Green pharmaceutical supply chain coordination considering green investment,green logistics,and government intervention

Environmental Science and Pollution Research - Despite their important role in the fight against global climate change, the coordination of green pharmaceutical supply chains (GPSC) has rarely been...     

稀土镧改性聚合硫酸铁机理分析及其应用

为进一步提高无机高分子絮凝剂的处理效果并降低处理成本,研究"一步法"絮凝剂制备工艺,同时引入稀土镧对絮凝剂进行改性处理,制备固体稀土镧聚合硫酸铁絮凝剂(La-PFS).实验通过响应面优化絮凝性能,研究结果表明.聚合温度为123℃、镧铁摩尔比为1∶105.56、OH~-/Fe摩尔比为0.19时,制备产品对高浊度废水除浊效率效果达到99.41%.引入稀土镧在一定程度上增长絮凝剂链状结构,增强吸附能力.在对造纸废水处理中,稀土镧聚合硫酸铁对造纸废水处理效果明显优于传统市售絮凝剂,絮凝沉淀速度有较大提升,浊度去除率达到68%,COD_(Cr)去除率达到35%.     

基于计算模拟与响应面分析漆酶对己烯雌酚的降解作用

己烯雌酚(Diethylstilbestrol,DES)作为水环境中最具雌激素活性的合成化合物之一,其给生物体和环境带来的危害已经引起人们的关注.本研究首先通过分子对接与分子动力学模拟从理论上分析漆酶与DES的相互作用;其次通过实验分析其降解动力学模型及不同反应条件和介质对漆酶催化转化DES的影响;最后使用响应面分析方法优化漆酶-ABTS系统催化转化DES的最佳条件.计算结果表明,漆酶与DES的反应能够自发进行且它们之间主要存在氢键和疏水作用力.实验结果表明,反应6 h左右,50 mg·L^-1的DES的降解率达到93%以上;根据Michaelis-Menten模型得到的动力学参数K_m和V_max分别为36.18 mg·L^-1和45.98 mg·L^-1·h^-1,模型的R²为0.99.漆酶催化降解DES的最佳pH为6,最佳温度为55℃.几种介质中,ABTS对漆酶催化降解DES的作用最强.通过响应面分析发现,在pH=5.5、55.98℃、1....     

水平波纹板组处理含油废水

采用水平波纹板组处理含油废水。通过正交小试,筛选出最佳波纹板,并对不同板间距、流速、原水温度以及油种作了除油效率影响试验。在此基础上,进行了水平波纹板除油装置的放大并用于实际含油废水处理的试验。结果表明.该除油技术可用于非乳化的含油废水处理。与目前国内其它重力分离技术相比,具有除油效率高(95％以上)和能去除20μm以下的微小油珠的特点。     

Metagenomic insights into responses of microbial population and key functional genes to fulvic acid during partial nitritation

The long-term impact of fulvic acid (FA) on partial nitritation (PN) system was initially examined in this study. The obtained results revealed that the FA lower than 50 mg/L had negligible effect on the nitrite accumulation rate (NAR nearly 100%) and ammonium removal rate (ARR 56.85%), while FA over 50 mg/L decreased ARR from 56.85% to 0.7%. Sludge characteristics analysis found that appropriate FA (<50 mg/L) exposure promoted the settling performance and granulation of PN sludge by removing Bacteroidetes and accumulating Chloroflexi. The analysis of metagenomics suggested that the presence of limited FA (0-50 mg/L) stimulated the generation of NADH, which favors the denitrification and nitrite reduction. The negative impact of FA on the PN system could be divided into two stages. Initially, limited FA (50-120 mg/L) was decomposed by Anaerolineae to stimulate the growth and propagation of heterotrophic bacteria (Thauera). Increasing heterotrophs competed with AOB (Nitrosomonas) for dissolved oxygen, causing AOB to be eliminated and ARR to declined. Subsequently, when FA dosage was over 120 mg/L, Anaerolineae were inhibited and heterotrophic bacteria reduced, resulting in the abundance of AOB recovered. Nevertheless, the ammonium transformation pathway was suppressed because genes amoABC and hao were obviously reduced, leading to the deterioration of reactor performance. Overall, these results provide theoretical guidance for the practical application of PN for the treatment of FA-containing sewage.     

Distribution and variation of mercury in frozen soils of a high-altitude permafrost region on the northeastern margin of the Tibetan Plateau

Environmental Science and Pollution Research - The Tibetan Plateau (TP) is home to the largest permafrost bodies at low- and mid-latitudes, yet little is known about the distribution and variation...     

基于局部强度阶梯折减法的边坡渐进破坏研究∗

通过强度折减法获取边坡的潜在滑裂带是目前数值计算广泛使用的方法,研究边坡滑裂带形成的渐进过程及坡体内部土体的应力状态具有重要的理论意义和工程价值。基于边坡破坏的渐进性思想,针对均质边坡提出了一种局部强度阶梯折减的方法。该方法以屈服接近度(YAI)作为判别土体是否存在破损区的评价标准,将局部破损区按不同破损次序分配予不同的折减系数,利用通用软件ABAQUS对局部坡体进行强度折减计算,研究边坡渐进变形过程,直至边坡发生整体破坏。计算结果表明,坡体内部初始破损区参与了潜在滑裂面的形成过程,对边坡后期渐进变形具有贡献;有效解决了传统强度折减法潜在滑裂面上折减区和非折减区边界处的塑性应变值的跳跃性问题,合理地演化了边坡的渐进失稳进程。     

微波功率、辐射时间及污泥量对污泥微波干燥效能的综合影响研究

通过正交实验探讨了微波功率、辐射时间及污泥量对污泥微波干燥效能的综合影响研究,实验结果表明:在微波功率为140～580 W,辐射时间为5～20 min,污泥量为200～350 g的实验条件下,微波功率、辐射时间及两者之间的交互作用对污泥微波干燥效能影响高度显著,污泥量影响不显著;并得出微波功率、辐射时间对污泥含水率综合影响的定量正交回归方程。     

汽油介质输送抢维修工艺研究

由于汽油特殊的物化性质,在管输过程中一旦发生泄漏极易造成火灾、爆炸及中毒事故,从而导致重大人员伤亡及财产损失。在深入分析汽油泄漏事故特点及危险性的基础上,结合汽油管输事故抢维修工作的实际经验,提出了事故抢维修工艺程序、危险性控制方法及辅助作业与后勤保障的基本要求,为汽油管输事故抢维修作业提供参考。     

基于动态贝叶斯网络的石化装置火灾事故动态风险分析

为揭示石油炼化装置事故风险动态特性和事故情景演变路径,在对石化装置进行风险因素分析的基础上构建石化装置火灾事故故障树,基于贝叶斯网络非常规突发事故的演变过程,构建情景演变下的动态贝叶斯网络模型,在综合考虑应急措施的基础上,利用MATLAB软件和联合概率公式计算出各种事故场景的状态概率.以丙烯精馏装置火灾事故为例,结果表...