全文获取类型
收费全文 | 913篇 |
免费 | 51篇 |
国内免费 | 265篇 |
专业分类
安全科学 | 59篇 |
废物处理 | 58篇 |
环保管理 | 70篇 |
综合类 | 465篇 |
基础理论 | 202篇 |
污染及防治 | 264篇 |
评价与监测 | 38篇 |
社会与环境 | 37篇 |
灾害及防治 | 36篇 |
出版年
2024年 | 1篇 |
2023年 | 19篇 |
2022年 | 46篇 |
2021年 | 34篇 |
2020年 | 29篇 |
2019年 | 33篇 |
2018年 | 33篇 |
2017年 | 41篇 |
2016年 | 40篇 |
2015年 | 38篇 |
2014年 | 65篇 |
2013年 | 76篇 |
2012年 | 74篇 |
2011年 | 68篇 |
2010年 | 54篇 |
2009年 | 58篇 |
2008年 | 41篇 |
2007年 | 49篇 |
2006年 | 36篇 |
2005年 | 37篇 |
2004年 | 31篇 |
2003年 | 34篇 |
2002年 | 40篇 |
2001年 | 25篇 |
2000年 | 29篇 |
1999年 | 32篇 |
1998年 | 41篇 |
1997年 | 23篇 |
1996年 | 17篇 |
1995年 | 21篇 |
1994年 | 13篇 |
1993年 | 6篇 |
1992年 | 9篇 |
1991年 | 10篇 |
1990年 | 6篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1986年 | 4篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 3篇 |
1977年 | 2篇 |
1969年 | 1篇 |
排序方式: 共有1229条查询结果,搜索用时 62 毫秒
961.
Raymond R. Tan Denny K.S. Ng Dominic C.Y. Foo Kathleen B. Aviso 《Process Safety and Environmental Protection》2009,87(3):197-205
This paper presents a novel superstructure-based optimization model for the synthesis of industrial water networks with partitioning regenerators. Such regenerators function by splitting a contaminated water stream into a regenerated lean stream and a low-quality reject stream. Membrane separation-based processes are examples of these types of regenerators. The optimization model presented in this work integrates a single, centralized partitioning regenerator with a source–demand superstructure under the assumption that the processes within the plant are of the fixed flow rate type. The formulation is non-linear as a result of the presence of bilinear terms in the regenerator balance equations, but global optimal solutions can be found using commercial software. The features of the model are illustrated by solving case studies from the literature. It is notable from these examples that considerable design flexibility exists in networks of this type, since potentially both the lean and reject streams from the partitioning regenerator can be reused/recycled within the plant. 相似文献
962.
臭氧/ 生物活性炭深度处理循环养殖废水 总被引:5,自引:0,他引:5
随着工厂化循环水养殖的不断发展,高浓度循环养殖废水对环境污染日益严重.为实现环境友好和资源节约,采用臭氧/生物活性炭对循环养殖废水进行深度处理中试研究.实验结果表明,臭氧化臭氧最佳投加量为4 mg/L,显著增强水体的可生化性,使TOC(总有机碳)/UV254(在波长为254 nm处的单位比色皿光程下的紫外吸光度)提高80%.臭氧/生物活性炭对循环养殖废水中的有机物和氨氮具有良好的去除效果.臭氧/生物活性炭对TOC、高锰酸盐指数和UV254的最终去除率比生物活性炭分别高11.9%、13.4%和6.5%.臭氧/生物活性炭和生物活性炭对氨氮的最终去除率分别为96.0%、90.7%. 相似文献
963.
Chao He Yunshan Ge Jianwei Tan Kewei You Xunkun Han Junfang Wang Qiuwen You Asad Naeem Shah 《Atmospheric environment (Oxford, England : 1994)》2009,43(24):3657-3661
The characteristics of carbonyl compounds emissions were investigated on a direct injection, turbocharged diesel engine fueled with pure biodiesel derived from soybean oil. The gas-phase carbonyls were collected by 2,4-dinitrophenylhydrazine (DNPH)-coated silica cartridges from diluted exhaust and analyzed by HPLC with UV detector. A commercial standard mixture including 14 carbonyl compounds was used for quantitative analysis. The experimental results indicate that biodiesel-fueled engine almost has triple carbonyls emissions of diesel-fueled engine. The weighted carbonyls emission of 8-mode test cycle of biodiesel is 90.8 mg (kW h)?1 and that of diesel is 30.7 mg (kW h)?1. The formaldehyde is the most abundant compound of carbonyls for both biodiesel and diesel, taking part for 46.2% and 62.7% respectively. The next most significant compounds are acetaldehyde, acrolein and acetone for both fuels. The engine fueled with biodiesel emits a comparatively high content of propionaldehyde and methacrolein. Biodiesel, as an alternative fuel, has lower specific reactivity (SR) caused by carbonyls compared with diesel. When fueled with biodiesel, carbonyl compounds make more contribution to total hydrocarbon emission. 相似文献
964.
