Investigation of Selective Catalytic Reduction Impact on Mercury Speciation under Simulated NOx Emission Control Conditions

Abstract

Selective catalytic reduction (SCR) technology increasingly is being applied for controlling emissions of nitrogen oxides (NO_x) from coal-fired boilers. Some recent field and pilot studies suggest that the operation of SCR could affect the chemical form of mercury (Hg) in coal combustion flue gases. The speciation of Hg is an important factor influencing the control and environmental fate of Hg emissions from coal combustion. The vanadium and titanium oxides, used commonly in the vanadia-titania SCR catalyst for catalytic NO_x reduction, promote the formation of oxidized mercury (Hg²⁺).

The work reported in this paper focuses on the impact of SCR on elemental mercury (Hg⁰) oxidation. Bench-scale experiments were conducted to investigate Hg⁰ oxidation in the presence of simulated coal combustion flue gases and under SCR reaction conditions. Flue gas mixtures with different concentrations of hydrogen chloride (HCl) and sulfur dioxide (SO₂) for simulating the combustion of bituminous coals and subbituminous coals were tested in these experiments. The effects of HCl and SO₂ in the flue gases on Hg⁰ oxidation under SCR reaction conditions were studied. It was observed that HCl is the most critical flue gas component that causes conversion of Hg⁰ to Hg²⁺ under SCR reaction conditions. The importance of HCl for Hg⁰ oxidation found in the present study provides the scientific basis for the apparent coal-type dependence observed for Hg⁰ oxidation occurring across the SCR reactors in the field.     

Chlorinated Solvent Treatment Wetland

A first‐of‐its‐kind wetland restoration project was completed in October 2000 to treat trichloroethene‐(TCE‐)impacted groundwater from a former manufacturing facility prior to discharge into a highly valued recreational surface water body in the upper Midwest. This article summarizes the design, construction, operation, and effectiveness of the restored wetland. The groundwater‐surface water discharge zone at the site was restored as a wetland to improve the natural degradation of TCE and subsequent degradation by‐products. For the past 11 years, the treatment wetland performance was evaluated by monitoring the wetland vegetation, wetland hydraulics, and water chemistry. Water quality data have been used to assess the wetland geochemistry, TCE and TCE‐degradation by‐product concentrations within the wetland, and the surface water quality immediately downgradient of the wetland. The treatment wetland has been performing according to design, with TCE and TCE‐degradation by‐products not exceeding surface water criteria. The monitoring results show that TCE and TCE‐degradation by‐products are entering the treatment wetland via natural hydraulic gradients and that the geochemistry of the wetland supports both reductive dechlorination (anaerobic degradation) and cometabolic degradation (aerobic degradation) of TCE and TCE‐degradation by‐products: cis‐ and trans‐1,2‐dichloroethene and vinyl chloride. © 2013 Wiley Periodicals, Inc.     

Influence of Sampling Frequency on Estimation of Annual Total Phosphorus and Total Suspended Solids Loads1

Abstract: The determination of sediment and nutrient loads is typically based on the collection and analysis of grab samples. The frequency and regularity of traditional sampling may not provide representation of constituent loading, particularly in systems with flashy hydrology. At two sites in the Little Bear River, Utah, continuous, high‐frequency turbidity was used with surrogate relationships to generate estimates of total phosphorus and total suspended solids concentrations, which were paired with discharge to estimate annual loads. The high frequency records were randomly subsampled to represent hourly, daily, weekly, and monthly sampling frequencies and to examine the effects of timing, and resulting annual load estimates were compared to the reference loads. Higher frequency sampling resulted in load estimates that better approximated the reference loads. The degree of bias was greater at the more hydrologically responsive site in the upper watershed, which required a higher sampling frequency than the lower watershed site to achieve the same level of accuracy in estimating the reference load. The hour of day and day of week of sampling impacted load estimation, depending on site and hydrologic conditions. The effects of sampling frequency on the determination of compliance with a water quality criterion were also examined. These techniques can be helpful in determining necessary sampling frequency to meet the objectives of a water quality monitoring program.     

Linking sustainable consumption and production: The government role

Achieving sustainable development depends on comprehensive approaches which integrate consumption and production initiatives. At present, sustainable consumption is being overemphasized to the neglect of the more important production side. This paper examines the role of governments in promoting sustainable consumption and production to identify gaps in national schemes which reduce their overall effectiveness. Public policy tools promoting sustainable consumption and production are discussed in terms of whether they are aimed at correcting: 1) market failures (regulations, taxes, subsidies); or 2) systems failures (labels, communications, education, public procurement). The challenge for governments is to link sustainable consumption initiatives to policies aimed at increasing the sustainability of production in the private sector in both their national and international dimensions. In this way, governments can enlist the aid of consumers in pushing producers towards sustainability and to achieve the ultimate goal of sustainable development.     

