Using supercritical carbon dioxide as solvent to replace water in polyethylene terephthalate (PET) fabric dyeing procedures

Dyeing fabrics in supercritical carbon dioxide (SCD) instead of water can save energy, reduce water use and prevent pollution. The special pilot plant was designed to test dyeing procedures in supercritical carbon dioxide and the analyses of the results indicate major benefits as compared to water based procedures. The dyeing of polyethylene terephthalate (PET) fabric in supercritical carbon dioxide using special pilot plant was investigated. Disperse dye, C.I. (color index) Disperse Blue 79, was used in this study. After dyeing, rinsing in supercritical carbon dioxide, which removes the excess dyes, was also discussed. At the same dyeing conditions, K/S (color yield) of dyed fabric significantly increased with increasing the dye concentration from 1% o.w.f. (on weight of fabric) to 5% o.w.f. Dyeing temperature and pressure had a strong influence on the color yield. When the temperature rose above 110 °C, the increase in color yield was obvious. At 20 MPa, 120–130 °C, dyeing reached equilibrium after 60 min. The excess dye of the dyed PET fabric was small. The suitable condition in supercritical carbon dioxide for removal of excess dye from the dyed fabric was 70 °C, 20 MPa. The PET fabric dyed in supercritical carbon dioxide had good fastness and physical properties.     

甲烷吸附塔模拟装置阻火性能的实验研究

为了研究甲烷变压吸附提纯装置工作过程中的安全性,研制了甲烷吸附塔阻火性能模拟试验装置.通过改变吸附层厚度、空间位置和工作压力,测试点火引爆后的压力和温度,得到了爆炸火焰穿透介质层的规律,并按照各个因素对火焰穿透性能的影响建立了指数评价公式模型,根据该模型可以判断甲烷吸附塔内发生火焰传播的可能性.     

城市灾害风险等级评估流程的探讨及其实证研究

城市在社会发展的进程中起着主要作用,然而,城市灾害造成的严重后果已经对当今社会的发展构成了严重的阻碍,如何确定城市灾害总体风险等级并提出相应的对策措施亟需探讨。本文在分析城市常见四大类灾害(自然灾害、事故灾害、公共卫生灾害、社会安全灾害)的基础之上,进行城市灾害评估流程的介绍,包括灾害识别、灾害分析、灾害评价、提出对策措施,从而为城市灾害的总体等级的确定奠定初步的理论基础。以青岛市统计局相关资料为依据,对青岛市的城市灾害风险等级进行评估,确定其风险等级并提出相关建议措施。     

压裂返排液处理技术现状及展望

针对页岩气压裂返排液的特点、危害,综述了氧化-絮凝-过滤/吸附联合处理工艺、氧化-絮凝-电解-过滤/吸附联合处理工艺、氧化-絮凝-电解-过滤/吸附-生化联合处理工艺的特点、适用性及处理效果,经过多种工艺处理后,压裂返排液中COD等污染物可以有效去除,出水可以达标。并对压裂返排液处理技术的发展前景进行展望,认为回收重复利用是未来压裂返排液处理的发展趋势。     

基于知识流动和关系平台视角的临时性产业集群研究——以中国国际工业博览会为例

博览会作为一种临时性的产业集群,其作用多是为知识流动提供关系平台,因此需要以一个新的视角来研究博览会,其重要性不仅由企业的销售成果来体现,还应以获取行业知识和市场信息、拓展关系等方面进行衡量。分析了博览会的功能、行为主体的参会动机,并以中国国际工业博览会为例,研究了当今博览会的作用和关键功能。     

连续施用发酵猪粪对土壤中四环素抗性基因数量的影响

为了研究连续施用发酵猪粪之后,土壤中抗性基因的数量以及发酵猪粪的施用量对土壤抗性基因的影响,采用实时荧光定量PCR方法,对稻麦轮作模式下连续6年施用4.5t/hm2和9.0t/hm2发酵猪粪的土壤进行了四环素抗性基因(TRGs)的检测和定量分析.在施用发酵猪粪的土壤中能够检测到9种TRGs.施用发酵猪粪显著增加了土壤中tet G、tet L、tet B(P)、tet O、tet W的绝对数量,其中tet B(P)、tet W、tet O的绝对数量受到了施肥用量的影响;而tet Z、tet C和tet S的绝对数量则没有受到施肥的影响.上述8种TRGs在同一施肥处理的0~5cm、5~10cm以及10~20cm土壤中的相对丰度分布均无显著差异.发酵猪粪的施用也显著增加了tet G、tet L、tet B(P)和tet O的相对丰度,但是仅有tet O的相对丰度受到了施肥用量的显著影响.本研究表明,在稻麦轮作模式下,农田土壤中的TRGs数量会受到发酵猪粪中残留TRGs的影响,连续施用该粪肥会显著增加土壤中tet G、tet L、tet B(P)和tet O的绝对数量和相对丰度.因此,需要优化畜禽粪堆肥发酵工艺,以减少抗性基因在粪肥中的残留.     

