Analysis of collection systems for sorted household waste in Spain

This work analyses the separate collection systems used in Spanish towns with between 5000 and 50,000 inhabitants. The study looks at the systems and their efficiency by means of the indicators fractioning rate, quality in container rate and separation rate. The results obtained are compared with those from a similar study conducted earlier that was applied to towns and cities with populations over 50,000. It can be concluded that the most widely implemented system in Spain involves the collection of mixed waste from kerbside bins and picking up paper/cardboard, glass and lightweight packaging from drop-off points. Findings show that the best system is the one that collects mixed waste, organic material and multiproduct waste door-to-door, and glass from drop-off points. The indicator separation rate made it possible to establish beta regression models to analyse the influence of the following logistic variables: inhabitants per point (people/pt), time (years) and frequency of collection (freq). From these models it can be seen that people/pt has a negative effect on all the fractions, while freq and years have a positive effect in the case of paper.     

Co-digestion of cattle manure with food waste and sludge to increase biogas production

Anaerobic co-digestion strategies are needed to enhance biogas production, especially when treating certain residues such as cattle/pig manure. This paper presents a study of co-digestion of cattle manure with food waste and sewage sludge. With the aim of maximising biogas yields, a series of experiments were carried out under mesophilic and thermophilic conditions using continuously stirred-tank reactors, operating at different hydraulic residence times. Pretreatment with ultrasound was also applied to compare the results with those obtained with non-pretreated waste. Specific methane production decreases when increasing the OLR and decreasing HRT. The maximum value obtained was 603 LCH(4)/kg VS(feed) for the co-digestion of a mixture of 70% manure, 20% food waste and 10% sewage sludge (total solid concentration around 4%) at 36°C, for an OLR of 1.2g VS/Lday. Increasing the OLR to 1.5g VS/Lday led to a decrease of around 20-28% in SMP. Lower methane yields were obtained when operating at 55°C. The increase in methane production when applying ultrasound to the feed mixtures does not compensate for the energy spent in this pretreatment.     

Highly concentrated phenolic wastewater treatment by the photo-Fenton reaction, mechanism study by FTIR-ATR

Phenol degradation by Photo-Fenton reaction has been studied in highly concentrated wastewaters and most intermediate species have been identified by Fourier Transform IR-Spectroscopy with ATR device. During the photodegradation of highly concentrated phenol solutions, the formation of dissolved and precipitate tannin has been observed. The possibility of a Fe3+-Pyrogallol complex formation, previous to the tannin formation, has been proposed too. The complex formation involving Fe3+ ions could be related to the observed Photo-Fenton activity decrease. Tannin formation inhibits the complete mineralization of phenol because *OH radicals attack will produce further condensation steps and the polymer size increase. This fact limits the applicability of the process for highly concentrated phenolic wastes mineralization. However, the tannin precipitation allows its separation from the solution by conventional filtration, and reduction of the corresponding dissolved organic carbon. These observations have been proved from the identification of primary degradation products, catechol and hydroquinone. Catechol is considered to be the first step for the formation of tannins. Degradation process for phenol, catechol and hydroquinone have been monitored by total organic carbon (TOC) measurements along the reaction time span. From these results, a global mechanism for the Photo-Fenton degradation of phenol is proposed.     

The ability of selected cladoceran species to utilize domestic wastewaters in Mexico City

The population growth patterns of four cladocerans, viz. Alona rectangula, Ceriodaphnia dubia, Moina macrocopa and Daphnia pulex on wastewaters from a treatment plant at Iztacalco, Mexico City were analyzed in this study. Crude wastewater (tank A) did not support A. rectangula and all animals in the replicates died after 5 days. A. rectangula with partially treated wastewater (tank B) showed growth curves similar to controls where algal density was 1 x 10(6) cells ml(-1). With wastewater from tank C (last stage before treatment with purifying agents such as chlorine), the populations maintained a low density (7 ind. ml(-1)). In wastewaters from tanks A and B, C. dubia showed no positive population growth, but in water from tank C, they maintained a low density (2 ind. ml(-1)). D. pulex showed no positive growth in all replicates involving wastewater. Only in controls (diet of algae Chlorella), the population density increased with time. M. macrocopa showed higher population growth in crude wastewaters than controls. Partially treated wastewater from tank B also resulted in a greater population growth than in the controls. However, when wastewater from the tank C was used, the population declined after day 12. Under comparable conditions, A. rectangula reached much higher peak abundances (55 ind. ml(-1)) than the rest of the cladoceran species. The rates of population growth (r) of the tested cladoceran species followed trends similar to the peak population densities. A. rectangula had the highest growth rates (0.25 per day) in controls and from the wastewater from tank B. The r-values were negative for A. rectangula and C. dubia in crude wastewater. For M. macrocopa the r-values were higher (0.19) in crude wastewater than in algae (0.15). However, r-values of M. macrocopa became negative when cultured in treated wastewater from tank C.     