Local and distant residence times of contaminants in multi-compartment models. Part I: a review of the theoretical basis

In this, Part I of a two-part series, a review is presented of some generally appreciated residence time properties of multimedia models. The novel concept of “distant residence time” (DRT) is developed to provide additional insights into the characterization of environmental transport. DRT is the proportionality constant between the rate of emission of a contaminant into one compartment or region and the mass that results at steady-state in a distant compartment. The concept, which can be viewed as an expression of environmental mobility, is illustrated for various configurations of compartments and is shown to be consistent with the concepts of global fractionation and cold condensation. The dynamic responses of chemical quantities at distant locations to changing emission rates are also discussed. It is shown that approximate solutions for DRTs and their time dependence are useful for characterizing the long-range transport of chemicals and for interpreting monitoring data.     

Local and distant residence times of contaminants in multi-compartment models. Part II: application to assessing environmental mobility and long-range atmospheric transport

In Part I, the concepts of inherent, local and distant residence times (DRTs) were reviewed as metrics of the extent to which chemical discharges or emissions in one region or box are transported to distant regions. In this second part, the concepts are applied to geographically relevant systems to illustrate their applicability to the assessment of chemicals for long-range transport potential (LRTP). It is shown that the relative ranking of chemicals as characterized by the DRT method is similar to that of the characteristic travel distance concept. A DRT source-receptor matrix is developed that can express the chemical-specific potential of source regions to contaminate a specific receptor region of concern such as the Arctic. The matrix can be modified to identify for a specific source region the likely destinations of emissions as well as to assess the relative vulnerability of regions in the global environment to contaminants of concern.     

Mass balance modelling of contaminants in river basins: application of the flexible matrix approach

It is useful to have available a variety of catchment-scale water quality models that range in complexity, spatial resolution and data requirements. In a previous paper [Warren, C., Mackay, D., Whelan, M., Fox, K., 2005. Mass balance modelling of contaminants in river basins: a flexible matrix approach. Chemosphere 61, 1458-1467] a series of simple to intermediately complex mass balance models was presented which can be used for tiered exposure assessments in river basins. The connectivity of the segments is expressed using a matrix that permits flexibility in application, enabling the model to be re-segmented and applied to different catchments as required. In this paper, the intermediate models, QWASI matrix-rate constant (QMX-R) and QWASI matrix-fugacity (QMX-F) are used to estimate concentrations of linear alkylbenzene sulfonates (LAS) in the rivers Aire and Calder, UK, and of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) in the Fraser River basin, Canada. The results compare satisfactorily with monitoring data, suggesting that these QWASI-based models for exposure and risk assessment may be applicable under data-limited conditions. The use of QWASI-based models for regulatory purposes in an evaluative river system is also discussed with reference to assessments of para-dichlorobenzene (pDCB), trichloroethylene (TCE), bis(2-ethylhexyl) phthalate (DEHP) and toluene. It is shown that multi-media QWASI model predictions can be usefully depicted graphically on chemical space diagrams and used to highlight regions in which advection, partitioning to sediments and volatilization may be important determinants of chemical fate in river systems.     

Technical aid for hydraulics research in developing nations

Many water-related problems are shared by most of the developing countries and the industrialized nations could be in position of offering aid in such problems. Water scarcity and access to safe water, water pollution, severe storms and floods, droughts, waterborne diseases and landslides and mud floods are the most commonly shared problems among developing nations. These problems were discussed in a workshop organized as part of the Fifth International Symposium on Environmental Hydraulics in 2008. The discussion included identification of actors both in the developing and developed nations (vgr. local and national governments, NGOs, universities, foundations and private and public research institutions), aid modalities such as education, technology transfer, technology development and direct investment as well as restrictions and barriers in the form of political and legal issues, economic limitations, cultural differences and geographic distances. Recommendations about how developed nations could help developing countries are issued.     

LAND-USE AND WATER-QUALITY RELATIONSHIPS IN THE GEORGES CREEK BASIN,MARYLAND1

ABSTRACT: Models developed in Ohio to predict water quality conditions resulting from various land uses associated with the surface mining of coal are employed to ascertain their transferability to Maryland conditions. Discriminant analysis is employed to assess patterns of association between water quality and land use variables, and predictive models were then constructed with which to quantify changes in stream quality to be expected from the changing mosaic of upstream land uses in the Georges Greek basin of western Maryland. Data collected under procedures specified by the regulatory authority in Maryland may have accounted for the lack of statistically significant results from these models. Suggested changes in the collection of data are made for the coal region of Maryland.