超声破解吸持稠油粘土颗粒的研究 总被引:2,自引:0,他引:2
在频率为28 kHz的超声辐照下,研究了超声作用功率和辐照时间对石油污染土壤淋洗液中吸持稠油粘土颗粒的破解作用,并采用GC/MS分析了超声辐照时间对淋洗液中特征有机物的影响。结果表明,随着超声作用功率和辐照时间的增加,粘土颗粒吸持的稠油显著下降,辐照时间为45 min,作用功率为100 W时,粘土颗粒吸持稠油的解吸率为7925%;作用功率为60 W,辐照时间为75 min时,粘土颗粒吸持稠油的解吸率为77.36%。超声波能够显著增加解吸稠油在水中的溶解率,辐照时间为45 min,作用功率为80 W时,水相含油率升高92%;当作用功率为60 W,辐照时间为75 min时,水相含油率升高近1倍。随着超声辐照时间的增加,极性相对较强的环烷酮类有机物的相对丰度随之增加,极性相对较弱的环烷二酮类有机物相对丰度则显著减小。超声波有利于异位化学淋洗在高含粘土颗粒石油污染土壤修复中的应用。 相似文献
965.
Modelling of the fate of selected endocrine disruptors in a municipal wastewater treatment plant in South East Queensland, Australia 总被引:3,自引:0,他引:3
The aim of this study was to develop a fugacity-based analysis of the fate of selected industrial compounds (alkylphenols and phthalates) with endocrine disrupting properties in a conventional activated sludge wastewater treatment plant (WWTP A) in South East Queensland, Australia. Using mass balance principles, a fugacity model was developed for correlating and predicting the steady-state-phase concentrations, the process stream fluxes, and the fate of four phthalates and four alkylphenols in WWTP A. Input data are the compound's physicochemical properties, measured concentrations and the plant's operating design and parameters. The relative amounts of chemicals that are likely to be volatilized, sorbed to sludge, biotransformed, and discharge in the effluent water was determined. Since it was difficult to predict biotransformation, measured concentrations were used to calibrate the model in terms of biotransformation rate constant. Results obtained by applying the model for the eight compounds showed <40% differences between most of the estimated and measured data from WWTP A. All eight compounds that were modelled in this study had high removal efficacy from WWTP A. Apart from benzyl butyl phthalate and bisphenol A, the majority is removed via biotransformation followed by a lesser proportion removed with the primary sludge. Fugacity analysis provides useful insight into compound fate in a WWTP and with further calibration and validation the model should be useful for correlative and predictive purposes. 相似文献
966.
Feng XH Zhai LM Tan WF Liu F He JZ 《Environmental pollution (Barking, Essex : 1987)》2007,147(2):366-373
Several Mn oxide minerals commonly occurring in soils were synthesized by modified or optimized methods. The morphologies, structures, compositions and surface properties of the synthesized Mn oxide minerals were characterized. Adsorption and redox reactions of heavy metals on these minerals in relation to the mineral structures and surface properties were also investigated. The synthesized birnessite, todorokite, cryptomelane, and hausmannite were single-phased minerals and had the typical morphologies from analyses of XRD and TEM/ED. The PZCs of the synthesized birnessite, todorokite and cryptomelane were 1.75, 3.50 and 2.10, respectively. The magnitude order of their surface variable negative charge was: birnessite> or =cryptomelane>todorokite. The hausmannite had a much higher PZC than others with the least surface variable negative charge. Birnessite exhibited the largest adsorption capacity on heavy metals Pb(2+), Cu(2+), Co(2+), Cd(2+) and Zn(2+), while hausmannite the smallest one. Birnessite, cryptomelane and todorokite showed the greatest adsorption capacity on Pb(2+) among the tested heavy metals. Hydration tendency (pK(1)) of the heavy metals and the surface variable charge of the Mn minerals had significant impacts on the adsorption. The ability in Cr(III) oxidation and concomitant release of Mn(2+) varied greatly depending on the structure, composition, surface properties and crystallinity of the minerals. The maximum amounts of Cr(III) oxidized by the Mn oxide minerals in order were (mmol/kg): birnessite (1330.0)>cryptomelane (422.6)>todorokite (59.7)>hausmannite (36.6). 相似文献
967.
968.
969.
战略环境影响评价(SEA)在中国的开展—区域环境评价(REA) 总被引:10,自引:0,他引:10
实践和研究表明 :传统的环境影响评价 (EIA) ,即在项目层次上开展的EIA ,不尽完美。而包含有战略环境影响评价的新一代EIA体系将很好的弥补项目EIA的不足 ,并且将可持续发展的思想真正贯彻到实际中去。中国在开展环境影响评价方面 ,也逐渐注重两个层次上EIA的开展 ,特别是结合当前发展的新特点 ,开展了区域环境影响评价。文章论证了区域环境评价 ,无论从层次上 ,还是从评价的对象、内容上都是属于战略环境影响的形式。并基于这个观点 ,介绍了区域环评在中国的开展及今后发展应注意的一些问题。 相似文献
970.
污水生物除磷若干影响因素分析 总被引:23,自引:2,他引:21
在系统阐述污水生物除磷机理的基础上,深入分析了微生物群体平衡、城市污水水质、环境因子以及工艺运行参数和运行方式等方面对生物除磷效果的影响.分析结果表明:生物除磷系统的溶解氧浓度不宜太高,一般好氧区DO<2 mg/L,厌氧区DO<0.2 mg/L;厌氧段存在硝酸盐对生物释磷有负面影响,缺氧段存在一定浓度的硝酸盐有利于生物聚磷;碳源必须充分、易降解;TKN/COD<0.1的城市污水有利于生物除磷;pH偏碱性可提高生物除磷效率;低温对生物除磷效果影响不明显. 相似文献