4-氯苯酚在水溶液中的光化学反应(Ⅰ)单线态氧和自由基的产生

在模拟太阳光照射下，４氯苯酚（４ＣＰ）浓度迅速降低，反应过程对应着产生大量的单线态氧和自由基．金属离子Ｆｅ２＋、Ｆｅ３＋、Ａｌ３＋能够加速这一过程，尤以Ｆｅ２＋、Ｆｅ３＋的影响更明显；在模拟太阳光照射下，向４ＣＰ体系加入的富里酸（ＦＡ），对４ＣＰ浓度降低略起抑制作用，这表明二者之间存在相互作用．但当再加入金属离子Ｆｅ２＋、Ｆｅ３＋、Ａｌ３＋后，能够加速４ＣＰ浓度降低，尤以Ｆｅ２＋、Ｆｅ３＋的影响更显著．     

废旧橡胶粉用于道路改性沥青的研究

从环保的角度出发，利用废旧橡胶粉对道路沥青改性进行了试验研究，分析了废胶粉的细度及掺量对沥青性能的影响，并就橡胶粉改性沥青所采用的胶粉细度、掺量以及改性措施提出了合理的建议。     

北海污水汽提装置运行探讨

介绍北海分公司含硫污水汽提装置改造情况及运行效果，并对装置存在的问题进行分析，提出解决办法。     

城市污泥好氧堆肥过程中能量平衡的理论分析

从热力学角度研究城市污泥的好氧堆肥过程,根据热力学第一定律,建立了好氧堆肥过程中的能量平衡关系,并给出了平衡关系中各参数的计算方法。     

高压聚乙烯装置粉尘污染的防治

分析了产生粉尘过多的原因及粉尘收集系统存在的问题，结合本装置的实际情况提出了粉尘的综合防治方案，并取得了初步的成功。     

矿区土地复垦与对策

较系统地总结了从开矿到复垦过程中需要在土地整理方面做的工作，研究借鉴目前国内外土地复垦的方法，讨论土地复垦过程中出现的问题及复垦后所应采取的对策。     

有机物分子结构与光催化氧化反应活性的关系

从正辛醇－水分配系数与Ｈａｍｍｅｔｔ常数，光催化氧化过程中的光解作用，表面活性剂的微环境效应及取代基的诱导效应等方面，探讨了有机物分子结构与其光催化氧化反应性之间的关系。     

Insights into reactive oxygen species formation induced by water-soluble organic compounds and transition metals using spectroscopic method

Ambient particulate matter (PM) can cause adverse health effects via their ability to produce Reactive Oxygen Species (ROS). Water-Soluble Organic Compounds (WSOCs), a complex mixture of organic compounds which usually coexist with Transition Metals (TMs) in PM, have been found to contribute to ROS formation. However, the interaction between WSOCs and TMs and its effect on ROS generation are still unknown. In this study, we examined the ROS concentrations of V, Zn, Suwannee River Fulvic Acid (SRFA), Suwannee River Humic Acid (SRHA) and the mixtures of V/Zn and SRFA/SRHA by using a cell-free 2′,7′-Dichlorodihydrofluorescein (DCFH) assay. The results showed that V or Zn synergistically promoted ROS generated by SRFA, but had an antagonistic effect on ROS generated by SRHA. Fluorescence quenching experiments indicated that V and Zn were more prone to form stable complexes with aromatic humic acid-like component (C1) and fulvic acid-like component (C3) in SRFA and SRHA. Results suggested that the underlying mechanism involving the fulvic acid-like component in SRFA more tending to complex with TMs to facilitate ROS generation through π electron transfer. Our work showed that the complexing ability and complexing stability of atmospheric PM organics with metals could significantly affect ROS generation. It is recommended that the research deploying multiple analytical methods to quantify the impact of PM components on public health and environment is needed in the future.     

活性艳红X-3B微波辅助光催化脱色的研究

研究了微波辅助光催化氧化(MW/UV/TiO2)处理活性艳红(X 3B)模拟废水。结果表明:400mg/LX 3B在反应150min时的脱色率由UV/TiO2体系的7.07%、MW体系的13.52%提高到了MW/UV/TiO2体系的56.35%。脱色反应速率随初始浓度(CX 3B)的增大而减慢;在强酸性介质中,脱色率更高;光照度(E)越强,越有利于X 3B脱色反应;改变催化剂投加量对X 3B脱色影响不大;H2O2浓度增加,X 3B脱色率升高;在以上条件下,X 3B的脱色反应均符合一级反应动力学方程,脱色反应中同时存在自由基反应与直接光解反应。     

Nitrogen removal in sequencing batch reactor

ＮｉｔｒｏｇｅｎｒｅｍｏｖａｌｉｎｓｅｑｕｅｎｃｉｎｇｂａｔｃｈｒｅａｃｔｏｒＷａｎｇＦｕｚｈｅｎ；ＰｅｎｇＹｏｎｇｚｈｅｎ；ＹｕＥｒｊｉｅ；ＬｉＢａｉｋｕｎ（ＨａｒｂｉｎＡｒｃｈｉｔｅｃｔｕｒａｌａｎｄＣｉｖｉｌＥｎｇｉｎｅｅｒｉｎｇＩｎｓｔｉｔｕ...