Pollution profiles and physicochemical parameters in old uncontrolled landfills

The long-term effectiveness of the geological barrier beneath municipal-waste landfills is a critical issue for soil and groundwater protection. This study examines natural clayey soils directly in contact with the waste deposited in three landfills over 12 years old in Spain. Several physicochemical and geological parameters were measured as a function of depth. Electrical conductivity (EC), water-soluble organic carbon (WSOC), Cl⁻, NH₄⁺, Na⁺ and exchangeable NH₄⁺ and Na⁺ were used as parameters to measure the penetration of landfill leachate pollution. Mineralogy, specific surface area and cationic-exchange capacities were analyzed to characterize the materials under the landfills. A principal component analysis, combined with a Varimax rotation, was applied to the data to determine patterns of association between samples and variables not evident upon initial inspection. The main factors explaining the variation in the data are related to waste composition and local geology. Although leachates have been in contact with clays for long time periods (13-24 years), WSOC and EC fronts are attenuated at depths of 0.2-1.5 m within the clay layer. Taking into account this depth of the clayey materials, these natural substrata (>45% illite-smectite-type sheet silicates) are suitable for confining leachate pollution and for complying with European legislation. This paper outlines the relevant differences in the clayey materials of the three landfills in which a diffusive flux attenuation capacity (A_c) is defined as a function (1) of the rate of decrease of the parameters per meter of material, (2) of the age and area of the landfill and (3) of the quantity and quality of the wastes.     

An integrative negotiation model to deal with conflicts toward water resources management: a case study in Brazil

Environment, Development and Sustainability - An integrative negotiation model is proposed so that watershed committees (WSC) can deal better with conflicts over alternatives for protecting water...     

Polishing of painting process effluents through adsorption with biochar from winemaking residues

Environmental Science and Pollution Research - A real industrial effluent from the pre-treatment and painting processes was polished through adsorption using alternative biochar derived from grape...     

A review of the main methods for composite adsorbents characterization

Environmental Science and Pollution Research - Adsorption is a promising technology for removing several contaminants from aqueous matrices. In the last years, researchers worldwide have been...     

Preparation and characterization of biochar from cement waste for removal of rhodamine B dye

Journal of Material Cycles and Waste Management - Cement waste (CW) is one of the main environmental problems in the cement industry due to the high amount that is used and its incorrect disposal....     

Effects of oil contamination on plant growth and development: a review

Environmental Science and Pollution Research - Oil spills generate several environmental impacts and have become more common with the increase in petroleum extraction, refining, transportation, and...     

The potential of animal manure management pathways toward a circular economy: a bibliometric analysis

Environmental Science and Pollution Research - Improper disposal of animal waste is responsible for several environmental problems, causing eutrophication of lakes and rivers, nutrient overload in...     

Enhancing the visible-light photoactivity of silica-supported TiO2 for the photocatalytic treatment of pharmaceuticals in water

Environmental Science and Pollution Research - Catalyst samples based on SiO2-supported TiO2 were prepared with the incorporation of Ag (metal), S (nonmetal), and ZnO@S (semiconductor and...     

ATR-FTIR Spectroscopy Combined with Chemometric Methods for the Classification of Polyethylene Residues Containing Different Contaminants

Journal of Polymers and the Environment - Low density polyethylene (LDPE) and high density polyethylene (HDPE) are the principal plastics present in solid plastic waste and are found out as the...     

Bioactive Material with Microorganisms can Enhance the Micronutrients Solubilization and Sulfate Availability from Low Reactive Sources: Insight for Application as Coating Fertilizer Granules

Journal of Polymers and the Environment - Fertilization is essential to provide suitable conditions for plant development and crop productivity, but the environmental cost of fertilizers is a...