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231.
232.
Yong-Kook Kwon Hyun-Whee Bae Sun Kyoung Shin Tae-Wan Jeon Jungju Seo Geum-Sook Hwang 《Environmental science and pollution research international》2014,21(17):10453-10460
Leachate, generated by the decomposition of animal carcasses, presents many environmental, sanitary, and food safety hazards. However, research on the characteristics of leachate is lacking. In this study, we performed biochemical profiling of leachate from two animal species (pig and cattle) in two soil types (sandy loam and sandy soil) using 1H-NMR-based profiling, followed by multivariate data analysis. The leachate was collected from a well-controlled artificial burial site over a 31-week period. Principal components analysis (PCA) of the NMR data showed similar patterns between species and soil types. Organic components, including organic acids and phenols, predominated, and their levels increased with time. The methylamine level in leachate from pig carcasses 18 weeks following burial was significantly higher than that from cattle carcasses; leachate from cattle carcasses in sandy soil 1 week after burial contained unique components (specifically ethanol, formate, alanine, N-methylation, and taurine), in contrast with those from sandy loam soil. This study suggests that a NMR-based profiling approach is useful to characterize the organic components in leachate from animal carcasses over time. 相似文献
233.
The behavior and mechanism of Li leaching from lithium aluminum silicate glass-ceramics which can be used as a secondary source of Li using aqueous NaOH solution was investigated. The Li leaching efficiency is increased with increasing concentration of NaOH, specific surface area, and reaction temperature. When leached under optimum conditions, 2 mol/L NaOH, 53 μm particle undersize, 1:10 solid/liquid ratio, 250 r/min stirring speed, 100°C reaction temperature, 12 hr, the Li leaching efficiency was approximately 70%. However, when the leaching experiment was performed for 48 hr, the concentration of Li+ ions contained in the leach liquor decreased from 1160 to 236 mg/L. To investigate the origin of this phenomenon, the obtained leach residue was analyzed by X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. These analyses show that zeolite was formed around the lithium aluminum silicate glass-ceramics, which affected the leaching of by adsorbing Li+ ions. In addition, using the shrinking-core model and the Arrhenius equation, the leaching reaction with NaOH was found to depends on the chemical reaction of the two reactants, with a higher than 41.84 kJ/mol of the activation energy. 相似文献
234.
In Jae Shin 《Journal of Loss Prevention in the Process Industries》2013,26(4):803-814
This paper examines effectiveness of a regulatory enforcement organization (Major industrial Accident Prevention Center, MAPC), and a grading system for implementation of the Process Safety Management (PSM) regulation in Korea. A lot of chemical installations have been built in Korea since the 1960s. The frequent occurrence of major industrial accidents had made people's concerns grow. The Korean government enacted PSM regulations in 1996 in order to curb these accidents.However, a key question is how to make sure companies comply with the PSM regulations. In order to improve company’ compliance with PSM regulations the Ministry of Employment and Labor (MOEL) responsible for the regulation introduced a grading management system in 2001 and then established special supervisory centers for enforcement of PSM regulations in 2005. This paper reviews the role and effectiveness of the system in term of PSM enforcement. The author found that the grade-based approach has encouraged employers to implement the requirements of the PSM regulations. MAPCs play an effective role in enhancing enforcement performance. Although the more chemical plants have been established in Korea, the fewer major industrial accidents have occurred since the introduction of the system. The results may be useful for the policy maker to build an effective and efficient enforcement system. 相似文献
235.
Wonkyoung Shin 《International journal of occupational safety and ergonomics》2019,25(1):110-122
This study involves performing improvements in workstation specification using a three-dimensional human modeling tool and proposing well-balanced work scheduling (WBWS) to prevent work-related musculoskeletal disorders (WMSDs) in a small manufacturing plant. To analyze risk factors of WMSDs, various tasks at 10 different types of workstation were evaluated with detailed motion analysis using a customized checklist. Questionnaires were administered to 27 workers to evaluate symptoms related to WMSDs. Revised workstation specifications were suggested based on anthropometric characteristics of workers using before–after analyses as an engineering control. Additionally, WBWS was proposed as an administrative control to avoid continuous physical stress on specific body parts in repetitive tasks. A software tool for WBWS was developed for convenient and easy application. The results of the study may aid managers in applying ergonomic interventions with time and cost savings, and enhance worker satisfaction and motivation due to improvements in working conditions to prevent WMSDs. 相似文献
236.
To examine the levels of PCDD/DFs pollution in environmental samples in the vicinity of various incinerators, the levels of PCDD/DFs in air and soil samples collected near 17 incinerators and stack emission gases were investigated between 2003 and 2006. A total of 434 soil, 28 stack emission gas, and 38 air samples were analyzed for their PCDD/DFs concentrations. The PCDD/DFs concentrations in the flue gas samples ranged from 0.02 to 16.41 ng I-TEQ/Sm(3), with an arithmetical mean value of 3.13 ng I-TEQ/Sm(3). The PCDD/DFs concentrations in the air samples ranged from 0.032 to 0.965 pg I-TEQ/Sm(3). The soil samples contained between N.D. and 153.23 pg I-TEQ/g-dry, with an average of 7.36 pg I-TEQ/g-dry. These levels were generally consistent with or lower than many previous studies. The average PCDD/DFs levels in the soil samples decrease with increasing distance from the incinerator. From the PCDD/DFs level gradient from each plant, a distance of 500 m is suggested as being under the influence of an incinerator. 相似文献
237.
