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61.
62.
The leachability of some metals (Al, As, Ba, Ca, Cr, Cu, Fe, K, Mg, Mn, Ti, Zn) from fly ashes was studied in the presence of ethylenediamine tetraacetic acid (EDTA) and naturally occurring complexing agents-humic acids (HAs). Secondary complex-forming equilibria taking place in the leachates increase significantly the leached amounts of most metals. Kinetic experiments showed that almost the whole "available" amounts of metals are leached from fly ash within a time period of several hours (mostly within 20 h), with exceptions of matrix constituents (typically aluminium), which are released more slowly. 相似文献
63.
Olga S. Arvaniti Marilena E. Dasenaki Alexandros G. Asimakopoulos Niki C. Maragou Vasilios G. Samaras Korina Antoniou Georgia Gatidou Daniel Mamais Constantinos Noutsopoulos Zacharias Frontistis Nikolaos S. Thomaidis Athanasios S. Stasinakis 《Frontiers of Environmental Science & Engineering》2022,16(11):148
64.
Estimation of end of life mobile phones generation: the case study of the Czech Republic 总被引:2,自引:0,他引:2
The volume of waste electrical and electronic equipment (WEEE) has been rapidly growing in recent years. In the European Union (EU), legislation promoting the collection and recycling of WEEE has been in force since the year 2003. Yet, both current and recently suggested collection targets for WEEE are completely ineffective when it comes to collection and recycling of small WEEE (s-WEEE), with mobile phones as a typical example. Mobile phones are the most sold EEE and at the same time one of appliances with the lowest collection rate. To improve this situation, it is necessary to assess the amount of generated end of life (EoL) mobile phones as precisely as possible. This paper presents a method of assessment of EoL mobile phones generation based on delay model. Within the scope of this paper, the method has been applied on the Czech Republic data. However, this method can be applied also to other EoL appliances in or outside the Czech Republic. Our results show that the average total lifespan of Czech mobile phones is surprisingly long, exactly 7.99 years. We impute long lifespan particularly to a storage time of EoL mobile phones at households, estimated to be 4.35 years. In the years 1990-2000, only 45 thousands of EoL mobile phones were generated in the Czech Republic, while in the years 2000-2010 the number grew to 6.5 million pieces and it is estimated that in the years 2010-2020 about 26.3 million pieces will be generated. Current European legislation sets targets on collection and recycling of WEEE in general, but no specific collection target for EoL mobile phone exists. In the year 2010 only about 3-6% of Czech EoL mobile phones were collected for recovery and recycling. If we make similar estimation using an estimated average EU value, then within the next 10 years about 1.3 billion of EoL mobile phones would be available for recycling in the EU. This amount contains about 31 tonnes of gold and 325 tonnes of silver. Since Europe is dependent on import of many raw materials, efficient recycling of EoL products could help reduce this dependence. To set a working system of collection, it will be necessary to set new and realistic collection targets. 相似文献
65.
Holubová Šmejkalová Adéla Zíková Naděžda Ždímal Vladimír Plachá Helena Bitter Miroslav 《Environmental science and pollution research international》2021,28(11):13352-13364
Environmental Science and Pollution Research - Highly time-resolved particle number size distributions (PNSDs) were evaluated during 5 years (2013–2017) at four background stations in the... 相似文献
66.
Thirty different white rot strains were screened for Orange G and Remazol Brilliant Blue R (RBBR) decolorization on agar plates. Three promising strains, Dichomitus squalens, Ischnoderma resinosum and Pleurotus calyptratus, selected on the basis of this screening, were used for decolorization study in liquid media. All three strains efficiently decolorized both Orange G and RBBR, but they differed in decolorization capacity depending on cultivation conditions and ligninolytic enzyme production. Two different decolorization patterns were found in these strains: Orange G decolorization in I. resinosum and P. calyptratus was caused mainly by laccase, while RBBR decolorization was effected by manganese peroxidase (MnP); in D. squalens laccase and MnP cooperated in the decolorization processes. 相似文献
67.
