Epiphytic lichens as sentinels for heavy metal pollution at forest ecosystems (central Italy)

The results of a study using epiphytic lichens (Parmelia caperata) as sentinels for heavy metal deposition at six selected forest ecosystems of central Italy are reported. The woods investigated are characterized by holm oak (Quercus ilex), turkey oak (Quercus cerris) and beech (Fagus sylvatica) and represent the typical forest ecosystems of central Italy at low, medium and high elevations, respectively. The results showed that levels of heavy metals in lichens were relatively low and consequently no risk of heavy metal air pollution is expected for the six forest ecosystems investigated. However, for two of them there are indications of a potential risk: the beech forest of Vallombrosa showed signs of contamination by Pb as a consequence of vehicle traffic due to the rather high touristic pressure in the area, and the holm oak forest of Cala Violina showed transboundary pollution by Mn, Cr and Ni originating from the steel industry in Piombino. Epiphytic lichens proved to be very effective as an early warning system to detect signs of a changing environment at forest ecosystems.     

Evaluation of mercury biogeochemical cycling at the sediment–water interface in anthropogenically modified lagoon environments

The Marano and Grado Lagoon is well known for being contaminated by mercury(Hg) from the Idrija mine(Slovenia) and the decommissioned chlor-alkali plant of Torviscosa(Italy).Experimental activities were conducted in a local fish farm to understand Hg cycling at the sediment–water interface. Both diffusive and benthic fluxes were estimated in terms of chemical and physical features. Mercury concentration in sediments(up to 6.81 μg/g)showed a slight variability with depth, whereas the highest methylmercury(MeHg) values(up to 10 ng/g) were detected in the first centimetres. MeHg seems to be produced and stored in the 2–3 cm below the sediment–water interface, where sulphate reducing bacteria activity occurs and hypoxic–anoxic conditions become persistent for days. DMeHg in porewaters varied seasonally(from 0.1 and 17% of dissolved Hg(DHg)) with the highest concentrations in summer. DHg diffusive effluxes higher(up to 444 ng/m~2/day) than those reported in the open lagoon(~ 95 ng/m~2/day), whereas DMeHg showed influxes in the fish farm(up to-156 ng/m~2/day). The diurnal DHg and DMeHg benthic fluxes were found to be higher than the highest summer values previously reported for the natural lagoon environment. Bottom sediments, especially in anoxic conditions, seem to be a significant source of MeHg in the water column where it eventually accumulates. However, net fluxes considering the daily trend of DHg and DMeHg, indicated possible DMeHg degradation processes. Enhancing water dynamics in the fish farm could mitigate environmental conditions suitable for Hg methylation.     

Vitellogenesis in the deep-sea shark Centroscymnus coelolepis

At present, information on the reproductive physiology of Centroscymnus coelolepis, which is one of most important and widespread deep-sea shark species, is completely lacking. In this study, we investigated vitellogenesis, a key step in the reproduction biology of fishes. Specimens of C. coelolepis were collected at 2850 m depth in the Western Mediterranean Sea. The size of the collected sharks (range: 35.5–65.0 cm TL) was much lower than those typically reported for the Atlantic and Pacific Oceans. The marked distinctiveness of Mediterranean and Atlantic/Pacific populations was reflected by the achievement of sexual maturity at a smaller size in Mediterranean specimens. The examination of cytoplasmatic components of oocytes indicated that vitellogenin uptake in the ovary started when oocytes reached 14 mm in diameter. Only reproductive females displayed a significant relationship between plasmatic vitellogenin and gonadal development, suggesting that vitellogenesis in C. coelolepis is a discontinuous process. Oestradiol levels were tightly coupled with gonadal development, underlining the importance of this hormone in controlling vitellogenesis. All these findings suggest that vitellogenesis in this yolk-sac viviparous shark might occur with similar mechanisms of oviparous vertebrates.     

