Biological and chemical analysis of the toxic potency of pesticides in rainwater.

A newly developed method for measuring the integrated esterase inhibiting potency of rainwater samples was applied in practice, and the results are compared to the toxic potency calculated from concentrations of 31 organophosphate (OP) and carbamate pesticides, out of a total of 66 chemically analyzed pesticides. In addition, the general toxic potency of the rainwater samples was evaluated in a microtiter luminescence assay with Vibrio fischeri bacteria. Rainwater samples were collected over four consecutive 14-day periods in both open and wet-only samplers. The esterase inhibiting potency of the open rainwater samples (expressed as ng dichlorvos-equivalents/l) corresponded well with the chemical analyses of the rainwater samples collected by both types of samplers (r = 0.83-0.86). By far, the highest esterase inhibiting potency was found in a sample collected in an area with intense horticultural activities in June, and was attributed to high concentrations of dichlorvos, mevinphos, pirimiphos-methyl and methiocarb. The esterase inhibiting potency of this sample was equivalent to a dichlorvos concentration of 1380 ng/l in the rainwater, which is almost 2000 times higher than the maximum permissible concentration (MPC) of dichlorvos set for surface water in Netherlands. Maximum individual concentrations of dichlorvos and pirimiphos-methyl even exceeded the EC50 for Daphnia, suggesting that pesticides in rainwater pose a risk for aquatic organisms. Not all responses of the luminescence-assay for general toxicity could be explained by the analyzed pesticide concentrations. The bio-assays enable a direct assessment the toxic potency of all individual compounds present in the complex mixture of rainwater pollutants, even if they are unknown or present at concentrations below the detection limit. Therefore, they are valuable tools for prescreening and hazard characterization purposes.     

Adaptation options in agriculture to climate change: a typology

Adaptation in agriculture to climate change is important for impact andvulnerability assessment and for the development of climate change policy. A wide variety of adaptation options has been proposed as having thepotential to reduce vulnerability of agricultural systems to risks related toclimate change, often in an ad hoc fashion. This paper develops atypology of adaptation to systematically classify and characterize agriculturaladaptation options to climate change, drawing primarily on the Canadiansituation. In particular, it differentiates adaptation options in agricultureaccording to the involvement of different agents (producers, industries,governments); the intent, timing and duration of employment of theadaptation; the form and type of the adaptive measure; and the relationshipto processes already in place to cope with risks associated with climatestresses. A synthesis of research on adaptation options in Canadianagriculture identifies four main categories: (i) technological developments,(ii) government programs and insurance, (iii) farm production practices,and (iv) farm financial management. In addition to these `directadaptations', there are options, particularly information provision, that maystimulate adaptation initiatives. The results reveal that most adaptationoptions are modifications to on-going farm practices and public policydecision-making processes with respect to a suite of changing climatic(including variability and extremes) and non-climatic conditions (political,economic and social). For progress on implementing adaptations to climatechange in agriculture there is a need to better understand the relationshipbetween potential adaptation options and existing farm-level andgovernment decision-making processes and risk management frameworks.     

Behaviour of horses and cattle at two stocking densities in a coastal salt marsh

Livestock grazing has been practiced in salt marshes in the Wadden Sea area since 600 B.C. Currently livestock grazing is also applied for conservation management. However, effects of such grazing management on salt marshes are likely to vary depending on the species of livestock and stocking density due to differences in the behaviour of the animals. Yet, little is known about the behaviour of different livestock species and stocking densities grazing in salt marshes. We studied the grazing behaviour of horses and cattle by focal observation in an experiment with four different grazing treatments on a coastal salt marsh. In all treatments we recorded diet choice, movement and grazing activity, and spatial distribution. Livestock species shared an overlap in diet choice. Yet, horses more often foraged on the short grass Puccinellia maritima, while the cattle diet contained a higher amount of Aster tripolium. Horses travelled longer distances per day and spent more time grazing than cattle. Spatial distribution of cattle was significantly clustered, while horses showed a random distribution utilizing the whole area. Animal behaviour differs between livestock species and stocking densities with respect to diet choice, activity and spatial distribution.     

