribute to abiotic natural attenuation in anaerobic environments. Batch kinetic experiments were performed under anoxic conditions at pH 8.0. Surface-area-normalized pseudo-first-order rate constants for CT transformation did not differ significantly for the three HS- treated iron oxides, but the rate of CT transformation by bisulfide-treated kaolinite was significantly lower, most likely due to kaolinite's lower iron content. The yield of chloroform (CF) from CT transformation was typically approximately 1%. There was negligible or only slight adsorption of several natural organic matter (NOM) model compounds to the surface of HS- treated goethite, and these compounds had no influence on CT transformation rate constants or CF yields. Juglone, on the other hand, adsorbed to a greater extent, and also significantly influenced the CF yield, increasing it by a factor of approximately 20 for HS- treated hematite. We speculate that juglone or its HS- addition product adsorbed to the mineral surface and acted as a hydrogen atom donor that reacted with the trichloromethyl radical intermediate, increasing the CF yield.     

加油站罐区防泄漏的控制

实现本质安全是政府和企业管理者不懈追求的目标,困扰实现本质安全的4个方面是:人的不安全行为、物的不安全状态、管理上的缺陷、有害作业环境.其中物的不安全状态和人的不安全行为是事故多发的主要元素,两者相互联系又互为因果.人的不安全行为、管理上的缺陷、有害作业环境可以通过技能培训、安全教育、制度的完善、加强管理、合理规划等行政手段来提高或改善.而物的不安全状态则受自然环境、技术、资金投入的限制,要实现本质安全必须使"物的状态"要有一个根本的改变.     

Beijing Ministerial Declaration on Environment and Development

Abstract

As the main organic pollutant in municipal living waste, kitchen waste causes secondary pollution in the course of its being gathered and transported to the landfill by mixing with other refuse and by decomposition. This makes pollution prevention more difficult and raises the cost of landfill engineering. However, the amount of solid waste to be treated can be decreased and such pollution burden lessened by disposing of the solid waste in local municipal areas. The program in Beijing also shows that this works well with our situation in China and can accelerate marketization and public participation.     

县域土地利用细碎度综合度量与空间分异研究——以江苏省东海县为例

土地细碎化是与土地规模经营理念相背离的一种土地形态,细碎化的土地经营模式会造成土地利用效率下降、粮食减产以及景观美观度降低等一系列问题。目前,土地细碎化程度的衡量多通过细碎度表征,但尚无统一标准,且主要针对农用地。以江苏东海县为例,首先结合景观指数与主成分分析,分别计算耕地、基础设施用地、居民点用地以及生态用地的细碎度,再通过系统聚类,分析不同地类细碎度组合的地域分异特征。结果显示：不同用地类型的细碎度是自然、社会经济的综合影响结果,耕地细碎度与居民点细碎度有着较显著的正相关关系,与生态用地细碎度有着较显著的负相关关系,基础设施用地细碎度和居民点细碎度存在一定的正相关关系,与生态用地细碎度存在一定的负相关关系,土地细碎度基于不同自然、社会经济条件,其分区也有着特定的区位特征。探讨不同用地类型细碎度间的关联性及空间分异特征可以为土地利用、经济发展以及景观改善等提供科学的引导     

中国仍应严格控制人口增长——论人口增长与经济增长的关系

在中国人均资源贫乏、人口对生态系统压力增大、经济落后、有效需求不足以及失业严重的情况下 ,人口过快增长既不能促进资本增长 ,也不能促进技术进步 ,它只能会减缓人均收入的提高。因此 ,为了促进人均收入的提高 ,必须尽可能降低人口增长速度     

北京大气气溶胶部分无机组分及相关气体的浓度变化

利用SJAC-MOBIC在2000-05～2000-09的3个采样时段测量了北京大气中的气溶胶SO₄^2-、NO₃^-、NO₂^-、Cl^-及相关气体组分,得出了这些污染组分的逐时变化.结果表明气溶胶Cl^-、NO₂^-、NO₃^-及气体HCl、HNO₂和HNO₃有明显的变化规律,SO₂和气溶胶SO₄^2-的变化取决于SO₂的排放,SO₄^2-的峰值一般比SO₂的峰值晚2h左右.     

三(1,3-二氯-2-丙基)磷酸酯诱发肝脏损害及病理改变研究

本研究观测有机磷酯阻燃剂(OPFRs)污染是否可以诱发肝脏损害,考察其发生及发展程度,并探讨其发生机理,为有机磷阻燃剂污染的防治和相关疾病的有效治疗提供基础数据和科学依据。实验以大鼠为动物模型,将60只SPF级SD雄性大鼠分为5组,每组12只,选取典型的氯代有机磷阻燃剂三(1,3-二氯-2-丙基)磷酸酯(TDCPP)对大鼠进行染毒,空白对照组不做任何处理,溶剂对照组以相同体积的橄榄油灌胃,染毒组以不同剂量的TDCPP进行灌胃(125 mg·kg~(-1)·d~(-1)、250 mg·kg~(-1)·d~(-1)和500 mg·kg~(-1)·d~(-1)),每周测量体重,于第4周和第8周取血检测肝功及其他生化指标,在第8周每组抽取3只大鼠取肝脏组织做HE染色,并用透射电镜观察分析肝组织病理学改变。TDCPP对大鼠染毒8周后,结果表明:(1)体重指标在灌胃1周后开始发生差异,TDCPP处理组大鼠的体重有下降的趋势,染毒组与空白对照组和溶剂对照组相比较,差异显著(*P0.05,**P0.01),其中高剂量灌胃组的体重下降最为明显(**P0.01);(2)血清肝功指标表现出显著变化,血清谷丙转氨酶、谷草转氨酶、胆固醇和甘油三脂水平在第8周呈现明显下降趋势,染毒组与空白对照组和溶剂对照组比较,差异明显(*P0.05,**P0.01);(3) TDCPP暴露组生理生化指标变化明显,血清乙酰胆碱酯酶活性显著降低,MDA含量显著升高,SOD活力显著性降低,造成氧化损伤,与空白对照组和溶剂对照组比较,差异显著(*P0.05,**P0.01);(4)病理切片结果显示染毒组与对照组比较,细胞坏死现象明显,且高剂量组坏死更为严重。研究结果显示:TDCPP可引起大鼠体重明显下降,大鼠肝脏细胞损伤、合成功能下降,造成肝脏代谢功能紊乱,造成较为严重的肝损伤。