Fast screening compositions of PM2.5 by ATR-FTIR: Comparison with results from IC andOC/EC analyzers

Chemical speciation of fine particles or PM_(2.5) collected on filters is still a costly and timeconsuming task. In this study, filter-based PM_(2.5) samples were collected during November–December 2013 at four sites in Guangzhou, and the major components were fast screened(~7 min per filter sample) by Attenuated Total Reflectance(ATR)-Fourier Transform Infrared Spectroscopic(FTIR) in comparison with that measured by Organic carbon/Element carbon(OC/EC) analyzer and Ion Chromatography(IC). The concentrations of nitrate, ammonium, sulfate,primary organic carbon(POC) and secondary organic carbon(SOC) measured by OC/EC and IC analyzers were better correlated with their infrared absorption peak heights at 1320 cm~(-1) for nitrate, 1435, 3045 and 3215 cm~(-1) for ammonium, 615 cm~(-1) for sulfate, 690, 760 and 890 cm~(-1) for POC and 1640 and 1660 cm~(-1) for SOC respectively, during polluted days(PM_(2.5) 75 μg/m~3) than during clean days(PM_(2.5)≤ 75 μg/m~3). With the evolution of a haze episode during our field campaign, the concentrations of the major PM_(2.5) components displayed consistent variations with their infrared absorption peak heights, suggesting ATR-FTIR could be a fast and useful technique to characterize filter-based PM_(2.5) compositions particularly during pollution events although cautions should be taken when PM_(2.5) levels are low. Notably, elevated PM_(2.5) mass concentrations occurred with enhanced ratios of [NO_(-3)]/[SO_4~(2-)] and [NH~(+4)]/[SO_4~(2-)], implying that nitrogenous components play vital roles in the PM_(2.5) pollution events in the study region.     

纤维素酶的研究进展

利用微生物降解纤维素是当前处理纤维素废弃物最有效的方法。文章对此方面的研究情况作了系统的汇总，阐述了3种不同的纤维素酶（C1酶、Cx酶，纤维二糖酶）的提取，性质及测定方法，分析了现有研究中存在的问题，并对今后的研究趋势作了预测和展望。     

红碱淖生态环境质量评估及对策研究

红碱淖是中国最大、最年轻的沙漠淡水湖,水域面积67平方公里。通过数据收集统计及打分计算的方式对红碱淖水环境质量、生态环境质量、水生态健康进行定量分析,结果表明,红碱淖水环境质量从1981年至2010年有逐渐恶化的趋势;2010年红碱淖生态系统健康综合指数为59.86,属于中等水平,已经受到了一定影响;生态质量综合评价值为81.6分,具有较高的保护价值。并对造成红碱淖水质和生态系统逐步恶化的原因进行解析,同时提出相应的对策。     

人工湿地净化滇池入湖河道污水的示范工程研究

采用复合型人工湿地示范工程系统进行净化处理滇池入湖河道污水的研究,结果表明该系统对处理滇池入湖河道污水具有良好的适用性。在系统正常运行状态下,其对所处理河道污水中CODMn、BOD5、TN、TP的去除率分别最高可达6 7%、74 %、83%、6 5 %。     

经济改革背景下中国城市用地扩展的时空格局及其驱动因素分析

改革开放以来,中国进入了快速城市化发展时期.本文利用高分辨率陆地卫星(Landsat TM/ETM)遥感影像数据,监测了中国城市用地扩展态势,并分析了影响中国城市用地扩展的驱动因素.研究表明1990～2000年,中国城市用地扩展表现出明显的时空分异态势,城市用地增长了近82万hm2,其中前5年的扩展占80.8%,后5年的扩展占19.2%,后5年的扩展规模明显低于前5年.研究还发现,城市用地主要以同心圆模式、飞地模式、轴向扩展模式与多极核扩展模式以及4种扩展模式的组合模式扩张.本文选取13个特大城市作为典型案例,对其城市用地扩展的驱动机制进行了研究,研究发现,人口增长、经济发展以及土地管理法规政策的变化是影响城市用地扩展的主要因素.     

