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排序方式: 共有106条查询结果,搜索用时 15 毫秒
101.
Biobased Epoxy/Layered Silicate Nanocomposites: Thermophysical Properties and Fracture Behavior Evaluation 总被引:1,自引:0,他引:1
Hiroaki?Miyagawa Manjusri?Misra Lawrence?T.?Drzal Amar?K.?MohantyEmail author 《Journal of Polymers and the Environment》2005,13(2):87-96
The biobased epoxy containing epoxidized linseed oil (ELO) and its clay nanocomposites were processed with an anhydride curing agent. The certain amount of diglycidyl ether of bisphenol F (DGEBF) was replaced by ELO. The selection of the DGEBF, ELO, an anhydride curing agent, and organo-montmorillonite clay resulted in an excellent combination, to provide new biobased epoxy/clay nanocomposites showing high elastic modulus, high glass transition temperature, and high fracture toughness with larger amount of ELO. Izod impact strength was almost constant while changing the amount of ELO. This is a promising result for future applications in different engineering industries. 相似文献
102.
Chidya Russel Derbalah Aly Abdel-Dayem Sherif Kaonga Chikumbusko Tsuji Hiroaki Takeda Kazuhiko Sakugawa Hiroshi 《Environmental science and pollution research international》2022,29(45):67894-67907
Environmental Science and Pollution Research - We assessed the contamination, dynamics, and health risks of the pesticides cyanazine, simetryn, fenarimol, isoprothiolane, diazinon, irgarol,... 相似文献
103.
Impact of FEBRA (fermented brown rice with Aspergillus oryzae, a rich dietary fiber) intake on the concentrations of polychlorinated-biphenyls (PCBs), -dioxin-like polychlorinated biphenyls (DLPCBs), -dibenzo-p-dioxins (PCDDs), and -dibenzofurans (PCDFs) in blood of nine married Japanese were studied for 2 years. Concentrations of total PCBs (average+/-standard deviation) were greater 326,000+/-263,000 and 207,000+/-89,000 in FEBRA-intake and non-FEBRA-intake groups, respectively, on pg/g lipid (from now onwards data expressed on pg/g lipid). DLPCBs were second major contaminants 94,000+/-77,000 and 60,000+/-28,000, orderly in FEBRA-intake and non-FEBRA-intake groups. The concentrations of PCDD/DFs were several orders of magnitude lower than those of PCBs, whereas PCDDs were greater (433+/-233 and 512+/-511, in FEBRA-intake and non-FEBRA-intake groups, respectively) than PCDFs (56+/-50 and 43+/-35). Calculated toxic equivalency (TEQ) concentrations were 34+/-24 and 23+/-10 in FEBRA-intake and non-FEBRA-intake groups, respectively. In order to corroborate the impact of FEBRA, the changes of PCDD/DFs and PCB concentrations for 0.5-year, 1-year, 1.5-year, and 2-year samples were estimated from average concentration of 1-day before study commences and 1-week study samples. The results explicit FEBRA-intake group eliminated 7%, 33%, 45%, 36%, and 26% and non-FEBRA-intake group eliminated 8%, 28%, 36%, 31%, and 20% of DLPCBs, PCDDs, PCDFs, PCDD/DF TEQ and total TEQ, respectively. This study is the first of its kind showing the possible elimination of PCDDs, PCDFs and their TEQ in humans from Japan after the consumption of FEBRA. 相似文献
104.
The degradation characteristics of PPCPs commonly found in surface water under UV treatment were examined for 30 kinds of PPCPs using a UV/Lamp1 that emits light at a wavelength of 254 nm and a UV/Lamp2 that emits light at 254 nm and 185 nm in pure water. When a UV dose of some 230 mJ/cm2 was introduced to the 30 PPCPs, photodegradation rates of about > 3% (theophylline) to 100% (diclofenac) and about > 15% (clarithromycin) to 100% (diclofenac) were observed for UV/Lamp1 and UV/Lamp2, respectively. This study also showed that UV/Lamp2, which photolyzes water molecules and generates OH radicals, is more effective for PPCP removal than UV/lamp1. It was postulated that the degradation rates of sulfamethoxazole, sulfamonomethoxine, sulfadimethoxine and sulfadimidine, all, including sulfamethoxazole, derived from sulfanilamide, under UV/Lamp1 resulted mainly from the bond-breaking reactions occurring between –SO2– and its side atoms, the C–S bond and the N–H bond. Some PPCPs with amide bonds, such as cyclophosphamide and DEET, were highly resistant to photodegradation by UV/Lamp1. AOPs (Advanced oxidation processes) such as the UV/H2O2 or UV/O3 processes should therefore be considered for their potential to remove these substances effectively. 相似文献
105.
Takashi Okuda Naoyuki Yamashita Hiroaki Tanaka Hiroshi Matsukawa Kaoru Tanabe 《Environment international》2009,35(5):815-820
In this study, occurrence of 66 PPCPs (pharmaceuticals and personal care products) in liquid and solid phases of sewage sludge was elucidated. The extraction methods for the PPCPs from sludge were newly developed employing Pressurized Liquid Extraction (PLE) and Ultrasonic Solvent Extraction (USE). As an appropriate method, PLE using water (pH2), PLE using methanol (pH4), and USE using mixture of methanol and water (1/9,v/v, pH11) was found most effective because total recovery of most of the PPCPs indicated 40 to 130%. The developed extraction method with previously developed method for liquid phase analysis was applied to field survey at wastewater treatment plants (WWTPs) in Japan. 56 compounds were detected from the primary sludge and 61 compounds were detected from the excess sludge. The concentration was ranged between several ng/g and several μg/g. Solid-water distribution coefficient (Log Kd) ranged between 0.9 L/kg (Caffeine) and 3.7 L/kg (Levofloxacin) for primary sludge and between 1.4 L/kg (Sulpirid) and 4.3 L/kg (Mefenamic acid) for excess sludge. 相似文献
106.
Polybrominated diphenyl ethers and persistent organochlorines in Japanese human adipose tissues 总被引:5,自引:1,他引:5
Kunisue T Takayanagi N Isobe T Takahashi S Nose M Yamada T Komori H Arita N Ueda N Tanabe S 《Environment international》2007,33(8):1048-1056
The present study determined concentrations of polybrominated diphenyl ethers (PBDEs) and persistent organochlorines (OCs) in Japanese human adipose tissues collected during 2003–2004. Concentrations of PBDEs in adipose tissues were 1–2 orders of magnitude lower than those of OCs. However, observed PBDE congener levels in this study were relatively higher than those in Japanese human adipose tissues collected during 2000 reported previously, while OC levels were comparable to those in specimens collected during 1999 reported by our group. In addition, no age-dependent accumulation of PBDEs was observed, while OC levels except chlordane compounds increased with age. These results indicate recent human exposure to PBDEs in Japan. Among PBDE congeners accumulated in Japanese adipose tissues, BDE-153 was dominant, but this trend was different from those in human milk (BDE-47) and blood (BDE-209) reported previously in Japan, implying the congener-specific kinetics in human bodies. The significant positive correlations between PBDEs and OCs were observed in Japanese adipose tissues, indicating the similar exposure route of these contaminants for Japanese citizens, probably via fish intake. 相似文献