Facing the water framework directive challenges: A baseline of stakeholder participation in the European Union

Public participation is a key element of Integrated Water Resources Management and, in the European Union (EU), is a major challenge in the implementation of the Water Framework Directive (WFD), which was adopted in December 2000. When new legislation enters into force it is essential to set a baseline against which to measure the progress towards the established goals at significant milestones of its implementation. This paper presents an assessment of the quality of stakeholder participation at the beginning of the WFD implementation in twenty countries belonging to or with close institutional relationships with the EU. The evaluation was completed by environmental non-governmental organizations and it shows that already in 2003 there were positive examples of stakeholder participation in several countries but that, in general, the WFD implementation will require significant efforts to improve on participatory practices throughout Europe.     

Multi-level interactions in a context of political decentralization and evolving water-policy goals: the case of Spain

Regional Environmental Change - Spain is a highly decentralized country where water governance is a multi-level institutional endeavor requiring effective intergovernmental coordination—in...     

Palladium recovery from monolithic ceramic capacitors by leaching,solvent extraction and reduction

Journal of Material Cycles and Waste Management - Palladium finds a remarkable use in electronic devices and catalysts; therefore, an efficient and complete recovery from the containing secondary...     

Spatial distribution patterns of the soft corals Alcyonium acaule and Alcyonium palmatum in coastal bottoms (Cap de Creus, northwestern Mediterranean Sea)

Current knowledge on the abundance and distribution patterns of different soft coral species is relatively limited when compared to other benthic suspension feeders such as gorgonians and hard coral species. To overcome this scarcity of information, the distribution patterns of the soft corals Alcyonium acaule and Alcyonium palmatum were investigated in northwestern Mediterranean benthic communities over a wide geographical (60 km of coastline) and bathymetrical (0–70 m depth) extent using a remotely operated vehicle. A. acaule was the most abundant species in the study area with highest recorded density of 18 col m^?2 found at depths of 35–45 m in areas that are directly exposed to strong near-bottom currents. Conversely, A. palmatum was only found as scattered solitary colonies at greater depths in soft bottoms, with maximum density of 2.4 col m^?2. Medium and large colonies of A. acaule were preferentially found on sloping and vertical rocky bottoms where they form dense patches. High-density patches of A. acaule were preferentially found on vertical rocky bottom, while isolated colonies were preferentially observed on coralligenous substrata as well as on flat soft and maërl substrates. A. acaule biomass distribution showed highest values between 40 and 45 m depth, and between 60 and 65 m depth. This suggests that deeper populations are formed by colonies that are bigger than the equivalent shallower ones. Although both species are almost genetically identical, ecologically they are very different. For this reason, conservation plans should consider the differential ecological traits shown by these two soft coral species.     

Evaluation of the impact on entomocoenosis of active agents allowed in organic olive farming against Bactrocera oleae (Gmelin, 1790)

Several attempts for evaluating environmental impact of active agents allowed in organic olive farming against Bactrocera oleae have been made, but very few studies were performed contemporaneously on more than one of them. Insects were chosen as indicators because they are known to react very quickly to environmental perturbations, mainly at the community level. In fact, the coenosis is the functional unit interacting with biotic and abiotic environmental parameters. Seven taxa, known for their sensitivity to habitat alterations, were sampled and grouped in functional groups: predators and parasitoids, phytophagouses and pollinators. The coenotic balance between these two functional groups was analyzed. The study was carried out in an organic olive orchard in the municipality of Terranova da Sibari, Cosenza, Southern Italy. The tested active agents (Azadirachtin, Rotenone, Copper Oxychloride) were sprayed twice (end of September and middle October). During the treatments the population dynamics of all the taxa were knocked-down. No one tested compound seems to be harmless to the entomocoenosis, particularly on phytophagouses and pollinators. In truly organic farming it is necessary to provide natural refuge areas to beneficial insects (i.e. pest antagonists) in which no active agents are sprayed and alternative preys could be found.     

Agricultural policies and the emergence of voluntary landscape enhancement efforts: an exploratory analysis of rural tourism using an agent-based model

Conservation and enhancement of ecosystem services have become a priority of rural policies. Feedback loops from rural policies on ecosystem service supply have often been highlighted in the literature, but only vaguely investigated. In this paper, we model feedback loops from rural policies through an agent-based model, and we analyse whether feedback loops can indirectly create a system in which voluntarily landscape enhancement emerges from the interactions between farmers and rural tourists. The results suggest that, in certain conditions, feedback loops from policies can be a relevant element to take into account, but that greater attention to the ecosystem service demand is required.