Arsenic contaminated site at an abandoned copper smelter plant: waste characterization and solidification/stabilization treatment

A preliminary survey of an arsenic contaminated site from an abandoned copper smelting facility and feasibility study of using solidification/stabilization (S/S) process to treat the contaminant waste were undertaken. It was found that the waste, located in the three-flue gas discharge tunnels, contained 2-40% arsenic. The pH of the contaminated waste is extremely low (ranging from 1.8 to 3.6). The X-ray diffraction evidence indicates that the arsenic particles present in the flue gas mainly exist as As(III), or As(2)O(3). The total amount of arsenic contaminated waste is estimated to be 700 ton in the studied area. About 50% of the particle sizes are less than 2 mm. Arsenic is easily extracted from wastes with a variety of leaching solutions. In order to meet the arsenic leaching standard of the toxicity characteristic leaching procedure (TCLP), an extremely high cement dosage is required in the S/S process (cement/waste weight ratio>6). The waste with lower particle size having higher specific surface area exhibits somewhat positive effect on the S/S performance. The use of fly ash from municipal waste incinerators, in conjunction with the reduced amount of cement, is able to meet the TCLP arsenic and lead standards. The use of lime alone could meet the TCLP arsenic standard, but lead leaching concentrations exceeded leaching Pb standard. The results of semi-dynamic leaching tests of some solidified samples indicate higher accumulated arsenic leaching concentrations after only a few leachant renewals.     

Effects of experimental parameters on NF(3) decomposition fraction in an oxygen-based RF plasma environment

Clean procedure is one of the major emitters of perfluorinated compounds (PFCs) in semiconductor manufacturing. Nitrogen trifluoride (NF(3)) is increasingly the process gas of choice for eliminating PFC emissions. However, its toxic to human and similar global warming potential compared to most other PFCs made NF(3) warranted much more investigation. This study demonstrated a radio-frequency plasma system for decomposing NF(3). The effects of experimental parameters: input power, O(2)/NF(3) ratio, operational pressure and NF(3) feeding concentration on NF(3) decomposition fraction (eta(NF3)) and energy efficiency E(NF3) were examined in detail. The analytical results demonstrated that the NF(3) was almost completely decomposed (>99%) at input power=30W, [NF(3)](in)=1.0% and eta(NF3) increased with input power. However, adding O(2) to the system inhibited NF(3) decomposition and decreased E(NF3). Moreover, eta(NF3) and E(NF3), decreased with gradually increasing operational pressure. Notably, increasing the NF(3) feeding concentration increased molecule density, reducing eta(NF3), but increasing E(NF3). Furthermore, the products detected in the NF(3)/O(2)/Ar plasma system were NO(2), NO, N(2)O, SiF(4), N(2) and F(2). Potential reaction pathways in the oxygen-based NF(3) plasma environment were built-up and elucidated.     

MODIFIED WATER QUANTITY RECEIVING MODEL FOR FLORIDA CONSERVATION AREAS1

ABSTRACT: The Conservation Areas in South Florida have been considered as one of the major water storage areas to provide a water supply for the Everglades National Park and Lower East Coast (LEC). Due to the increasing water demands of the area, additional backpumping of the surplus runoff from the LEC area into the Conservation Areas has been considered as one of several alternative plans. The Receiving Water Quantity (EPA, 1971) model has been adapted and modified to be applicable in the Conservation Areas to investigate the possible impact of additional inflow under various backpumping cases. The modification of the model included Manning's roughness coefficient, depth of flow, width of hypothetical channels through marsh areas, rainfall input, seepage rate, etc. The use of the Monte Carlo technique for area computations was found to be easy and time saving both in area and weighting rainfall input to each node. Comparison of results generated by this modified model with the recorded values in Conservation Areas 1 and 2A indicated that the model not only can be a very good evaluation tool to simulate the hydraulic regime of the Conservation Areas system but also a proper tool for investigating the impact of additional inflow resulting from the backpumping related to the water use planning and management.     

A TECHNIQUE USED TO DETERMINE RANDOM POINT POSITION1

ABSTRACT: The Monte Carlo method is a procedure which takes advantage of the high speed of electronic computer in solving complex problems in physical and mathematical fields. A rigid technique to determine whether a random point falls within an arbitrary-shaped boundary is not available. This study is to present a new technique which can be used to determine whether a random point falls within any shape of boundary, together with its range of application. A modified fixed random walk procedure is also developed to solve the problems of groundwater movement. A flowchart and computer program are also demonstrated. Comparisons of this newly developed method are made with other approximate solutions. The results indicates that the new technique is more applicable and powerful than other methods.     

First detection of enteric adenoviruses genotype 41 in recreation spring areas of Taiwan

Environmental Science and Pollution Research - Human adenoviruses (HAdVs) are DNA viruses found in recreational water, such as water parks and swimming pools. Human adenovirus 41 (HAdV-41) is the...     

A Routing and Scheduling System for Infectious Waste Collection

Most hospitals and clinics in Taiwan do not have on-site treatment facilities for their infectious waste and must rely on outside agencies for their collection and treatment. The problem of optimally routing and scheduling the collection of medical waste from a disperse group of facilities is recognized as a periodic vehicle routing problem. This study develops a computer system to solve the resulting optimization problem based on a two-phased approach proposed earlier. The first phase solves a standard vehicle routing problem to determine a set of individual routes for the collection vehicles. The second phase uses a mixed integer programming method to assign routes to particular days of the week. The computer system is user-friendly and consists of several Visual Basic programs while the geographical information system is incorporated to facilitate input and output interface and database management. An illustrative example for the infectious waste of 348 hospitals in the Tainan City area demonstrates the effectiveness of the system.     

Factors affecting the concentrations of PM10 in central Taiwan

In this study, the synoptic weather types that have high probability and low probability of producing PM10 episode are referred to as HPE and LPE, respectively. Multiple linear regressions analysis showed that NO2 was the most important contributor (35.61%) to the concentrations of PM10 for HPE weather. For LPE weather, the season factor had the greatest contribution (48.11%) to the concentrations of PM10. Using the correlation coefficients between the concentrations of PM10 and SO2 or NO2 on HPE and LPE to calculate the increase of PM10 from LPE to HPE, we found that the increase of PM10 owing to the increase of SO2 and NO2 from LPE to HPE was 12.93microg/m3 which was about 51% of the total amount of PM10 increased from LPE to HPE. Results of factor analysis showed that the first component could be attributed to the result of local pollution especially for the weather patterns of types P3 and P6, while the secondary component for the weather patterns of types P1 and P4 can be attributed to the long-range transport of SO2 pollutants from China.