Challenges in quantifying biosphere-atmosphere exchange of nitrogen species

Recent research in nitrogen exchange with the atmosphere has separated research communities according to N form. The integrated perspective needed to quantify the net effect of N on greenhouse-gas balance is being addressed by the NitroEurope Integrated Project (NEU). Recent advances have depended on improved methodologies, while ongoing challenges include gas-aerosol interactions, organic nitrogen and N(2) fluxes. The NEU strategy applies a 3-tier Flux Network together with a Manipulation Network of global-change experiments, linked by common protocols to facilitate model application. Substantial progress has been made in modelling N fluxes, especially for N(2)O, NO and bi-directional NH(3) exchange. Landscape analysis represents an emerging challenge to address the spatial interactions between farms, fields, ecosystems, catchments and air dispersion/deposition. European up-scaling of N fluxes is highly uncertain and a key priority is for better data on agricultural practices. Finally, attention is needed to develop N flux verification procedures to assess compliance with international protocols.     

Effects of marine biofouling on gas sensor membrane materials

The use of underwater gaseous sensors has increased rapidly in the last 10 years. The majority of such sensors employ a thin membrane through which the gas diffuses. These sensors are potentiometric gas-sensing probes and essentially they are ion-selective electrodes. The deployment time of these membranes is curtailed by the formation of biofouling on the membrane leading to erroneous results. The physical properties of a variety of commonly used membranes were investigated using SEM and AFM. This showed that there were differences in topography between the PTFE membranes, such as pore sizes and surface roughness, which may be attributed to the manner in which they are manufactured. The pore size of the PTFE membranes varied greatly, ranging from circular pores with a diameter of 500 nm to elongated pores measuring 1 x 22 microm. The contact angle of each membrane showed that they were all hydrophobic. The amount of fouling on each was also observed and its affect on oxygen diffusion was monitored. Fouling slowed down the response of the instrument and caused reduced diffusion through the membranes. The amount of fouling varied between the membranes with the YSI membrane fouling least. Some of the membranes tested did foul less than others and there could be lifetime advantages of choosing a membrane with a smoother surface and a small pore size.     

Preparation and evaluation of candidate certified reference materials (CRMs) for nutrients in seawater

Certified reference materials (CRMs) are an essential part of the quality assurance (QA) necessary for the reliable analytical measurement of nutrients in seawater. The CRMs currently available for these analyses are not matrix matched to marine samples. QUASIMEME routinely produces test materials for the nutrients in seawater and nutrients in estuarine water and low-salinity open water Laboratory Performance Studies (LPS) that are both homogeneous and stable. QUASIMEME, in conjunction with Eurofins Scientific, Denmark have produced two reference materials (RMs). The homogeneity testing and preliminary stability studies were carried out by QUASIMEME, and the results are presented in this article. Participants of the QUASIMEME LPS who demonstrated satisfactory long-term performance for the analysis of nutrients in seawater and nutrients in estuarine water and low-salinity open water were invited to take part in the certification exercise. Twenty laboratories returned data, a summary of which is also presented. The certification and long-term stability testing and additional data analysis were carried out by Eurofins Scientific, Denmark, and are outwith the scope of this article and not reported here. Eurofins Scientific, Denmark have marketed these RMs as part of their range of VKI Reference Materials (further information is available from eurofins@eurofins.dk).     

