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A three component model of organizational commitment was used to study job withdrawal intentions, turnover and absenteeism. Affective commitment emerged as the most consistent predictor of these outcome variables and was the only view of commitment related to turnover and to absenteeism. In contrast, normative commitment was related only to withdrawal intentions while no direct effects for continuance commitment were observed. Continuance commitment, however, interacted with affective commitment in predicting job withdrawal intentions and absenteeism. The form of the interaction was such that high sunk costs tempered relationships between affective commitment and the relevant outcome variables.  相似文献   
13.
Quantifying chemical variability in different lake types is important for the assessment of both chemical and biological responses to environmental change. For monitoring programs that emphasize a large number of lakes at the expense of frequent samples, high variability may influence how representative single samples are of the average conditions of individual lakes. Intensive temporal data from long-term research sites provide a unique opportunity to assess chemical variability in lakes with different characteristics. We compared the intra- and inter-annual variability of four acidification related variables (Gran alkalinity, pH, sulphate concentration, and total base cation concentration) in four lakes with different flushing rates and acid deposition histories. Variability was highest in lakes with high flushing rates and was not influenced by historic acid deposition in our study lakes. This has implications for the amount of effort required in monitoring programs. Lakes with high flushing rates will require more frequent sampling intervals than lakes with low flushing rates. Consideration of specific lake types should be included in the design of monitoring programs.  相似文献   
14.
Cormorant eggs and lipid samples from juvenile Cormorants were analyzed for 14 organochlorine contaminants. Low concentrations (geometric mean < 0.05 microg/g) of hexachlorobenzene (HCB), lindane, oxy-chlordane, heptachlor epoxide, dieldrin, endrin, mirex, DDD and DDT in eggs primarily reflected the wintering-ground origin of organochlorine contaminants. Overall geometric mean concentrations of DDE and PCBs in Cormorant eggs were 3.90 and 2.22 microg/g egg respectively, and would not affect reproduction or eggshell thickness. Eggshells averaged 0.44 mm in thickness and no correlation (r2 = 0.17) with log-transformed DDE residues in Cormorant eggs was evident. Only DDE and PCBs were detected in lipid samples from 5- to 8-week-old Cormorants (geometric mean approximately 1.0 microg/g lipid for each compound). The PCB: DDE ratios in Cormorant lipid from some individual colonies were 2-3.5 times greater than the ratio in eggs from the same colony, suggesting an accumulation of PCBs related to local diet. Juvenile Cormorants might serve as regional indicators of chemical residue contamination in Alberta, and provide a temporal perspective on changes in contaminant burdens in aquatic ecosystems.  相似文献   
15.
Spatial analysis of land use impact on ground water nitrate concentrations   总被引:1,自引:0,他引:1  
In spatial analyses of causes or health effects of environmental pollutants, small units of analyses are usually preferred for internal environmental homogeneity reasons but can only be done when fine resolution data are available for most units. Objectives of this study were to determine which land use practices were spatially associated with ground water nitrate concentrations across Prince Edward Island (PEI), Canada, and which spatial aggregation is the preferred unit of analyses. Nitrate concentrations were determined for 4855 samples from private wells. Validated field-by-field land use data were available. Average nitrate concentration and percentage of area for the 14 major land use categories in PEI were determined for each of three spatial aggregations: watersheds based on topography and hydrology; freeform polygon boundaries based on similar neighboring nitrate concentrations; and 500-m buffer zones around each well. Results showed that the percentages of potato, grain, and hay coverage were positive predictors of ground water nitrate concentrations. Percentage of blueberry was a marginally significant negative predictor in the watershed and freeform polygon models, and percentage of residential coverage was a positive predictor in the freeform polygon and buffer zone models. Spatial autocorrelation was present in the freeform polygon and buffer zone models even after land use was taken into account. In conclusion, analyses based on watersheds produced the best predictive model with the percentages of land cover of potato, hay, and grain being significantly associated with ground water nitrate concentrations, and the percentages of blueberry, clear-cut woodland, and other agriculture being marginally significant.  相似文献   
16.
Despite initial enthusiasm for using survival analysis techniques to gain new insights into employee turnover, nearly one decade later hardly any studies based on survival methodologies are evident in the literature. Consequently, the potential for survival analysis to open new avenues in turnover research remains unassessed, and the need for research on this topic is readily apparent. In this study, survival analysis methods were compared with those inherent in ‘traditional’ turnover research. Results indicated significant divergences between these two methods. The traditional turnover methodology reproduced findings characteristic of the vast majority of research on this topic—job withdrawal intentions emerged as the sole predictor of employee turnover behavior. In contrast, continuance commitment and ethnicity were directly predictive of turnover behavior using survival analysis methods. Implications of these results and directions for future research are discussed. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   
17.
Abstract: The effects of water level fluctuations on fish and other aquatic biota, with an emphasis on winter water withdrawal in northern regions is reviewed. Water demands for population growth and development are adding pressure on water reserves, particularly when coupled with changing climatic conditions. Water level fluctuations can have adverse effects on the environment, most notably to hydrologic and biotic processes ranging in magnitude from the micro‐scale to landscape level. Water level management of lakes and reservoirs can affect all forms of aquatic biota. The severity of effect is dependant on the magnitude, duration and timing of the fluctuation, and the species exposed. In northwestern Canada and northern Alaska, water is withdrawn from water bodies to construct ice‐roads and other winter based developments. Biota in small, isolated water bodies are particularly sensitive to reductions in winter water levels. Water withdrawals can reduce the oxygen available to overwintering fish, while reduced water levels can reduce habitat for fish and furbearers, and freeze littoral areas killing plants, invertebrates, and fish eggs. Regulatory winter water withdrawal thresholds have been developed in the Northwest Territories and Alaska and continue to be refined as new data becomes available. The use of thresholds can help minimize or avoid negative impacts to the environment, particularly fish, from winter water withdrawal activities. Many different factors may influence the effect that winter water withdrawal has on a water body, such as basin shape, substrate and location. More research is warranted to better understand the linkages between anthropogenic and natural water level fluctuations and their combined effect on aquatic ecosystems. A general decision support system is proposed for minimizing risk to aquatic life from winter water withdrawal activities.  相似文献   
18.
The information presented in this paper is directed to persons concerned with control of exhaust odors from diesel-engine-powered vehicles. This paper summarizes projects sponsored by the Environmental Protection Agency (EPA) over the past years in the field of diesel-exhaust odor. These investigations have concentrated on developing measurement methods for quantifying different odor levels, evaluating various odor control methods, and evaluating public opinions of such odors.

