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451.
为了脱除CO2温室气体,提出了利用氨水土壤混合物去除CO2的新方法。分别考察了土壤颗粒粒径、CO2初始流量、氨水浓度(质量比)和温度对CO2脱除量和脱除率的影响。实验结果表明,该方法去除CO2的量较土壤物理吸附量和氨水化学吸收量的总和提高了大约15%;随着氨水浓度的增大,CO2的脱除率和脱除量都增大;随着土壤颗粒粒径和CO2初始流量的增大,CO2的脱除率和脱除量都减小;当温度由22℃升高到31℃,CO2的脱除率随着温度的升高而增大,但是继续升高温度到40℃,CO2的脱除率反而下降。 相似文献
452.
Yu Ren Aijun Ding Tao Wang Xinhua Shen Jia Guo Jiamin Zhang Yan Wang Pengju Xu Xinfeng Wang Jian Gao Jeffrey L. Collett 《Atmospheric environment (Oxford, England : 1994)》2009,43(9):1702-1711
Measurement of ambient gas-phase total peroxides was performed at the summit of Mount Tai (Mt. Tai, 1534 m above sea level) in central-eastern China during March 22–April 24 and June 16–July 20, 2007. The hourly averaged concentration of peroxides was 0.17 ppbv (± 0.16 ppbv, maximum: 1.28 ppbv) and 0.55 ppbv (± 0.67 ppbv, maximum: 3.55 ppbv) in the spring and summer campaigns, respectively. The average concentration of peroxides at Mt. Tai, which is in a heavily polluted region, was much lower than hydrogen peroxide measurements made at some rural mountain sites, suggesting that significant removal processes took place in this region. An examination of diurnal variation and a correlation analysis suggest that these removal processes could include chemical suppression of peroxide production due to the scavenging of peroxy and hydroxy radicals by high NOx, wet removal by clouds/fogs rich in dissolved sulfur dioxide which reacts quickly with peroxides, and photolysis. These sinks competed with photochemical sources of peroxides, resulting in different mean concentrations and diurnal pattern of peroxides in the spring and summer. A principal component analysis was conducted to quantify the major processes that influenced the variation of peroxide concentrations. This analysis shows that in the spring photochemical production was an important source of peroxides, and the major sink was scavenging during upslope transport of polluted and humid air from the lower part of the planetary boundary layer (PBL) and wet removal by synoptic scale clouds. During the summer, highly polluted PBL air (with high NOx) was often associated with very low peroxides due to the chemical suppression of HO2 by high NOx and wet-removal by clouds/fogs in this sulfur-rich atmosphere, especially during the daytime. Higher concentrations of peroxides, which often appeared at mid-nighttime, were mainly associated with subsidence of air masses containing relatively lower concentrations of NOy. 相似文献
453.
P. Bogaert G. Christakos M. Jerrett H.-L. Yu 《Atmospheric environment (Oxford, England : 1994)》2009,43(15):2471-2480
This paper is concerned with the spatiotemporal mapping of monthly 8-h average ozone (O3) concentrations over California during a 15-years period. The basic methodology of our analysis is based on the spatiotemporal random field (S/TRF) theory. We use a S/TRF decomposition model with a dominant seasonal O3 component that may change significantly from site to site. O3 seasonal patterns are estimated and separated from stochastic fluctuations. By means of Bayesian Maximum Entropy (BME) analysis, physically meaningful and sufficiently detailed space–time maps of the seasonal O3 patterns are generated across space and time. During the summer and winter months the seasonal O3 concentration maps exhibit clear and progressively changing geographical patterns over time, suggesting the existence of relationships in accordance with the typical physiographic and climatologic features of California. BME mapping accuracy can be superior to that of other techniques commonly used by EPA; its framework can rigorously assimilate useful data sources that were previously unaccounted for; the generated maps offer valuable assessments of the spatiotemporal O3 patterns that can be helpful in the identification of physical mechanisms and their interrelations, the design of human exposure and population health models, and in risk assessment. As they focus on the seasonal patterns, the maps are not contingent on short-time and locally prevalent weather conditions, which are of no interest in a global and non-forecasting framework. Moreover, the maps offer valuable insight about the space–time O3 concentration patterns and are, thus, helpful for disentangling the influence of explanatory factors or even for identifying some influential ones that could have been otherwise overlooked. 相似文献
454.