Incompatible Land Uses and the Topology of Cumulative Risk

The extensive literature on environmental justice has, by now, well defined the essential ingredients of cumulative risk, namely, incompatible land uses and vulnerability. Most problematic is the case when risk is produced by a large aggregation of small sources of air toxics. In this article, we test these notions in an area of Southern California, Southeast Los Angeles (SELA), which has come to be known as Asthmatown. Developing a rapid risk mapping protocol, we scan the neighborhood for small potential sources of air toxics and find, literally, hundreds of small point sources within a 2-mile radius, interspersed with residences. We also map the estimated cancer risks and noncancer hazard indices across the landscape. We find that, indeed, such large aggregations of even small, nondominant sources of air toxics can produce markedly elevated levels of risk. In this study, the risk profiles show additional cancer risks of up to 800 in a million and noncancer hazard indices of up to 200 in SELA due to the agglomeration of small point sources. This is significant (for example, estimates of the average regional point-source-related cancer risk range from 125 to 200 in a million). Most importantly, if we were to talk about the risk contour as if they were geological structures, we would observe not only a handful of distinct peaks, but a general “mountain range” running all throughout the study area, which underscores the ubiquity of risk in SELA. Just as cumulative risk has deeply embedded itself into the fabric of the place, so, too, must intervention seek to embed strategies into the institutions and practices of SELA. This has implications for advocacy, as seen in a recently initiated participatory action research project aimed at building health research capacities into the community in keeping with an ethic of care.     

Characteristics that make trophy hunting of giant pandas inconceivable

In November 1928, Theodore Jr. and Kermit Roosevelt led an expedition to China with the expressed purpose of being the first Westerners to kill the giant panda (Ailuropoda melanoleuca). The expedition lasted 8 months and resulted in the brothers shooting a giant panda in the mountains of Sichuan Province. Given the concurrent attention in the popular press describing this celebrated expedition, the giant panda was poised to be trophy hunted much like other large mammals around the world. Today, however, the killing of giant pandas, even for the generation of conservation revenue, is unthinkable for reasons related to the species itself and the context, in time and space, in which the species was popularized in the West. We found that the giant panda's status as a conservation symbol, exceptional charisma and gentle disposition, rarity, value as a nonconsumptive ecotourism attraction, and endemism are integral to the explanation of why the species is not trophy hunted. We compared these intrinsic and extrinsic characteristics with 20 of the most common trophy-hunted mammals to determine whether the principles applying to giant pandas are generalizable to other species. Although certain characteristics of the 20 trophy-hunted mammals aligned with the giant panda, many did not. Charisma, economic value, and endemism, in particular, were comparatively unique to the giant panda. Our analysis suggests that, at present, exceptional characteristics may be necessary for certain mammals to be excepted from trophy hunting. However, because discourse relating to the role of trophy hunting in supporting conservation outcomes is dynamic in both science and society, we suspect these valuations will also change in future.     

Evaluation of the National Land Cover Database for Hydrologic Applications in Urban and Suburban Baltimore,Maryland1

Smith, Monica Lipscomb, Weiqi Zhou, Mary Cadenasso, Morgan Grove, and Lawrence E. Band, 2010. Evaluation of the National Land Cover Database for Hydrologic Applications in Urban and Suburban Baltimore, Maryland. Journal of the American Water Resources Association (JAWRA) 46(2):429-442. DOI: 10.1111/j.1752-1688.2009.00412.x Abstract: We compared the National Land Cover Database (NLCD) 2001 land cover, impervious, and canopy data products to land cover data derived from 0.6-m resolution three-band digital imagery and ancillary data. We conducted this comparison at the 1 km², 9 km², and gauged watershed scales within the Baltimore Ecosystem Study to determine the usefulness and limitations of the NLCD in heterogeneous urban to exurban environments for the determination of land-cover information for hydrological applications. Although the NLCD canopy and impervious data are significantly correlated with the high-resolution land-cover dataset, both layers exhibit bias at <10 and >70% cover. The ratio of total impervious area and connected impervious area differs along the range of percent imperviousness – at low percent imperviousness, the NLCD is a better predictor of pavement alone, whereas at higher percent imperviousness, buildings and pavement together more resemble NLCD impervious estimates. The land-cover composition and range for each NLCD urban land category (developed open space, low-intensity, medium-intensity, and high-intensity developed) is more variable in areas of low-intensity development. Fine-vegetation land-cover/lawn area is incorporated in a large number of land use categories with no ability to extract this land cover from the NLCD. These findings reveal that the NLCD may yield important biases in urban, suburban, and exurban hydrologic analyses where land cover is characterized by fine-scale spatial heterogeneity.     

