排序方式: 共有48条查询结果,搜索用时 218 毫秒
41.
为了切实履行《关于汞的水俣公约》,落实美丽中国建设战略,我国亟待加强对大气环境及各涉汞行业的监管.采用文献调研、分类梳理的方法,系统地分析和总结了近年来国内外常用的大气汞监测技术现状与问题,并探讨了未来技术发展方向.结果表明:为了满足大气环境中低浓度多形态汞的监测需求,越来越多功能的大气汞监测技术被研发,当前基于AFS(原子荧光光谱)和AAS(原子吸收光谱)等方法的监测技术对Hg0(元素汞)可实现ng/m3的检出限,对Hg2+(氧化态汞)和Hgp(颗粒态汞)有着低至pg/m3的检出限.自动化采样监测技术是未来汞监测的发展趋势,当前技术对大气中Hg0有着2.5~5.0 min水平的时间分辨率,对大气中Hgp可达到1~2 h的时间分辨率,同时可实现远程传输数据.人工采样监测和被动采样监测技术虽然时间分辨率较差,但在Hg2+和Hgp的监测方面有着一定优势.研究显示,完善大气汞监测管理体系,除了需要研发更强大的Hg2+和Hgp测定技术用于理解相关迁移转化过程,还亟待在相应的标定方法上实现技术革新,并应用这些技术组建地区和全球大气汞监测网络. 相似文献
42.
Niobium oxide nanowire-deposited carbon fiber(CF) samples were prepared using a hydrothermal method with amorphous Nb_2O_5·nH_2O as precursor. The physical properties of the samples were characterized by means of numerous techniques, including X-ray diffraction(XRD), energy-dispersive spectroscopy(EDS), scanning electron microscopy(SEM), transmission electron microscopy(TEM), selected-area electron diffraction(SAED), UV–visible spectroscopy(UV–vis), N_2 adsorption–desorption, Fourier transform infrared spectroscopy(FT-IR), and X-ray photoelectron spectroscopy. The efficiency for the removal of Cr(VI) was determined.Parameters such as pH value and initial Cr(VI) concentration could influence the Cr(VI) removal efficiency or adsorption capacity of the Nb_2O_5/carbon fiber sample obtained after hydrothermal treatment at 160°C for 14 hr. The maximal Cr(VI) adsorption capacity of the Nb_2O_5 nanowire/CF sample was 115 mg/g. This Nb_2O_5/CF sample also showed excellent photocatalytic activity and stability for the reduction of Cr(VI) under UV-light irradiation: the Cr(VI) removal efficiency reached 99.9% after UV-light irradiation for 1 hr and there was no significant decrease in photocatalytic performance after the use of the sample for 10 repeated cycles. Such excellent Cr(VI) adsorption capacity and photocatalytic performance was related to its high surface area,abundant surface hydroxyl groups, and good UV-light absorption ability. 相似文献
43.
针对洞口段富水浅埋软弱围岩隧道易发生挤压性大变形的特点,依托某隧道,通过监控量测、室内试验、数值模拟等手段分析隧道的变形特征、影响因素及其致灾机制与力学破坏模式。结果表明,隧洞开挖后变形具有流变特性,且持续时间长、变形量大;此外,上、中台阶开挖造成的拱顶沉降、围岩收敛分别占总变形的 61.16%、63.34%, 是大变形产生的主要阶段;洞内大变形是在多种影响因素的耦合作用下产生的,地下水是造成该软岩隧道大变形的主要控制因素,地下水的软化、渗流是大变形的主要变形机理,破坏力学模式主要有软岩塑流和累进性松脱扩展两种,软岩塑流造成侧墙鼓出、顶压以及钢拱架扭曲等现象,累进性松脱扩展造成垮塌、地表裂缝等现象。数值模拟验证了大变形力学机理的正确性并反演了大变形发展趋势。最终针对该隧道大变形产生的主要原因,提出并实践形成了“内外结合”的主动控制技术:洞外掌子面动态跟进超前降水,洞内“中管棚+小导管”超前支护、上台阶 “核心土+扩大拱脚”、中台阶“临时仰拱+大锁脚”、下台阶“短进短衬,快速支护”,成功穿越 300 m 浅埋富水极软岩段,研究成果可为类似工程提供借鉴。 相似文献
44.
生态文明建设是关系中华民族永续发展的千年大计。近年来,为加强我国生态文明建设,国家层面制定了一系列生态文明建设试点政策,发挥了对全局性改革的示范、突破和带动作用,但也存在部分试点政策执行进展偏慢、效果不如预期等问题,亟待进行系统评估。本研究基于政策过程理论,从政策制定与政策执行两个维度遴选26项评估指标,通过定量分析与定性分析相结合,对我国的生态文明试点政策体系(共9大类、53项)进行系统评估。研究发现:(1)政策目标有待完善,考核机制尚需健全;(2)改革任务交叉重复且分工不明,存在部门利益导向;(3)试点的空间、类型分布不均衡,试点选择科学性不足;(4)立法、市场、社会参与等管理手段有待进一步完善。在此基础上,本研究从目标设置、任务优化、试点布局以及管理机制运用等四个方面提出了若干对策建议,以期对完善我国生态文明建设制度体系提供决策参考。 相似文献
45.
Feng Chen Shihao Guo Yihao Wang Lulu Ma Bing Li Zhimin Song Lei Huang Wen Zhang 《Frontiers of Environmental Science & Engineering》2022,16(5):57
46.
Huang Daquan Zhu Shihao Liu Tao 《Environmental science and pollution research international》2022,29(5):6414-6432
Environmental Science and Pollution Research - Examining the heterogeneous factors behind the conversion of various types of non-urban land into urban use is of great significance for controlling... 相似文献
47.
Zhu Huijia Liu Yong Wang Feng Song Shihao Cai Jiali 《Journal of Material Cycles and Waste Management》2023,25(4):2012-2024
Journal of Material Cycles and Waste Management - To explore the factors that influence residents’ waste separation intention (WSI) and the interaction mechanism among different influencing... 相似文献
48.
Xiao Zumian Ma Shiqun Sun Hanwen Ren Jiameng Feng Chao Cui Shihao 《Environmental science and pollution research international》2022,29(38):57421-57436
Environmental Science and Pollution Research - Clarifying the time-varying spillovers among pilot carbon emission permit trading markets in China is an important foundation for building the... 相似文献