红外测温法测定硫化矿石堆自热温度的影响因素研究

硫化矿自燃是一个以氧化放热为主、自发产生热量及热量积蓄引起硫化矿堆升温的非常复杂的物理化学过程.因此,研究硫化矿自热过程是研究硫化矿自燃早期预测预报方法的前提.文章以红外非接触方式,利用RaytekminiTemp红外测温仪和CENTER可记录温度计测定硫化矿石堆氧化自热温度,重点分析了测定过程中的实际温度时影响精度的有关因素,主要有矿样种类、矿样温度、矿样块度、检测距离、环境温度、光束与矿样的夹角.通过实验室研究,为研制出专门用于舍硫矿自燃预测预报的装置提供理论依据,从而达到预测预报硫化矿自燃的目的.     

Formation mechanisms of nitrous acid (HONO) during the haze and non-haze periods in Beijing, China

As an important precursor of hydroxyl radical (OH), nitrous acid (HONO) plays a significant role in atmospheric chemistry. Here, an observation of HONO and relevant air pollutants in an urban site of Beijing from 14 to 28 April, 2017 was performed. Two distinct peaks of HONO concentrations occurred during the observation. In contrast, the concentration of particulate matter in the first period (period Ⅰ) was significantly higher than that in the second period (period Ⅱ). Comparing to HONO sources in the two periods, we found that the direct vehicle emission was an essential source of the ambient HONO during both periods at night, especially in period Ⅱ. The heterogeneous reaction of NO₂ was the dominant source in period Ⅰ, while the homogeneous reaction of NO with OH was more critical source at night in period Ⅱ. In the daytime, the heterogeneous reaction of NO₂ was a significant source and was confirmed by the good correlation coefficients (R²) between the unknown sources (P_unknown) with NO₂, PM_2.5, NO₂ × PM_2.5 in period Ⅰ. Moreover, when solar radiation and OH radicals were considered to explore unknown sources in the daytime, the enhanced correlation of P_unknown with photolysis rate of NO₂ and OH ($J_{{\mathrm{NO}}_2}$ × OH) were 0.93 in period Ⅰ, 0.95 in period Ⅱ. These excellent correlation coefficients suggested that the unknown sources released HONO highly related to the solar radiation and the variation of OH radicals.     

The preparation of slow-release fertilizers with biomass ash and water/waste acid solutions from desulfurization and denitrification of flue gas

Environmental Science and Pollution Research - In this study, a method of preparing fertilizers with the fly ash from biomass power plants and the waste acid solution from flue gas desulfurization...     

Tracing the impact of stack configuration on interface resistances in reverse electrodialysis by in situ electrochemical impedance spectroscopy

• RED performance and stack resistance were studied by EIS and LSV. • Interface resistance were discriminated from Ohmic resistance by EIS. • Impacts of spacer shadow effect and concentration polarization were analyzed. • Ionic short current reduced the power density for more cell pairs. • The results enabled to predict RED performance with different configurations. Reverse electrodialysis (RED) is an emerging membrane-based technology for the production of renewable energy from mixing waters with different salinities. Herein, the impact of the stack configuration on the Ohmic and non-Ohmic resistances as well as the performance of RED were systematically studied by using in situ electrochemical impedance spectroscopy (EIS). Three different parameters (membrane type, number of cell pairs and spacer design) were controlled. The Ohmic and non-Ohmic resistances were evaluated for RED stacks equipped with two types of commercial membranes (Type I and Type II) supplied by Fujifilm Manufacturing Europe B.V: Type I Fuji membranes displayed higher Ohmic and non-Ohmic resistances than Type II membranes, which was mainly attributed to the difference in fixed charge density. The output power of the stack was observed to decrease with the increasing number of cell pairs mainly due to the increase in ionic shortcut currents. With the reduction in spacer thickness from 750 to 200 µm, the permselectivity of membranes in the stack decreased from 0.86 to 0.79 whereas the energy efficiency losses increased from 31% to 49%. Overall, the output of the present study provides a basis for understanding the impact of stack design on internal losses during the scaling-up of RED.     

Measuring the environmental protection efficiency and productivity of the 49 largest iron and steel enterprises in China

Environment, Development and Sustainability - China is the largest source of carbon emissions in the world, and the Chinese iron and steel sector is the main contributor to the growth in greenhouse...     

Inter-provincial responsibility allocation of carbon emission in China to coordinate regional development

Environmental Science and Pollution Research - To establish the carbon emission trading scheme and achieve the carbon emission reduction goals in China, it is critical to allocate the carbon...     

Bioremediation of tetramethyl thiuram disulfide and resource utilization of natural rubber wastewater by WR-2 Bacillus-dominated microbial community

Environmental Science and Pollution Research - Tetramethyl thiuram disulfide (TMTD), an emerging pollutant with ecotoxicity and accumulation in rubber wastewater, is directly discharged by...     

Assessing the impact of mechanism of green public consumption policy on environmental equity: evidence from China

Environment, Development and Sustainability - This study investigates the impact of the mechanism of green public consumption policy on environmental equity and provides a feasible reference for...     

Does foreign private investment affect the clean industrial environment? Nexus among foreign private investment,CO2 emissions,energy consumption,trade openness,and sustainable economic growth

Environmental Science and Pollution Research - This study examines to what extent foreign private investment (FPI) affects the clean industrial environment and sustainable economic growth through...     

椅式桩板结构地震响应分析与简化计算方法研究

椅式桩板结构在高陡边坡路基工程中应用广泛,研究其高烈度地震下的响应特征对抗震分析具有重要意义.以拟建川藏铁路某斜坡椅式桩板结构路基支挡工程为背景,建立有限差分三维数值计算模型,研究了结构的静、动力学响应特性,分析了结构最不利状态响应物理量的取值方法,探讨了结构传力分担机制及重要受力部位,提出了结构地震响应简化计算方法....