The status and importance of crude protein and macro minerals in native pastures growing on Vertisols of the central highlands of Ethiopia

The effects of pasture management, season and soil nutrient status on crude protein (CP) and macro mineral concentration of native pasture was studied in the Vertisol areas of the central Ethiopian highland. Soil and herbage samples from 18 continuously grazed (CG) and 12 seasonally grazed (SG) pasture sites were analyzed for N, P, Ca, Mg, K and Na. Soil and dry season CG pasture samples were collected in January and February 2001 (dry season: November-February), while wet season CG and SG pasture samples were collected during September 2001 (wet season: April-October). The Potassium concentration (2.55%) of mixed herbage samples from SG pasture exceeded the K values (1.80%) from CG pasture (P?相似文献   

Stewardship to tackle global phosphorus inefficiency: The case of Europe

The inefficient use of phosphorus (P) in the food chain is a threat to the global aquatic environment and the health and well-being of citizens, and it is depleting an essential finite natural resource critical for future food security and ecosystem function. We outline a strategic framework of 5R stewardship (Re-align P inputs, Reduce P losses, Recycle P in bioresources, Recover P in wastes, and Redefine P in food systems) to help identify and deliver a range of integrated, cost-effective, and feasible technological innovations to improve P use efficiency in society and reduce Europe’s dependence on P imports. Their combined adoption facilitated by interactive policies, co-operation between upstream and downstream stakeholders (researchers, investors, producers, distributors, and consumers), and more harmonized approaches to P accounting would maximize the resource and environmental benefits and help deliver a more competitive, circular, and sustainable European economy. The case of Europe provides a blueprint for global P stewardship.     

Validation of road vehicle and traffic emission models – A review and meta-analysis

Road transport is often the main source of air pollution in urban areas, and there is an increasing need to estimate its contribution precisely so that pollution-reduction measures (e.g. emission standards, scrapage programs, traffic management, ITS) are designed and implemented appropriately. This paper presents a meta-analysis of 50 studies dealing with the validation of various types of traffic emission model, including ‘average speed’, ‘traffic situation’, ‘traffic variable’, ‘cycle variable’, and ‘modal’ models. The validation studies employ measurements in tunnels, ambient concentration measurements, remote sensing, laboratory tests, and mass-balance techniques. One major finding of the analysis is that several models are only partially validated or not validated at all. The mean prediction errors are generally within a factor of 1.3 of the observed values for CO₂, within a factor of 2 for HC and NO_x, and within a factor of 3 for CO and PM, although differences as high as a factor of 5 have been reported. A positive mean prediction error for NO_x (i.e. overestimation) was established for all model types and practically all validation techniques. In the case of HC, model predictions have been moving from underestimation to overestimation since the 1980s. The large prediction error for PM may be associated with different PM definitions between models and observations (e.g. size, measurement principle, exhaust/non-exhaust contribution).Statistical analyses show that the mean prediction error is generally not significantly different (p < 0.05) when the data are categorised according to model type or validation technique. Thus, there is no conclusive evidence that demonstrates that more complex models systematically perform better in terms of prediction error than less complex models. In fact, less complex models appear to perform better for PM. Moreover, the choice of validation technique does not systematically affect the result, with the exception of a CO underprediction when the validation is based on ambient concentration measurements and inverse modelling. The analysis identified two vital elements currently lacking in traffic emissions modelling: 1) guidance on the allowable error margins for different applications/scales, and 2) estimates of prediction errors. It is recommended that current and future emission models incorporate the capability to quantify prediction errors, and that clear guidelines are developed internationally with respect to expected accuracy.     

