Study of fluxing in Al refining process by rotary and crucible furnaces

The process used to obtain recycled Al alloys depends on the scrap quality. Rotary furnaces are normally used in Europe as they allow a great productivity and they can process low quality scrap using a salt flux to protect the molten metal from oxidation. In this article, the effect of the quantity of salt on the metal recovery has been experimentally investigated by melting several types of scrap under a mixture of NaCl–KCl–Na₃AlF₆ salts. The quantity of salt has been related to the salt factor (SF), which is the ratio between the non-metallic content in the scrap and the quantity of salt required. The same levels of salt factor have been tested by melting the scrap in rotary and crucible furnaces. The metal recovery increases with the salt content for both furnaces. The results obtained with the different melting processes are comparable because the yield difference is similar considering different salt factors. Crucible furnace gives greater metal recovery but it cannot replace rotary furnace in Al refining industry due to lower melting capacity. However, the results highlight that the optimisation of the Al refining process can be supported by preliminary tests through crucible furnaces reducing the time and material consumptions.     

Challenges in assessing the environmental consequences of dietary changes

Tom et al. (Environ Syst Decis 1–12, 2015) compared the energy requirements, water footprint, and greenhouse gas emissions of diet regimens recently recommended by the US Department of Agriculture. This editorial comments on a number of challenges related to the use of the results of life-cycle assessment studies to quantify the environmental impacts of dietary shifts.     

Remote sensing water observation for supporting Lake Victoria weed management

This paper aims to assess the suitability of remote sensing for enhancing the management of water body resources and for providing an inexpensive way to gather, on a wide area, weed infestation extent and optical parameter linked to the water body status. Remotely sensed satellite images and ancillary ground true data were used to produce land cover maps, trough classification techniques, and water compounds maps, applying radiative transfer models. The study proposed within the framework of the cooperation between Italian Foreign Affair Ministry (through the University of Rome) and Kenyan Authorities has been carried out on the Kenyan part of the Lake Victoria. This lake is one of the largest freshwater bodies of the world where, over the last few years environmental challenges and human impact have perturbed the ecological balance affecting the biodiversity. The objective of this research study is to define the thematic products, retrievable from satellite images, like weed abundance maps and water compound concentrations. These products, if provided with an appropriate time frequency, are useful to identify the preconditions for the occurrence of hazard events like abnormal macrophyte proliferation and to develop an up-to-date decision support system devoted to an apprised territory, environment and resource management.     

TG, FT-IR and NMR characterization of n-C16H34 contaminated alumina and silica after mechanochemical treatment

This paper deals with the application of mechanochemistry to model systems composed of alumina or silica artificially contaminated with n-C16H34. The mechanochemical treatment was carried out by means of a ring mill for times ranging from 10 to 40h. Thermogravimetry and infrared and nuclear magnetic resonance spectroscopies were used for the characterization of the mechanochemical products. The results have indicated that, in the case of alumina, almost all the contaminant n-C16H34 undergoes a complex oxidative reaction path whose end products are strongly held on the surface. These end products are most likely made of crosslinked, partially oxidized hydrocarbon chains bond to the solid surface via COO(-) groups. In the case of silica, the hydrocarbon undergoes a different, equally complex reaction path, but to a lower extent. In this case the end products are most probably carbonylic compounds and graphitic carbon. Then, for both solid matrices, the mechanochemical treatment promotes significant modification of the chemical nature of the polluting hydrocarbon with end products much more difficult to remove from the surface. As the systems studied are models of sites contaminated by aliphatic hydrocarbon, the results are worthy of consideration in relation to the mobility of the contaminants in the environment.     

Identification of stationary sources of air pollutants by concentration statistical analysis

The atmospheric concentrations of benzene, toluene, ethylbenzene and isomeric xylenes (BTEX) in a medium-sized town (S. Maria Capua Vetere, about 32000 inhabitants, Southern Italy) have been determined during working days and weekends in 2006. The procedure used was 24h passive adsorption by samplers distributed throughout the town followed by GC/MS analysis. On a yearly base, the arithmetic mean benzene concentrations were above the limit required by the 2000/69/CE European Directive. The Pearson correlation coefficients of the 24h geometric mean BTEX concentrations were indicative of stationary sources of toluene located in a well circumscribed area of the urban territory, active only during the working days and not officially recognized. The results highlight the effectiveness of the statistical approach used in this study for the identification of pollutant sources.     

Environmental and biological monitoring of iridium in the city of Rome

The use of iridium in the latest catalytic converters to further reduce nitrogen oxide emission in the exhaust of lean-burn engines could result in increased atmospheric levels of this element in high-density vehicle traffic areas. The objective of this study is to assess environmental Ir pollution and its urinary levels in workers and an urban control group. Environmental monitoring inside a tram consisted in air samplings of total suspended particles (TSP), PM10 and PM2.5 carried out during November 2005. Urinary Ir levels were evaluated in 64 municipal tram drivers and in 58 administrative employees as controls. Quantification of Ir in air samples and urine was performed by means of Sector Field Inductively Coupled Plasma Mass Spectrometry. Means+/-standard deviation of Ir levels in TSP, in PM10 and PM2.5 fractions were 1.43+/-1.66, 0.44+/-0.27 and 0.36+/-0.19 pg m(-3), respectively. No statistically significant differences were observed among urinary Ir values in the exposed subjects and control group. The Ir levels in Rome air are still sufficiently low, even if the increased use of new Ir-based catalysts could be of some concern in the near future. The results of our study are of interest as they are a first attempt to explore airborne levels and urinary concentrations of Ir in an urban context at medium-high density of vehicle traffic. Particular attention should be given to the fact that Ir was found in the finest dust particles as the effects of fine particles containing Ir have not yet been studied.     