The Effects of Some Air Pollutants and Meteorological Conditions on Airborne Algae and Protozoa

The purpose of this investigation was to determine the effects of meteorological conditions and specific air pollutants on the viability of airborne algae and protozoa. Such investigations will be of interest to medical researchers because these organisms are the source of many allergies. The three air pollutants that were continuously measured and recorded were sulfur, hydrocarbons, and particulate maiter. During the experiment, 25 different species of algae and 19 species of protozoa were collected from the atmosphere and cultured at the Westinghouse Environmental Station Laboratory in Raleigh, North Carolina. The algae and protozoa were collected over a one-year period (Jan-Dec 1971) by using a sequential sampler that moved air through a membrane filter at the rate of 15 ft³/hr. Every two hours a new filter was sequentially moved in to replace the old one. The results indicated a relationship between wind speed, wind direction, temperature, dew-point, particulate matter, barometric pressure, and rainfall to the percent frequency of positive culture tubes and number of cells/ft³ of air. Further studies are necessary to determine the interrelationships between the physical and chemical character of various air masses and their effect on the survival of algae and protozoa.     

Improvement of Ambient Sulfur Dioxide Concentrations by Conversion from Low to High Stacks

A study of the “before” and “after” ground-level S0₂ concentrations near the Muskingum River Plant of the American Electric Power System shows that the conversion from low to high stacks has accomplished marked reductions in ambient concentrations. These reductions are in reasonable agreement with theoretical calculations and are most apparent within 5 km of the source. EPA Standards are now being met in this area despite the presence of the 1440 MW power plant burning 5% sulfur fuel with no treatment of the stack gas.     

Results of Field Measurements of Industrial Particulate Sources and Electrostatic Precipitator Performance

This paper presents results of source size distribution measurements over the size range from 0.1 μm to 5 μm for six classes of particulate sources and fractional efficiency measurements on five full scale electrostatic precipitators and one pilot scale precipitator. The precipitators all showed moderately high to high particulate collection efficiencies for particles having diameters larger than a few micrometers or smaller than a few hundredths of a micrometer and a minimum in collection efficiency for particles having diameters of a few tenths of a micrometer.     

A Comparison of Mass,Lead, Sulfate,and Nitrate Concentrations in a Field Study Using Dichotomous,Size-Selective,and Standard Hi-Vol Samplers

Air monitoring In the San Francisco Bay Area was carried out to measure outdoor community air concentrations of poly cyclic aromatic hydrocarbons (PAH) and mutagenlc activity (mutagenlclty) In participate organic matter (POM). Monitoring began In 1979 and Is currently conducted at six stations. PAH and mutagenlclty tests were performed on organic extracts prepared from high volume (hl-vol) filters composited every four months, by meteorological season. PAH were determined by high pressure liquid chromatography (HPLC) with fluorescence and ultraviolet detection. Mutagenlclty was measured In the Ames Salmonella bloas-say using strain TA98 with and without metabolic activation. The nine-year mean concentration of benzo(a)pyrene (BaP) was 0.4 ng/m³. The mutagenlcfty of this amount of BaP accounted for only about 0.2% of the observed mutagenicity In POM and other measured PAH accounted for even less. Concentrations of PAH and mutagenlclty were three to nine times higher during the winter than during other seasons. Year-to-year wintertime trends In several PAH were also seen. Early In the 1980s, winter concentrations of BaP and benzo (g,h,i)perylene Increased. However since the mld-1980’s, their concentrations have fallen. The decrease In PAH concentrations may be the result of an Increasing proportion of vehicles with relatively low organic emissions. In contrast to PAH, mutagenlcfty did not show significant year-to-year time trends.