Rangeland dynamics in southern Ethiopia: (3). Assessment of rangeland condition in relation to land-use and distance from water in semi-arid Borana rangelands

The condition of the semi-arid Borana rangeland in southern Ethiopia was assessed by studying different land-use systems (communal land, a government ranch and a traditional grazing reserve enclosure) and along a distance gradient (near, middle and far) from water sources. The assessment incorporated the soil, herbaceous and woody plant layers. Two methods were employed to evaluate the grass layer, viz. ecological condition index (ECI) and weighted palatability composition (WPC). The ECI on the government ranch was 21.7% and 26% greater than that of the traditional reserve and the communal land, respectively. The WPC on the government ranch was 83.3% and 48.6% greater than that of the communal area and the traditional reserve, respectively. Both ECI and WPC values were similar for all distance sites from water. Tree equivalent (TE) density, of all encroaching woody plants combined, was higher on the communal land (504 TE ha(-1)) than the government ranch (373 TE ha(-)1) and traditional grazing reserve (118 TE ha(-1)), but with no marked variations in the distance sites from water. Height class distribution of encroaching woody plants in the study areas showed the largest abundance (range: >50-100%) at the height class >0-2m. Tree equivalents per hectare of encroaching woody plants were negatively correlated (r = -0.60) with ECI and WPC and positively correlated (r=0.87) with percentage bare ground. The correlation (r = 0.50) between percentage bare ground and soil compaction was positive and low. Although the government ranch had a greater composition of highly palatable grass species than the other land uses, the rangeland was not in good condition due to severe bush encroachment. The communal land was generally in poor condition. In the traditional grazing reserve, bush encroachment was not a problem, but the productivity of the grass layer was poor when assessed on the basis of ecological and palatability merits. The negative interaction of TE density of all encroaching woody plants combined with ECI or WPC and the positive interaction with bare ground, may suggest that the abundance of these species is more critical in aggravating deterioration in grassland productivity. Therefore, the priority of any bush control program must be towards minimizing the abundance of these woody plants.     

Antibiotika als Umweltkontaminanten — Effekte auf Bodenbakterien

Goal and scope

Among the human and veterinary pharmaceuticals, antibiotics form an important group. Recent research addressed the environmental ‘side effects’ of antibiotics. Evidence for environmental effects of antibiotics has for example been found for the respiratory activity of soil microorganisms. In the present contribution, results of studies on the ecotoxicology of antibiotics that are based on the utilization of carbon substrates in so-called Biolog plates are summarized.

Methods, Results and Conclusions

The method of pollution-induced community tolerance (PICT) takes centre stage. PICT is based on the changes in community composition of environmental communities brought about by a toxicant, which lead to an overall increase in community tolerance to this toxicant. The suitability of such an increase in community tolerance as ecotoxicological endpoint had been the subject of several experiments. It was shown that effect testing of antibiotics requires supplementation of the communities with nutrients, and that the PICT method reveals antibiotic effects with a high specificity. In an application of PICT, effects of three classes of antibacterial compounds were investigated. Dose-response relationships were obtained for all substances, and effect concentrations were partly in the range of expected environmental concentrations. The possible risks of antibiotic use for an increase in the occurrence of antibiotic resistance genes in the environment are also touched upon, including the extent of natural resistance.

Outlook

Due to its specificity, the PICT method has shown to be a suitable ecotoxicological assay. Due to possible effects of tetracyclines on the structure of the soil microbial community, it is advised to use veterinary antibiotics with caution. The risks of an increase in the occurrence of antibiotic resistance in the environment should be investigated in more detail.     

How knowledge is used in collaborative environmental governance: water classification in New Brunswick,Canada

Collaboration is an increasingly important approach to dealing with complex environmental challenges. Participation of diverse actors in collaborative processes necessitates attention to the use of different forms of knowledge. We use a multi-case study of governance for water in New Brunswick, Canada, to explore knowledge-related concerns that are prominent in collaborative processes. As is common in other contexts, local or lay (experiential) forms of knowledge appeared to play complementary but ultimately subordinate roles to expert technical and scientific knowledge in the cases. Importantly, we found that the distinction between ‘expert’ and ‘local’ knowledge was not at all clear for the many participants. This study reinforces the importance of designing reflexive and flexible processes for encouraging the active engagement and use of knowledge in collaboration.