The photochemistry of selected organic compounds, including common pollutants, on the paraffin (as a model matrix) and spruce wax surfaces was studied under laboratory conditions. Two model transformations were evaluated: (1) intramolecular rearrangements of valerophenone and 2-nitrobenzaldehyde, and (2) hydrogen abstraction between an excited benzophenone and the hydrocarbon paraffin/wax chains. The steric or polar influence of the solid matrix on conformational and translational motion, its optical properties, hydrogen abstraction probabilities, and consequences of the guest-molecule segregation are discussed in this work. Furthermore, the photochemical reactivity of some common anthropogenic pollutants, such as chlorinated biphenyls (4-chlorobiphenyl, 2,4-dichlorobiphenyl, and 4,4'-dichlorobiphenyl), 4-chlorophenol, and DDT, was evaluated. The surface of spruce wax is presented as probable reaction medium for photochemical transformations. Although the matrix presents certain restrictions for bimolecular reactions, common photodegradations should be generally feasible in nature. In addition, paraffin was found to be a suitable model matrix for the studies of possible photochemical transformations that can occur on natural plant surfaces. 相似文献
68.
Hogrefe O Schwab JJ Drewnick F Lala GG Peters S Demerjian KL Rhoads K Felton HD Rattigan OV Husain L Dutkiewicz VA 《Journal of the Air & Waste Management Association (1995)》2004,54(9):1040-1060
Several collocated semicontinuous instruments measuring particulate matter with particle sizes < or =2.5 microm (PM2.5) sulfate (SO4(2-)) and nitrate (NO3-) were intercompared during two intensive field campaigns as part of the PM2.5 Technology Assessment and Characterization Study. The summer 2001 urban campaign in Queens, NY, and the summer 2002 rural campaign in upstate New York (Whiteface Mountain) hosted an operation of an Aerosol Mass Spectrometer, Ambient Particulate Sulfate and Nitrate Monitors, a Continuous Ambient Sulfate Monitor, and a Particle-Into-Liquid Sampler with Ion Chromatographs (PILS-IC). These instruments provided near real-time particulate SO4(2-) and NO3- mass concentration data, allowing the study of particulate SO4(2-)/NO3- diurnal patterns and detection of short-term events. Typical particulate SO4(2-) concentrations were comparable at both sites (ranging from 0 to 20 microg/m3), while ambient urban particulate NO3- concentrations ranged from 0 to 11 microg/m3 and rural NO3- concentration was typically less than 1 microg/m3. Results of the intercomparisons of the semicontinuous measurements are presented, as are results of the comparisons between the semicontinuous and time-integrated filter-based measurements. The comparisons at both sites, in most cases, indicated similar performance characteristics. In addition, charge balance calculations, based on major soluble ionic components of atmospheric aerosol from the PILS-IC and the filter measurements, indicated slightly acidic aerosol at both locations. 相似文献
69.
Blubber biopsy and blood samples were collected from weaned grey seal pups and juveniles in 1998 and 1999. The relationship between the concentration of total PDBEs in the blubber and the circulating concentrations of serum proteins, minerals and thyroid hormones was investigated. Fifty-four post-weaned pups were sampled and 55 first year juveniles, of which 13 were recaptured post-weaned pups. The median concentration of total PBDEs in the pups' blubber was 170 and 460 ng g(-1) in the first-year animals. Total blubber PBDEs contributed significantly to the prediction of circulating thyroid hormone concentrations, after controlling for age and condition. Cholesterol and albumin concentrations were also positively related to blubber PBDEs. The results of this study suggest a link between thyroid hormones and exposure to PBDEs in grey seals during their first year of life. Such an association is not alone sufficient evidence for a cause and effect relationship, however it is in accordance with the hypothesis that these compounds are endocrine disrupters in grey seal pups. 相似文献
70.
A study of the biodegradability of nonionogenic surfactants of oxyethylenated n-butyl, isobutyl, n-pentyl and isopentyl alcohols was conducted by modified static test according to International Standard Organization method 9888. Degradation was evaluated by changes in concentrations of individual oligomers, ethylene glycols, carboxylic and dicarboxylic acids. Good biological degradability was found, with a "primary" degradability of 75-98% in 10 days. Obtained results, in agreement with our previous work, proved the dominant proportion of degradative scission in the hydrophile part of surfactant molecule. During biological degradation no significant cumulation of mono- to polyethylene glycols appeared neither that of mono- or dicarboxylic acids, and degradation of these components was not a rate-determining degradation factor. 相似文献