Zhi-Ping Wang Yang Song Jay Gulledge Qiang Yu Hong-Sheng Liu Xing-Guo Han 《Atmospheric environment (Oxford, England : 1994)》2009,43(13):2148-2153
A budget for the methane (CH4) cycle in the Xilin River basin of Inner Mongolia is presented. The annual CH4 budget in this region depends primarily on the sum of atmospheric CH4 uptake by upland soils, emission from small wetlands, and emission from grazing ruminants (sheep, goats, and cattle). Flux rates for these processes were averaged over multiple years with differing summer rainfall. Although uplands constitute the vast majority of land area, they consume much less CH4 per unit area than is emitted by wetlands and ruminants. Atmospheric CH4 uptake by upland soils was ?3.3 and ?4.8 kg CH4 ha?1 y?1 in grazed and ungrazed areas, respectively. Average CH4 emission was 791.0 kg CH4 ha?1 y?1 from wetlands and 8.6 kg CH4 ha?1 y?1 from ruminants. The basin area-weighted average of all three processes was 6.8 kg CH4 ha?1 y?1, indicating that ruminant production has converted this basin to a net source of atmospheric CH4. The total CH4 emission from the Xilin River basin was 7.29 Gg CH4 y?1. The current grazing intensity is about eightfold higher than that which would result in a net zero CH4 flux. Since grazing intensity has increased throughout western China, it is likely that ruminant production has converted China's grazed temperate grasslands to a net source of atmospheric CH4 overall. 相似文献
455.
Liming Zhang Dongsheng Yu Xuezheng Shi David C. Weindorf Limin Zhao Weixin Ding Hongjie Wang Jianjun Pan Changsheng Li 《Atmospheric environment (Oxford, England : 1994)》2009,43(17):2737-2746
Quantifying greenhouse gas (GHG) emissions from wetland ecosystems is a relatively new issue in global climate change studies. China has approximately 22% of the world's rice paddies and 38% of the world's rice production, which are crucial to accurately estimate the global warming potential (GWP) at regional scale. This paper reports an application of a biogeochemical model (DeNitrification and DeComposition or DNDC) for quantifying GWP from rice fields in the Tai-Lake region of China. For this application, DNDC is linked to a 1:50,000 soil database, which was derived from 1107 paddy soil profiles compiled during the Second National Soil Survey of China in the 1980–1990s. The simulated results show that the 2.34 Mha of paddy soil cultivated in rice–wheat rotation in the Tai-Lake region emitted about ?1.48 Tg C, 0.84 Tg N and 5.67 Tg C as CO2, N2O, and CH4 respectively, with a cumulative GWP of 565 Tg CO2 equivalent from 1982 to 2000. As for soil subgroups, the highest GWP (26,900 kg CO2 equivalent ha?1 yr?1) was linked to gleyed paddy soils accounting for about 4.4% of the total area of paddy soils. The lowest GWP (5370 kg CO2 equivalent ha?1 yr?1) was associated with submergenic paddy soils accounting for about 0.32% of the total area of paddy soils. The most common soil in the area was hydromorphic paddy soils, which accounted for about 53% of the total area of paddy soils with a GWP of 12,300 kg CO2 equivalent ha?1 yr?1. On a regional basis, the annual averaged GWP in the polder, Tai-Lake plain, and alluvial plain soil regions was distinctly higher than that in the low mountainous and Hilly soil regions. As for administrative areas, the average annual GWP of counties in Shanghai city was high. Conversely, the average annual GWP of counties in Jiangsu province was low. The high variability in soil properties throughout the Tai-Lake region is important and affects the net greenhouse gas emissions. Therefore, the use of detailed soil data sets with high-resolution digital soil maps is essential to improve the accuracy of GWP estimates with process-based models at regional and national scales. 相似文献
456.
Ionic composition of TSP and PM2.5 during dust storms and air pollution episodes at Xi'an,China 总被引:1,自引:0,他引:1
Zhenxing Shen Junji Cao Richard Arimoto Zhiwei Han Renjian Zhang Yuemei Han Suixin Liu Tomoaki Okuda Shunsuke Nakao Shigeru Tanaka 《Atmospheric environment (Oxford, England : 1994)》2009,43(18):2911-2918
TSP and PM2.5 samples were collected at Xi'an, China during dust storms (DSs) and several types of pollution events, including haze, biomass burning, and firework displays. Aerosol mass concentrations were up to 2 times higher during the particulate matter (PM) events than on normal days (NDs), and all types of PM led to decreased visibility. Water-soluble ions (Na+, NH4+, K+, Mg2+, Ca2+, F?, Cl?, NO3?, and SO42?). were major aerosol components during the pollution episodes, but their concentrations were lower during DSs. NH4+, K+, F?, Cl?, NO3?, and SO42? were more abundant in PM2.5 than TSP but the opposite was true for Mg2+ and Ca2+. PM collected on hazy days was enriched with secondary species (NH4+, NO3?, and SO42) while PM from straw combustion showed high K+ and Cl?. Firework displays caused increases in K+ and also enrichments of NO3? relative to SO42?. During DSs, the concentrations of secondary aerosol components were low, but Ca2+ was abundant. Ion balance calculations indicate that PM from haze and straw combustion was acidic while the DSs samples were alkaline and the fireworks' PM was close to neutral. Ion ratios (SO42?/K+, NO3?/SO42?, and Cl?/K+) proved effective as indicators for different pollution episodes. 相似文献
457.
