New tools and strategies for the inspection of the psychosocial working environment: The experience of the Danish Working Environment Authority

In 2007 the Danish Working Environment Authority launched a new strategy to strengthen and qualify primary prevention of work related stress. Part of the strategy consists of increased inspections of the psychosocial working environment as well as the development and implementation of a new inspection tool, namely the “guidance tool”.Twenty-four sector specific guidance tools have been developed to help WEA inspectors assess psychosocial working environment problems in all Danish enterprises. Based on recent research, the guidance tools consist, in each sector, of the three to five most important risk factors (for example quantitative demands, emotional demands, and work related violence), as well as the most important preventive factors, e.g. quality of management, influence/control and training.During the first years of the strategy, an increasing number of inspectors have issued improvement notices regarding work related stress and violence, and there has been an increasing number of notices issued on several risk factors. For some aspects, the tools have helped increase the clarity and comprehensibility of the improvement notices and reduce the WEA’s time consumption per enterprise.The guidance tools seem to be a suitable and efficient way of assessing several health and safety risks concerning work related stress and violence thereby allowing the WEA to detect more of the existing problems. Future challenges projected for the strategy include continuously training all WEA inspectors in the proper use of the tools and continuously refining the tools – or developing new tools – based on further research and experiences from practice.     

Leveraging assets: a case study of the sustainability initiative at the University of Minnesota,Morris

This article presents an overview of the sustainability initiative at the University of Minnesota, Morris, key components of which include a realistic goal of energy self-sufficiency by 2010, a new environmental studies curriculum, and various research and outreach projects. Many non-obvious institutional assets – such as lobbying networks in the state legislature, and geographic/demographic features that are more commonly thought of as liabilities – turned out to play critical roles in setting the initiative in motion. The initial physical assets have been leveraged into complementary opportunities for research, teaching, and institutional development in this direction.     

Chemical transformations of lead compounds under humid conditions: implications for bioaccessibility

This short communication documents chemical transformations caused by weathering of two Pb compounds that commonly occur in house dust. Chamber experiments were designed to simulate humid indoor environment conditions to determine whether Pb compounds undergo chemical transformations influencing bioaccessibility. Reference compounds of Pb metal (12 % bioaccessibility) and Pb sulfate (14 % bioaccessibility) were subjected to an oxygenated, humidified atmosphere in closed chambers for 4 months. X-ray diffraction (XRD) and X-ray absorption near-edge structure (XANES) spectroscopy were used to characterize the main Pb species, and the change in Pb bioaccessibility was determined using a simulated gastric acid digestion. At the end of the weathering period a small amount of Pb carbonate (9 % of total Pb) appeared in the Pb sulfate sample. Weathering of the Pb metal sample resulted in the formation of two compounds, hydrocerussite (Pb hydroxyl carbonate) and Pb oxide, in significant amounts (each accounted for 26 % of total Pb). The formation of highly bioaccessible Pb carbonate (73 % bioaccessibility), hydrocerussite (76 % bioaccessibility), and Pb oxide (67 % bioaccessibility) during weathering resulted in a measurable increase in the overall Pb bioaccessibility of both samples, which was significant (p = .002) in the case of the Pb metal sample. This study demonstrates that Pb compounds commonly found in indoor dust can ‘age’ into more bioaccessible forms under humid indoor conditions.     

Aquatic and terrestrial organic matter in the diet of stream consumers: implications for mercury bioaccumulation

The relative contribution of aquatic vs. terrestrial organic matter to the diet of consumers in fluvial environments and its effects on bioaccumulation of contaminants such as mercury (Hg) remain poorly understood. We used stable isotopes of carbon and nitrogen in a gradient approach (consumer isotope ratio vs. periphyton isotope ratio) across temperate streams that range in their pH to assess consumer reliance on aquatic (periphyton) vs. terrestrial (riparian vegetation) organic matter, and whether Hg concentrations in fish and their prey were related to these energy sources. Taxa varied in their use of the two sources, with grazing mayflies (Heptageniidae), predatory stoneflies (Perlidae), one species of water strider (Metrobates hesperius), and the fish blacknose dace (Rhinichthys atratulus) showing strong connections to aquatic sources, while Aquarius remigis water striders and brook trout (Salvelinus fontinalis) showed a weak link to in-stream production. The aquatic food source for consumers, periphyton, had higher Hg concentrations in low-pH waters, and pH was a much better predictor of Hg in predatory invertebrates that relied mainly on this food source vs. those that used terrestrial C. These findings suggest that stream biota relying mainly on dietary inputs from the riparian zone will be partially insulated from the effects of water chemistry on Hg availability. This has implications for the development of a whole-system understanding of nutrient and material cycling in streams, the choice of taxa in contaminant monitoring studies, and in understanding the fate of Hg in stream food webs.     