基于流域视角的水环境综合治理规划研究——以江苏省淀山湖为例

以流域为单元进行水资源综合规划和管理是实现水环境改善的重要途径。本文以太湖流域第二大省界湖泊—淀山湖为例,在综合分析流域水环境质量基础上,利用GIS 分析工具划分流域治理片区并制定分区管控策略。根据流域所含骨干河流流向、骨干河流与淀山湖交汇特点、上中下游不同河段及镇域行政边界,将淀山湖流域分为吴淞江流域、千灯浦- 淀山湖流域、昆南湖荡流域、元荡湖荡流域、太浦河流域五大片区138 个子评价单元。通过水环境容量与压力两类空间叠加分析,构建形成污染重点减排区、污染综合治理区、产业绿色化提升区、生态环境保育区等四个类型区域,并提出差异化的产业准入和环境治理措施。本研究不仅为以流域为治理单元的水环境治理规划提供了较为可行的技术体系,而且为太湖流域水环境综合整治思路创新提供了可借鉴的案例。     

Quantitative analysis of riparian herbaceous community in Liaohe River Conservation Area and its tributaries北大核心CSCD

Research on community characteristics of riparian herbs is an important scientific basis of riparian vegetation rehabilitation. This study aimed to investigate the species diversity and quantitative characteristics of riparian herbs in Liaohe River Conservation Area and its tributaries. Herbaceous communities were investigated by sample line method. Group average clustering analysis and detrended correspondence analysis (DCA) were used to find the major environmental factors affecting the distribution pattern of riparian herbaceous communities. The result showed altogether 154 herbaceous species, belonging to 40 families and 96 genera. The riparian herbaceous species diversity was found to be correlated to river slope, sinuosity and stream order, being lower in rivers of mountain area than in rivers of plain area, and higher in tributaries than in Liaohe River Conservation Area. Clustering analysis classified the herbaceous communities into 23 types, being dominated by hygrophytes including communities of Echinochloa crusgalli, Oenanthe javanica, Polygonum hydropiper, Murdannia keisak, Artemisia selengensis, Scirpus triqueter, Heleocharis soloniensis, Pycreus sanguinolentus, Cyperus fuscus, Phragmites australis, Polygonum amphibium, Carex diandra + Artemisia selengensis and Carex diandra + Rorippa islandica. Correlation analysis between DCA ordination axes and environmental factors showed that the altitude, river slope, sinuosity and stream level were the major environmental factors affecting the distribution pattern of herbaceous communities in the riparian zone of Liaohe River Conservation Area and its tributaries. The results of CCA showed that the contribution ratio of stream level was the highest, followed by altitude and slope, with sinuosity the last. The results suggested that riparian herbaceous characteristics are affected by the comprehensive force of altitude, river slope, sinuosity and stream order, and that Calamagrostis epigeios, Triarrhena sacchariflora and Phragmites australis are suitable species for riparian vegetation rehabilitation.     

沿海城市多灾种耦合危险性评估的初步研究——以福建泉州为例

如何处理区域内多灾种之间的相互作用关系是当前多灾种综合风险评估研究的热点和难点之一。在梳理沿海城市多灾种之间相互作用关系的基础上,提出一种基于触发关系的多灾种耦合危险性评估方法。首先选取多指标建立单灾种分级方案,计算单灾种初始危险性指数;然后构建基于触发关系的多灾种耦合规则,结合GIS技术进行空间耦合,计算耦合后的危险性指数;最后对耦合后的多灾种危险性的综合进行了探讨。以福建省泉州市为例进行了案例研究,结果表明:该方法在多灾种耦合危险性评估中具有可行性,为后续多脆弱性和多灾种综合风险的研究提供支持,为决策者进行科学风险管理提供依据。     

应用概率物种敏感度分布法研究太湖重金属水生生物水质基准

目前广泛使用的水质基准推导方法—物种敏感度分布法存在曲线拟合模型不确定、曲线拟合效果不佳、种内差异欠考虑、基准值不准确等诸多问题,概率物种敏感度分布法可有效解决上述问题。应用概率物种敏感度分布法构建了太湖水体中5种重金属Ag、Pb、Cd、Hg和Zn的概率物种敏感度分布曲线,在此基础上得到了保护水生生物的急性水质基准分别为1.079μg·L~(-1)、637.973μg·L~(-1)、19.465μg·L~(-1)、8.729μg·L~(-1)和105.506μg·L~(-1),慢性水质基准分别为0.108μg·L~(-1)、63.797μg·L~(-1)、1.947μg·L~(-1)、2.340μg·L~(-1)和52.753μg·L~(-1);不同类群间生物对重金属的敏感度存在差异,不同重金属对同一类群生物的毒性也存在差异;通过与国内外已有的重金属水质基准值比较,发现水质基准具有明显的区域性,目前基于国外水质基准或我国整体水域特点来制定的太湖水质标准,往往造成对太湖水生生物欠保护或过保护的状况。