计算机软件模拟油罐火灾对环境的影响

通过应用火灾模拟软件FDS,建立了某油库稳定燃烧的数学模型,并研究了在风速为8 m/s的实验条件下,油罐发生火灾时,火焰的发展状况,以及燃烧过程所产生的二氧化碳、一氧化碳和灰尘随时间的变化规律.     

一起氯乙烯压缩机缸盖破裂事故分析

采用故障树分析法剖析了引起氯乙烯气体压缩机缸盖破裂的因素,根据现场查证掌握的信息,分析确定了事故的原因、爆炸着火的源点及引爆源,提出了防止氯乙烯气体压缩机类似事故的安全措施。     

阴离子粘土(LDH)吸附腐殖酸的动力学研究

利用实验室制备的镁铝阴离子粘土材料,研究其吸附水中腐殖酸的动力学.研究结果表明:在初始浓度10～40 mg/L及温度298～323 K的范围内,阴离子粘土对水中腐殖酸的吸附动力学符合拟二级速率方程;阴离子粘土对腐殖酸的吸附符合Langmuir和Freundlich等温吸附方程,吸附是吸热反应,吸附量随温度升高而略有增加,但吸附表观活化能只有15.36 kJ/mol,说明温度对此吸附的影响并不显著.     

利用化学沉淀法降低焦化废水氨氮浓度的预处理工艺研究

为了有效净化高浓度氨氮工业废水,采用向废水中投加MgCl2·6H2O和Na3PO4·12H2O生成磷酸氨镁沉淀的方法,以去除其中的高浓度氨氮。结果表明,在pH值为9.0,Mg^2＋、NH4^＋、PO4^3-的摩尔比为1.2：1：0.9,反应温度为25℃,反应时间为20 min,沉淀时间为50 min的条件下,氨氮质量浓度可由3 100 mg/l降低到56mg/l,去除率达到98%以上,为后续生化处理创造了条件。     

生活污水的厌氧生物处理研究进展

生活污水处理是中国面临急待解决的环境问题。分析厌氧反应器的分类与特点及去污机理,与其它污水处理技术比较,总结出生活污水采用厌氧生物法处理具有投资少、运行费用低、出水水质好、操作简单等优点。对厌氧反应器在生活污水处理的应用前景进行了展望。     

开发区环境管理指标体系研究

开发区环境管理指标体系研究是建立开发区环境管理综合体系的基础性工作,也是考核开发区生态环境建设与管理效果的定量评价工具。本文在探讨环境管理指标体系的确定原则、选择和量化等基础上。提出了一套包括环境保护指标、循环经济指标、绿色管理指标和相关性指标四类指标在内的环境管理综合指标体系。并将该指标体系应用于杭州钱江经济开发区的环境管理实践。结果表明,杭州钱江经济开发区的环境管理完善程度总得分为74．6％,总体上还有待进一步完善,特别是ISO14001管理体系认证和环境质量改善等方面有待进一步加强。     

澳大利亚地方政府开展环保教育的做法及特点

以获得2004年澳大利亚国家奖励的地方政府有关项目为典型,对澳大利亚地方政府如何进行环保宣传教育进行分析。澳大利亚地方政府重视并积极开展环保教育,教育对象有儿童、学生、政府机构和社区以及企业各行各业的人群,内容有环保知识、技能和情报信息等,教育宣传方式、渠道及组织形式多样,并发动多方参与、广泛合作,为推进环保和可持续发展奠定了基础。     

Occurrence and distribution of organochlorine pesticides - lindane, p,p'-DDT, and heptachlor epoxide - in surface water of China

Persistent organochlorine pesticides pollutants (OCPs) have been reported to occur at relatively high concentrations in some Chinese waters. In order to map the distribution of organochlorine pesticides in the surface water throughout China, samples were collected from over 600 sites in seven major river basins and three main internal rivers drainage areas during 2003 and 2004. The surface water samples were analyzed for the representative organochlorine pesticides contaminants including lindane (gamma-HCH), p,p'-DDT and heptachlor epoxide. In general, the most frequently detected compound was lindane, being detected in 83.9% of samples (mean=31.3 ng/l; range <0.17-860 ng/l), and the highest concentration was present in the Yellow River basin. p,p'-DDT was detected in 63.1% of the samples collected (mean=14.6 ng/l; range <0.14-368 ng/l) with the highest concentration present in the Huaihe River basin. Heptachlor epoxide was detected in only 9.3% of water samples (range <0.11-10 ng/l). Measured concentrations for the three compounds were low and rarely exceed the environment quality standard for surface water of China. Lindane was more frequently detected at much higher concentrations in the rivers of northern China compared with those of southern China. The sites with higher concentration of lindane and p,p'-DDT mainly occurred in the Yellow River and Huaihe River basins, so the results of this investigation indicate that the organochlorine pesticide contamination of Yellow River and Huaihe River basins should be of particular concern relative to the other basins. When compared with other regions of the world, it appears that the Chinese surface water is moderately polluted by lindane and p,p'-DDT.     

Simulating mesoscale transport and diffusion of radioactive noble gases using the Lagrangian particle dispersion model

In order to simulate the impact of mesoscale wind fields and to assess potential capability of atmospheric Lagrangian particle dispersion model (LPDM) as an emergency response model for the decision supports, two different simulations of LPDM with the mesoscale prognostic model MM5 (Mesoscale Model ver. 5) were driven. The first simulation of radioactive noble gas ((85)Kr exponent) emitted during JCO accident occurred from 30 September to 3 October 1999 at Tokai, Japan showed that the first arriving short pulse was found in Tsukuba located at 60km away from the accidental area. However, the released radioactive noble gas was transported back to the origin site about 2 days later due to the mesoscale meteorological wind circulation, enhancing the levels of (85)Kr with the secondary peak in Tsukuba. The second simulation of atmospheric dilution factors (the ratio of concentration to the emission rate, chi/Q), during the underground nuclear test (UNT) performed by North Korea showed that high chi/Q moved to the eastward and extended toward southward in accordance with the mesoscale atmospheric circulations generated by mesoscale prognostic model MM5. In comparison with the measurements, the simulated horizontal distribution patterns of (85)Kr during the JCO are well accord with that of observation in Tsukuba such as the existence of secondary peak which is associated with the mesoscale circulations. However, the simulated level of (85)Kr anomaly was found to be significantly lower than the observations, and some interpretations on these discrepancies were described. Applications of LPDM to two mesoscale emergency response dispersion cases suggest the potential capability of LPDM to be used as a decision support model provided accurate emission rate of accident in case of a large accident.