SURFACE AREA CORRECTIONS APPLIED TO A RESOURCE MAP1

ABSTRACT: Generally a difference exists between the horizontal planar area of a watershed as measured on a map and the actual surface area. A technique is presented, utilizing a topographic map, for computing the difference in the two areas as well as yielding a prediction of the actual surface area. Spatial variations in the magnitude of the difference in the two areas for small local sites over the watershed are displayed on computer generated maps. The technique is also used to adjust various inventory variables on maps, such as vegetation density, to reflect actual surface coverage. This allows estimates to be made of the difference in using corrected versus uncorrected area related parameters in mathematical functions describing processes occurring in the atmosphere-surface boundary layer.     

Light and electronmicroscopic studies of the acute and long-term toxic effects of N-nitrosodipropylamine and N-methylnitrosurea on the marine mussel Mytilus edulis

The acute (1) and long-term (2) toxic effects of N-nitrosodipropylamine (NDPA) and N-methylnitrosurea (NMU) were studied by light and electronmicroscopy following injection of the chemicals into the foot of the mussels Mytilus edulis (L.) (1) Mussels reveived one injection of NDPA at concentrations of 0.25, 0.5, 1.0, and 2.0 mg NDPA mussel^-1, and one injection of NMU at concentrations of 0.25, 0.5, 1.0, and 4.0 mg NMU mussel^-1. Within 12d, necrosis of the epithelial lining of the digestive diverticula took place, and the vesicular connective tissue in the digestive diverticula were heavily infiltrated by eosinophilic granular leucocytes. (2) Mussels received four weekly injections of 0.5 mg NDPA mussel^-1, and 0.5 mg NMU mussel^-1. NDPA-exposed mussels were examined for a period of 17 weeks, and NMU-exposed mussels were examined for a period of 24 weeks. Both chemicals produced progressive tissue damage, characterized by destruction of digestive tubules and ducts in the digestive diverticula. Destroyed tubules and ducts were replaced by collagenous scars, and granulocytomas were frequently seen.     

Secular trends of atmospheric methane (CH4)

Due partly to human activities the present yearly emissions of CH₄ exceed the atmospheric sinks, thus leading to a 1.2–1.9% per year atmospheric increase in the concentration of CH₄. New evidence based on studies of polar ice cores suggests that several hundred years ago the concentrations of CH₄ were perhaps only half of current values. These diverse findings are tied together in a single unified logistic model of atmospheric concentrations past, present and future. Using realistic growth rates of the sources of CH₄ caused by human activities, the model explains the concentrations and current growth rates. It also predicts that a doubling of CH₄ relative to present levels is possible given the long (9-year) atmospheric lifetime. Such increases of CH₄ concentrations may have already perturbed our global environment and may continue to do so in the future. The environmental effects include increased surface temperature of the earth, additional O₃ and CO in the clean non-urban atmosphere, depletions of tropospheric OH radicals, but perhaps also protection of the stratospheric ozone layer from destruction by man-made fluorocarbons.     

Measuring visual opacity using digital imaging technology

The U.S. Environmental Protection Agency (EPA) Reference Method 9 (Method 9) is the preferred enforcement approach for verifying facility compliance with federal visible opacity standards. Supporters of Method 9 have cited its flexibility and low cost as important technological and economic advantages of the methodology. The Digital Opacity Compliance System (DOCS), an innovative technology that employs digital imaging technology for quantifying visible opacity, has been proposed as a technically defensible and economically competitive alternative to Method 9. Results from the field application of the DOCS at EPA-approved Method 9 smoke schools located in Ogden, UT, Augusta, GA, and Columbus, OH, demonstrated that, under clear sky conditions, the DOCS consistently met the opacity error rate established under Method 9. Application of hypothesis testing on the smoke school data set confirmed that the DOCS was equivalent to Method 9 under clear sky conditions. Under overcast sky conditions, human observers seemed to be more accurate than the DOCS in measuring opacity. However, within the smoke school environment, human observers routinely employ backgrounds other than sky (e.g., trees, telephone poles, billboards) to quantify opacity on overcast days. Under conditions that compel the use of sky as plume background (e.g., emission stacks having heights above the tree line), the DOCS appears to be a more accurate methodology for quantifying opacity than are human observers.