On-fibre photodegradation studies of polychlorinated biphenyls using SPME-GC-MS-MS: a new approach

The known advantages of solid-phase microextraction as a simple, one-step, rapid and solvent free extraction technique are exploited to study the photodegradation kinetics of polychlorinated biphenyls "on-fibre". The obtained results show the possibilities of this new approach not only to monitor the photolysis pathways of such compounds but to determine the photoproducts produced at different irradiation times and/or wavelengths. Photoproducts of PCB decomposition were less chlorinated biphenyls, among them some coplanar congeners have been found, which is important from a toxicological point of view.     

234U and 238U isotopes in water and sediments of the southern Baltic

The aim of this work was to determine the concentration of 234U and 238U and calculate the values of the 234U/238U activity ratio in waters and sediments from the various regions of the southern Baltic Sea: Gdańsk Deep, S?upsk Narrow and Bornholm Deep. The concentration of uranium in analysed sediments from southern Baltic increase with core depth to what probably is connected with diffusion from sediments to water through interstitial water, where uranium concentration is much higher than in bottom water. The highest concentrations of uranium were observed in sediments of S?upsk Narrow (0.66-7.11 mg kg(-1) d.w.) and S?upsk Bank (0.61-6.93 mg kg(-1) d.w.), the lowest in sediments from Bornholm Deep (0.54-3.77 mg kg(-1) d.w.). The 234U/238U activity ratio results indicated that the sedimentation of terrigenic material and Vistula River transport are the general sources of uranium in the southern Baltic sediments. The value of 234U/238U activity ratio in sediments from reduction areas from southern Baltic (Gdańsk Deep and Bornholm Deep) indicated that reduction process of U(VI) to U(IV) and removing of anthropogenic uranium from seawater to sediments constitutes a small part only in Gdańsk Deep.     

From the traditional concept of safety management to safety integrated with quality

This editorial reviews the evolution of the concepts of safety and quality that have been used in the traditional workplace. The traditional programs of safety are explored showing strengths and weaknesses. The concept of quality management is also viewed. Safety management and quality management principles, stages, and measurement are highlighted. The concepts of quality and safety guarantee are assessed. Total Quality Management concepts are reviewed and applied to safety quality. Total safety management principles are discussed. Finally, an analysis of the relationship between quality and safety from data collected from a company in Spain is presented.     

Study of 222Rn concentrations in drinking water in the north-eastern hydroregions of Poland

This paper presents the results of radon concentration measurements in the drinking water from the municipal water supply system and private wells located in the north-eastern part of Poland. The measurements were carried out on 643 samples using a liquid scintillation method. The mean value was found to be 5262 Bq m-3 with a maximum of 38347 Bq m-3. The samples were obtained from different water-bearing levels, i.e. surface water, deep borehole water and well water and have respective mean values of 3398, 5178 and 6155 Bq m-3. In 57 water samples, a guideline maximum level of 11,000 Bq m-3 was found to be exceeded. The observed radon concentration in water can contribute to a 2% increase in indoor radon concentration.     

Unsafe waters: the hydrosocial cycle of drinking water in Western Mexico

ABSTRACT

Mexico faces multiple water quality challenges, both in terms of the water supplied to the population as well as surface and underground water sources. Problems with drinking water supply affect the population in diverse ways, from associated health risks to high levels of intermittency in service to the poor perception of the quality of piped water – leading to high levels of bottled water consumption. In this text we explore the issue of drinking water quality in three contexts in the state of Jalisco: in Guadalajara, the state’s main urban area, in the peri-urban municipality of El Salto, and in the mid-sized city of San Juan de los Lagos. Our analysis explores drinking water regulations, the water quality monitoring undertaken by state and local authorities, access to information, as well as the actions and perceptions of water service providers. Looking at cases of indirect reuse of wastewater as well as groundwater sources with high levels of fluoride and arsenic, we argue that the foregrounding of water quality is key to illuminating social inequalities in access to water and in teasing out power relations prevailing in current hydrosocial regimes. We conclude that this hydrosocial cycle of drinking water is characterised by prioritising access to water for economic actors, facilitated by lax regulations and minimal enforcement, as well as by the systematic neglect by government authorities at all levels of the protection of watersheds and aquifers, and of water quality issues generally.