火焰原子吸收法测定废水中的钴

研究采用硝酸-高氯酸消解样品,用火焰原子吸收分光光度法测定废水中钴的方法.通过标准样品和实验样品的分析,验证了方法的准确度和精密度.方法的加标回收率为94.0％ ～ 108.0％,检出限为0.010mg/L.该方法简单可靠,干扰少,适合废水分析.     

Adsorption–desorption behavior of atrazine on agricultural soils in China

Adsorption and desorption are important processes that affect atrazine transport,transformation,and bioavailability in soils.In this study,the adsorption–desorption characteristics of atrazine in three soils(laterite,paddy soil and alluvial soil) were evaluated using the batch equilibrium method.The results showed that the kinetics of atrazine in soils was completed in two steps:a"fast" adsorption and a "slow" adsorption and could be well described by pseudo-second-order model.In addition,the adsorption equilibrium isotherms were nonlinear and were well fitted by Freundlich and Langmuir models.It was found that the adsorption data on laterite,and paddy soil were better fitted by the Freundlich model;as for alluvial soil,the Langmuir model described it better.The maximum atrazine sorption capacities ranked as follows:paddy soil alluvial soil laterite.Results of thermodynamic calculations indicated that atrazine adsorption on three tested soils was spontaneous and endothermic.The desorption data showed that negative hysteresis occurred.Furthermore,lower solution pH value was conducive to the adsorption of atrazine in soils.The atrazine adsorption in these three tested soils was controlled by physical adsorption,including partition and surface adsorption.At lower equilibrium concentration,the atrazine adsorption process in soils was dominated by surface adsorption;while with the increase of equilibrium concentration,partition was predominant.     

电锅炉技术及其应用对环境影响的分析研究

针对电锅炉技术及其应用对环境影响,以绿色电力能源代替煤、油、气等常规化石能源,减少因化石能源在城镇人群聚集区终端使用造成"雾霾"类大气污染,已经成为一种新的发展趋势.本文系统分析了电锅炉的常用技术,分别阐述了不同种类电锅炉的技术原理、技术特点、工艺流程、应用领域,并通过实际应用案例,分析了电锅炉技术推广应用对城镇人口聚集区环境污染改善的效果,最后提出电锅炉技术的应用建议,为推行电锅炉技术选型提供依据,保证绿色环境的生成.     

气质联用法测定空气中挥发性有机物的方法研究

通过美国Entech公司Summa罐采集大气样品,7100型大气预浓缩系统提取和富集样品中的挥发性有机物,省去了繁琐的有机物提取和净化工序,避免和有机溶剂接触,将样品直接输入气质联机进行分析。利用这种方法定性分析了某油罐区的大气成分,结果表明该地区大气中含有成分复杂的环己烷、苯和萘的衍生物,这些化合物的浓度远远大于居民区同类化合物的含量。     

Effects of synthesis methods on catalytic activities of CoOx–TiO2 for low-temperature NH3-SCR of NO

A series of cobalt doped TiO_2(Co-TiO_2) and Co Oxloaded TiO_2(Co/TiO_2) catalysts prepared by sol–gel and impregnation methods respectively were investigated on selective catalytic reduction with NH_3(NH_3-SCR) of NO. It was found that Co-TiO_2 catalyst showed more preferable catalytic activity at low temperature range. From characterization results of XRD,TEM, Raman and FT-IR, Co species were proved to be doped into TiO_2 lattice by replaced Ti atoms. After being characterized and analyzed by NH_3-TPD, PL, XPS, EPR and DRIFTS, it was found that the better NH_3-SCR activities of Co-TiO_2 catalysts, compared with Co/TiO_2 catalyst, were ascribed to the formation of more oxygen vacancies which further promoted the production of more superoxide ions(O-2). The superoxide ions were crucial for the formation of low temperature SCR reaction intermediates(NO-3) by reacting with adsorbed NO molecule. Therefore, these aspects were responsible for the higher low temperature NH_3-SCR activity of Co-TiO_2 catalysts.