Determination of 15 phthalate esters in air by gas-phase and particle-phase simultaneous sampling

Based on previous research, the sampling and analysis methods for phthalate esters (PAEs) were improved by increasing the sampling flow of indoor air from 1 to 4 L/min, shortening the sampling duration from 8 to 2 hr. Meanwhile, through the optimization of chromatographic conditions, the concentrations of 9 additional PAE pollutants in indoor air were measured. The optimized chromatographic conditions required a similar amount of time for analysis as before, but gave high responsivity, the capability of simultaneously distinguishing 15 kinds of PAEs, and a high level of discrimination between individual sample peaks, as well as stable peak generation. The recovery rate of all gas-phase and particle-phase samples of the 15 kinds of PAEs ranged from 91.26% to 109.42%, meeting the quantitative analysis requirements for indoor and outdoor air sampling and analysis. For the first time, investigation of the concentration levels as well as characteristics of 15 kinds of PAEs in the indoor air from four different traffic micro-environments (private vehicles, busses, taxis and subways) was carried out, along with validation of the optimized sampling and analytical method. The results show that all the 9 additional PAEs could be detected at relatively high pollution levels in the indoor air from the four traffic micro-environments. As none of the pollution levels of the 15 kinds of PAEs in the indoor air from the 4 traffic micro-environments should be neglected, it is of great significance to increase the types of PAEs able to be detected in indoor air.     

Quantifying public health benefits of environmental strategy of PM2.5 air quality management in Beijing–Tianjin–Hebei region, China

In 2013,China issued "Air Pollution Prevention and Control Action Plan(Action Plan)" to improve air quality.To assess the benefits of this program in Beijing-Tianjin-Hebei(BTH)region,where the density of population and emissions vary greatly,we simulated the air quality benefit based on Ben MAP to satisfy the Action Plan.In this study,we estimate PM_(2.5) concentration using Voronoi spatial interpolation method on a grid with a spatial resolution of 1 × 1 km~2.Combined with the exposure-response function between PM_(2.5) concentration and health endpoints,health effects of PM_(2.5) exposure are analyzed.The economic loss is assessed by using the willingness to pay(WTP) method and human capital(HC) method.When the PM_(2.5) concentration falls by 25% in BTH and reached 60 μg/m~3 in Beijing,the avoiding deaths will be in the range of 3175 to 14051 based on different functions each year.Of the estimated mortality attributable to all causes,3117 annual deaths were due to lung cancer,1924 – 6318 annual deaths were due to cardiovascular,and343 – 1697 annual deaths were due to respiratory.Based on WTP,the estimated monetary values for the avoided cases of all cause mortality,cardiovascular mortality,respiratory mortality and lung cancer ranged from 1110 to 29632,673 to 13325,120 to 3579,1091 to 6574 million yuan,respectively.Based on HC,the corresponding values for the avoided cases of these four mortalities were 267 to 1178,161 to 529,29 to 143 and 261 million yuan,respectively.     

Mesoporous carbon nanomaterials induced pulmonary surfactant inhibition, cytotoxicity, inflammation and lung fibrosis

Environmental exposure and health risk upon engineered nanomaterials are increasingly concerned. The family of mesoporous carbon nanomaterials(MCNs) is a rising star in nanotechnology for multidisciplinary research with versatile applications in electronics,energy and gas storage, and biomedicine. Meanwhile, there is mounting concern on their environmental health risks due to the growing production and usage of MCNs. The lung is the primary site for particle invasion under environmental exposure to nanomaterials. Here, we studied the comprehensive toxicological profile of MCNs in the lung under the scenario of moderate environmental exposure. It was found that at a low concentration of 10 μg/mL MCNs induced biophysical inhibition of natural pulmonary surfactant. Moreover, MCNs at similar concentrations reduced viability of J774 A.1 macrophages and lung epithelial A549 cells.Incubating with nature pulmonary surfactant effectively reduced the cytotoxicity of MCNs.Regarding the pro-inflammatory responses, MCNs activated macrophages in vitro, and stimulated lung inflammation in mice after inhalation exposure, associated with lung fibrosis.Moreover, we found that the size of MCNs played a significant role in regulating cytotoxicity and pro-inflammatory potential of this nanomaterial. In general, larger MCNs induced more pronounced cytotoxic and pro-inflammatory effects than their smaller counterparts. Our results provided valuable information on the toxicological profile and environmental health risks of MCNs, and suggested that fine-tuning the size of MCNs could be a practical precautionary design strategy to increase safety and biocompatibility of this nanomaterial.     