Songjun Guo Sheng Wen Xinming Wang Guoying Sheng Jiamo Fu Ping Hu Yingxin Yu 《Atmospheric environment (Oxford, England : 1994)》2009,43(22-23):3489-3495
Formaldehyde and acetaldehyde are two most abundant carbonyls in ambient air. Biogenic emission has been proposed as a significant source other than anthropogenic emissions and atmospheric secondary formation. Here at a forest site in South China, the carbon isotopic compositions of formaldehyde and acetaldehyde emitted from leaves of three tree species (Litsea rotundifolia, Canarium album and Castanea henryi) were measured in comparison with the bulk carbon isotopic compositions of tree leaves. δ13C data of the emitted aldehydes (from ?31‰ to ?46‰) were quite different for tree species, which were all more depleted in 13C than the tree-leaf bulk δ13C values (from ?27‰ to ?32‰). Formaldehyde in ambient air at the forest site had δ13C values different from those of leaf-emitted formaldehyde, indicating other sources for ambient formaldehyde apart from direct emission from leaves, most probably the photooxidation of biogenic hydrocarbon like isoprene and monoterpene. The δ13C differences of acetaldehyde between ambient data and those of tree leaves emission were less than 1‰, implying direct biogenic emission as the dominant source. 相似文献
458.
对国内外公众参与环境保护的现状进行了介绍,分析了公众在参与环境保护过程中出现的问题,并针对这些问题提出了改进建议。 相似文献
459.
Ismet ok Menekse Keski Donmez Mine Uner Erkan Demirkaya Bernhard Henkelmann Heqing Shen Jarmila Kotalik Karl-Werner Schramm 《Chemosphere》2009,76(11):1563-1571
Human breast milk offers the optimal nutrition for all infants and have been widely used in biomonitoring programs to assess human exposure to lipophylic environmental contaminants such as polychlorinated dibenzo-p-dioxins (PCDD), polychlorinated dibenzofurans (PCDF) and polychlorinated biphenyls (PCB). There are no previous reports from Turkey on chemically determined levels of PCDDs, PCDFs, and PCBs in human breast milk expressed as World Health Organization (WHO) toxic equivalents (TEQ). To get an overview of the levels of these contaminants in Turkish human milk, samples from 51 Turkish women living in the Ankara, İstanbul, Antalya, Kahramanmaraş, and Afyon provinces were analyzed by high resolution gas chromatography/high resolution mass spectrometry (HRGC/HRMS) throughout 2007. The mean concentrations of WHOPCDD/F-TEQ and WHOPCB-TEQ of all samples from the five regions were 7.5 and 3.1 pg g−1 on a lipid basis, respectively. PCDD/F concentrations ranged between 0.78 and 29.3 pg WHO-TEQ g−1 fat (1.7 and 36.2 pg WHO-TEQ g−1 fat, respectively, including PCB). Of the five studied locations, the lowest levels of ∑TEQs (PCDD/F + PCB) were found in the Afyon (6.8 pg WHO-TEQ g−1 fat) and the highest in the Antalya (15.6 pg WHO-TEQ g−1 fat) province. The results have been discussed in terms of regions and PCDD/F and PCBs for which analyses had been made. The mean levels of PCDD/Fs and PCBs in Turkish human milk are comparable to that found in other countries. 相似文献
460.
The article studies tourism eco-environment of 14 cities of Gangsu Province, China, based on GIS with many kinds of multi-subject spatial database, such as remote sensing data, observation data and literature data. The research results were as follows. First, spatial features of 14 cities' tourism eco-environment are displayed with five levels of vulnerability respectively. The vulnerability in Gansu becomes worse from Gannan City, located in southern Gansu to Hexi Corridor which lies in northwestern Gansu. Second, the areas of above the middle vulnerability level make up 75% of the total areas of Gansu Province. Third, more than 70% of high-level human and natural tourism resources are in the areas with high vulnerability eco-environment. Fourth, it is crucial to develop comprehensive tourism industry in order to improve the harmonious development between tourism industry and eco-environment in Gansu Province. 相似文献