Distribution of Cd and As in organs and tissues of four marine mammal species stranded along the Italian coasts

Concentrations of Cd and As were determined in organs and tissues (muscle, heart, kidney, lung and liver) of four cetacean species (Stenella coeruleoalba, Truncatus truncatus, Grampus griseus and Ziphius cavirostris) stranded along the Italian coasts during the period 2000-2009. Significant differences were found between Cd concentrations in the different analysed tissues. Particularly, the kidney shows the highest concentrations of Cd in all analysed specimens, followed by the liver. No systematic or statistically significant difference in As concentrations was found in the analysed tissues. Considerable differences of Cd and As values in samples from different geographical areas (Sicily Channel, Adriatic Sea and Tyrrhenian Sea) were found, with the highest values measured in samples from the Sicily Channel. This basically suggests that anthropogenic and natural sources significantly affect Cd and As content in cetaceans.     

21,000 Years of Ethiopian African monsoon variability recorded in sediments of the western Nile deep-sea fan

The Nile delta sedimentation constitutes a continuous high-resolution record of Ethiopian African monsoon (EAM) regime intensity. Multi-proxy analyses performed on hemipelagic sediments deposited on the Nile deep-sea fan allow the quantification of the Saharan aeolian dust and the Blue/White Nile River suspended matter frequency fluctuations during the last 21,000 years. The radiogenic strontium and neodymium isotopes, clay mineralogy, elemental composition and preliminary palynological analyses reveal large changes in source components, oscillating between a dominant aeolian Saharan contribution during the Last Glacial Maximum (LGM) and the late Holocene (~4,000–2,000 years), a dominant Blue/Atbara Nile River contribution during the early Holocene (15,000–8,000 years) and a probable White Nile River contribution during the middle Holocene (8,000–4,000 years). The following main features are highlighted: (1) The rapid shift from the LGM arid conditions to the African Humid Period (AHP) started at about 15,000 years. The AHP extends until 8,000 years, and we suggest that the EAM maximum between 15,000 and 8,000 years is responsible for a larger Blue/Atbara Nile sediment load and freshwater input into the eastern Mediterranean Sea. (2) The transition between the AHP and the arid late Holocene is gradual and occurs in two main phases between 8,400–6,500 years and 6,500–3,200 years. We suggest that the main rain belt shifted southward from 8,000 to ~4,000 years and was responsible for progressively reduced sediment load and freshwater input into the eastern Mediterranean Sea. (3) The aridification along the Nile catchments occurred from ~4,000 to 2,000 years. This dry period, which culminates at 3,200 year, seems to coincide with a re-establishment of increased oceanic primary productivity in the western Mediterranean Sea. Such a pattern imposes a large and rapid northward shift of the rain belt over the Ethiopian highlands (5–15°N) since 15,000 years. Precipitation over Ethiopia increased from 15,000 to 8,000 years. It was followed by a gradual southward shift of the rain belt over the equator from 8,000 to 4,000 years and finally a large shift of the rain belt south the equator between 4,000 and 2,000 years inducing North African aridification. We postulate that the decrease in thermohaline water Mediterranean circulation could be part of a response to huge volumes of freshwater delivered principally by the Nile River from 15,000 to 8,000 years in the eastern Mediterranean.     

Biological effects of ammonia released from a composting plant assessed with lichens

In this study, we investigated whether ammonia emissions from industrial composting of organic waste may influence the surrounding environment, using lichens as bioindicators. To this purpose, samples of N-tolerant and N-sensitive lichens, namely Xanthoria parietina and Evernia prunastri, were transplanted for 1–3 months along transects at increasing distance (0–400 m) from a composting facility in Tuscany, Italy. Atmospheric concentrations of ammonia were measured using passive samplers. The physiological response of lichen transplants was investigated by means of the photosynthetic efficiency (measured as chlorophyll a fluorescence emission), the integrity of cell membranes (measured as electrolyte leakage), and sample viability (measured as enzymatic activity of dehydrogenase). Epiphytic lichen communities were investigated using biodiversity indices. The results showed decreasing concentrations of ammonia, from 48.7 μg/m³ at the composting facility to 2.7 μg/m³ at 400 m. The N-tolerant X. parietina was not affected and some physiological parameters even showed a higher performance, while the N-sensitive E. prunastri showed a reduced performance with increasing atmospheric concentrations approaching the source. A shift from lichen communities composed by meso-acidophilous species (actual condition) to more nitrophilous communities in the near future, approaching the composting facility is suggested. It is concluded that lichens can provide useful data for decision-makers to establish correct science-based environmentally sustainable waste management policies.