闲置厌氧氨氧化微生物的启动及微生物分析

文章以闲置12个月的厌氧氨氧化生物膜填料重新启动厌氧氨氧化反应器,并对反应器的活性恢复情况、脱氮效果和微生物菌群结构开展研究。实验结果表明:在启动的200 d逐渐将进水氨氮、亚硝态氮浓度从50 mg/L提高到70 mg/L,水力停留时间从12 h缩短到4 h,后期氨氮去除率达80%以上,亚硝酸盐去除率达95%。170~200 d的稳定期中,平均去除负荷0.71±0.15 kg/(m~3·d)。另外,通过高通量测序技术对反应器中微生物群落变化情况进行了系统分析。启动过程中填料中污泥微生物浮霉菌门Planctomyctes的相对丰度从13.7%增长到了36.0%,成为优势菌群。     

Increasing the application of gas engines to decrease China’s GHG emissions

This paper employs a review of the technical literature to estimate the potential decrease in greenhouse gas (GHG) emissions that could be achieved by increasing the application of gas engines in China in three sectors: urban public transport vehicle; shipping; and thermal power plants. China’s gas engine development strategies and three types of gas resource are discussed in the study, which indicates that gas engines could decrease GHG emissions by 520 megatonnes (Mt) of carbon dioxide equivalent (CO_2e) by 2020. This would account for 9.7 % of the government’s target for decreasing GHG emissions and is dominated by methane recovery from the use of coal mine gas (CMG) and landfill gas (LFG) for power generation. In the public urban transport vehicle and shipping sectors the low price of natural gas and the increasing demand for the control of harmful emissions could spur the rapid uptake of gas engine vehicles. However, the development of CMG- and LFG-fuelled power plants has been limited by the unwillingness of local enterprises to invest in high-performance gas engine generators and the associated infrastructure. Therefore, further compulsory policies that promote CMG use and LFG recovery should be implemented. Moreover, strict regulations on limiting methane leakage during the production and distribution of gas fuels are urgently needed in China to prevent leakage causing GHG emissions and largely negating the climate benefits of fuel substitution. Strategies for increasing the application of gas engines, promoting gas resources and recovering methane in China are instrumental in global GHG mitigation strategies.     

石化行业有机液体储罐VOCs损耗估算方法浅析

总结了实测法、公式法、模型法等国内外石化行业有机液体储罐VOCs排放估算方法的主要特点和适用范围;运用公式法估算国内某石化企业典型油品储罐的VOCs排放量;分析了在我国直接套用美国环保署(EPA)开发的TANKS模型存在的问题;根据估算方法的实际应用研究,就美国AP-42源强手册第五版第七章(chapter 7:Liquid storage tank)中评价公式的"本土化"提出相关的建议。     

外浮顶原油储罐VOCs泄漏损耗及排放量核算

介绍了国内外浮顶原油储罐VOCs泄漏损耗形式。结合美国环保署(EPA)发布的AP-42中第7章储罐的VOCs相关排放公式,建立了外浮顶原油储罐VOCs排放量核算的方法,并对核算方法的应用进行了举例分析,有助于掌握现阶段原油外浮顶储罐的泄漏损耗量,为推进企业绿色低碳发展,控制原油储罐VOCs总量排放提供参考。     

炼化企业分析化验岗位职业病危害防治措施研究

采用现场职业卫生学调查方法了解炼化企业分析化验岗位接触各类危害因素情况,对正常情况下分析化验工作场所进行各类职业病危害因素检测,同时测量各通风橱控制点风速、排风罩罩口风速;通风橱(风机通风量增加、管道改造)以及排风罩改造后,再次进行控制点风速测量、工作场所危害因素采样检测,对比改造前后测量数据,探讨分析化验岗位职业病危害防治措施。结果显示,工作场所通风设施的风机选型、管道合理化布置、排风罩围挡的设置、补风等因素均对通风橱、排风罩控制点风速产生影响;通风设施改造后工作场所职业病危害因素浓度有所降低。由此可见,炼化企业分析化验工作场所通风设施是职业病危害防治的重要措施。     

FMEA和HAZOP在煤气柜风险分析中的综合应用

将故障类型和影响分析(FMEA)和危险和可操作性研究(HAZOP)相结合,对某电石生产企业的煤气柜设备和其涉及到的工艺的风险性进行了系统安全分析,并根据分析结果提出了针对性的控制措施。这两种分析方法各有所长,从不同角度系统全面地分析了潜在风险中的不安全因素,使其分析结果更加可靠、实用。     

炼化企业VOCs排放现状及治理对策

简要介绍了挥发性有机物(VOCs)的定义及危害,分析了炼化企业的VOCs排放现状,并简要介绍了VOCs有组织和无组织排放的种类。介绍了中国石化济南分公司延迟焦化装置和柴油加氢装置针对有组织排放和无组织排放开展的各种治理措施及LDAR检测开展情况。