Yoon Shin Kim 《Journal of the Air & Waste Management Association (1995)》2013,63(8):841-843
This paper discusses the potential for using commercially available treatment techniques to remove VOCs from hazardous waste streams and addresses some of the issues associated with making waste treatment a viable VOC emission control technique for hazardous waste management facilities. It discusses the waste streams of concern because of their volatile constituents and describes potentially applicable treatment techniques. The use of models for treatment process design is described. Finally, the paper discusses treatment cost, treatment residuals, and considerations of importance in choosing where in the life cycle of a hazardous waste stream to treat it. 相似文献
238.
Effects of low dissolved oxygen on early development and swimming behaviour of veliger larvae of the scavenging gastropod
Nassarius festivus were studied. Embryonic development was significantly delayed when dissolved oxygen level was reduced to 3.0 mg O2 l−1 and no embryo hatched successfully at 0.5 mg O2 l−1. Veliger larvae hatched at 4.5 mg O2 l−1 had significantly smaller velar lobe, shell length and shell width. Median 48-h LC50 value of the veliger larvae was estimated at 1.25 mg O2 l−1 with lower swimming speed (swimming velocity and dispersal velocity) being recorded for the survivors exposed to reduced
oxygen levels. The percentage of veliger larvae that developed into crawling juveniles was significantly reduced and metamorphosis
was delayed at 4.5 mg O2 l−1 whereas all larvae at 3.5 mg O2 l−1 died before they underwent metamorphosis. Juveniles developed at 4.5 mg O2 l−1 were also smaller than those at 6.0 mg O2 l−1. Results indicated that dissolved oxygen levels well above hypoxia levels (2.8 mg O2 l−1) have already had significant impact on the hatching success and larval development in gastropods, which may lead to long-term
decreases in population growth. 相似文献
239.
H.-H. Kim C.-S. Lee J.-M. Jeon S.-D. Yu C.-W. Lee J.-H. Park D.-C. Shin Y.-W. Lim 《Environmental science and pollution research international》2013,20(7):4831-4846
The objectives of this study were to survey elementary school students regarding the environmental conditions of their elementary schools and to assess the relationship between air pollution and allergic disease using the International Study of Asthma and Allergies in Childhood (ISAAC) questionnaire. Therefore, this study was designed as a cross-sectional study. In this study, seven elementary schools were selected and they were classified into three categories. The selection included one school with no traffic-related or other pollutants, three with traffic-related pollutants, and three with traffic-related and other pollutants from industrial and filling station sources. The ISAAC questionnaire survey was given to all of the students except to those in the 1st grade who were presumed to be less likely to be exposed to the school environment than the remainder of the students attending those seven schools. The assessment of allergic disease was conducted on a total of 4,545 students. Three school zones with critical exposure were selected within each school and they were evaluated based on the levels of black carbon (BC), PM10, SO2, NO2, and O3. There was a significant increase in the risks based on the odds ratios of treatment experiences (within 1 year) for allergy-related diseases such as asthma and allergic rhinitis (a) in the school group with traffic-related pollutants and the school group with complex pollutants were 2.12 (1.41–3.19) and 1.59 (1.06–2.37), respectively, in comparison to the school groups with no exposure to pollutants. This was determined based on the odds ratio of symptoms and treatment experiences for allergy-related diseases by group based on the home town zone as a reference. Also, in the case of atopic dermatitis, the odds ratio of treatment experiences (within 1 year) was 1.42 (1.02–1.97), which indicated elevated risks compared to the students in the S1 school. A regression analysis was used to assess the relationship between the substances and the symptomatic experiences within the last year. There were significant increases in the odds ratio of the symptoms associated with allergic rhinitis and the BC and SO2 in the complex pollution areas. The results of the assessment of the relationship between atopic dermatitis-associated symptoms and O3 showed that the odds ratio increased with statistical significance. 相似文献
240.
The present study investigated the photocatalytic activity of an S-doped TiO2 photocatalyst with regards to dimethyl sulfide degradation under visible-light irradiation, along with its deactivation and reactivation. The dimethyl sulfide conversion was between 85% and 93% for the lowest relative humidity range (10–20%) and close to 100% for the two higher relative humidity ranges (45–55% and 80–90%). The conversion was also close to 100% for the two lowest input concentrations (0.039 and 0.195 ppm), while it was between 91% and 96% at 3.9 ppm and between 85% and 90% at 7.9 ppm. In contrast to the input concentration dependences on conversion, the calculated degradation rates increased as input concentrations increased. The dimethyl sulfide conversion at low concentrations (≤0.39 ppm), which are associated with non-occupational inn occurring. However, catalyst deactivations were observed during the photocatalytic process whdoor air quality issues, was up to nearly 100% for long time periods (at least 603 h), without any significant catalyst deactivatioen higher concentrations (3.9 and 7.8 ppm) were used. The photocatalyst, reactivated by using two types of air (dried and humidified) under visible-light irradiation, did not regain all of its initial activities. Sulfate groups were qualitatively identified as the reaction products on the photocatalyst surface. In addition, gaseous byproducts, quantitatively determined, included dimethyl disulfide, methanol, and SO2. It is noteworthy that the peak concentration of dimethyl disulfide (0.79 ppm = 790 ppb), generated over the photocatalytic process with the highest dimethyl sulfide input concentration, exceeded the odor threshold value of 0.1–3.6 ppb for dimethyl disulfide. 相似文献