A human panel method using odor reference standards has been found suitable to measure these odor levels. In addition to this technique, chemical characterization work has been sponsored under a project jointly sponsored by the Coordinating Research Council and the EPA to isolate and identify those species responsible for the odor.

Knowledge of these odorous compounds and the techniques necessary to isolate them should lead to development of a chemical method to measure this type of odor, in place of human panelists. Such basic information would also lead to developing control techniques to minimize this odor.

Several control techniques were evaluated for diesel exhaust odor. To date, the most effective method is an improved needle injector for use in the Detroit Diesel type E 6V-71 engine commonly used in buses.

Finally, public reaction to diesel-engine-exhaust odor has been measured. It has been found that a systematic relationship exists between increasing public objections and increasing diesel odor intensity.  相似文献   
19.
The body of information presented in this paper is directed towards engineers in the field of environmental sciences involved in measuring and/or evaluating the emissions from a variety of diesel engines or vehicles. This paper summarizes recent data obtained by EPA on identification and quantification of different emissions (i.e. characterization) from a variety of diesel engines.

Extensive work has been done comparing emissions from some light duty diesel and gasoline passenger cars. The work on the diesel vehicles was expanded to include tests with five different diesel fuels to determine how fuel composition affects emissions. This work showed that use of a poorer quality fuel frequently made emissions worse. The investigation of fuel composition continued with a project in which specific fuel parameters were systematically varied to determine their effect on emissions. EPA is presently testing a variety of fuels derived from coal and oil shale to determine their effects on emissions.

EPA has also tested a heavy duty Volvo diesel bus engine designed to run on methanol and diesel fuel, each injected through its own injection system. The use of the dual fuel resulted in a reduction in particulates and NO x but an increase in HC and CO compared to a baseline Volvo diesel engine running on pure diesel fuel.

Finally, some Ames bioassay tests have been performed on samples from the diesel passenger cars operated on various fuels and blends. An increase in Ames test response (mutagenicity) was seen when the higher aromatic blend was used and also when a commercial cetane improver was used. Samples from the Volvo diesel bus engine fueled with methanol and diesel fuel showed that use of a catalyst increased the Ames response.  相似文献   
20.
Purple coneflower plants (Echinacea purpurea) were placed into open-top chambers (OTCs) for 6 and 12 weeks in 2003 and 2004, respectively, and exposed to charcoal-filtered air (CF) or twice-ambient (2x) ozone (O3) in 2003, and to CF, 2x or non-filtered (NF), ambient air in 2004. Plants were treated with ethylenediurea (EDU) weekly as a foliar spray. Foliar symptoms were observed in >95% of the plants in 2x-treated OTCs in both years. Above-ground biomass was not affected by 2x treatments in 2003, but root and total-plant biomass decreased in 2004. As a result of higher concentrations of select cell wall constituents (% ADF, NDF and lignin) nutritive quality was lower for plants exposed to 2x-O3 in 2003 and 2004 (26% and 17%, respectively). Significant EDU x O3 interactions for concentrations of cell wall constituents in 2003 indicated that EDU ameliorated O3 effects on nutritive quality. Interactions observed in 2004 were inconsistent.  相似文献   
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