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721.
Cadmium selenium (CdSe) quantum dots (QDs) are semiconductor nanocrystals that hold wide range of applications and substantial production volumes. Due to unique composition and nanoscale properties, their potential toxicity to aquatic organisms has increasingly gained a great amount of interest. However, the impact of CdSe QDs exposure on zebrafish embryo and larvae remains almost unknown. Therefore, the lab study was performed to determine the developmental and behavioral toxicities to zebrafish under continuous exposure to low level CdSe QDs (0.05-31.25 mg L−1) coated with mercaptopropionic acid (MPA). The results showed MPA-CdSe exposure from embryo to larvae stage affected overall fitness. Our findings for the first time revealed that: (1) The 120 h LC50 of MPA-CdSe for zebrafish was 1.98 mg L−1; (2) embryos exposed to MPA-CdSe resulted in malformations incidence and lower hatch rate; (3) abnormal vascular of FLI-1 transgenic zebrafish larvae appeared after exposure to MPA-CdSe including vascular junction, bifurcation, crossing and particle appearance; (4) larvae behavior assessment showed during MPA-CdSe exposure a rapid transition from light-to-dark elicited a similar, brief burst and a higher basal swimming rate; (5) MPA-CdSe induced embryos cell apoptosis in the head and tail region. Results of the observations provide a basic understanding of MPA-CdSe toxicity to aquatic organisms and suggest the need for additional research to identify the toxicological mechanism. 相似文献
722.
The present study employed ozonation process to treat the bamboo industry wastewater (BIWW). The impact of ozone dosage and initial organic concentration on color, COD and TOC removal rates were studied along with characterization of the major organics in raw and treated wastewater. The results suggested the ozone dosage of 3.15 g h−1 (concentration 52.5 mg L−1) was suitable for the treatment. After 25 min ozonation of 1 L raw wastewater, the color, COD and TOC removal efficiencies were 95%, 56% and 40%, respectively, with an influent COD concentration of 835 mg L−1. The ratio of kg O3 kg−1 COD at 3.15 g h−1 was 2.8 (<3), revealing that ozonation was a cost effective process for tertiary treatment of BIWW. Longer oxidization time was required to achieve similar results for raw wastewater with higher COD concentration. The chromatogram from gel permeation chromatography revealed that ozonation resulted in the breakdown of high molecular weight compounds into lower molecular weight components but could not completely mineralize the organic matter. The majority of these compounds were identified in both raw and ozonated samples via GC-MS analysis. In addition to ester derivatives as the main intermediates of ozonation, 1-chloroctadecane, methyl stearate, benzophenone and α-cyperone were identified as the by-products of ozonation. 相似文献
723.
724.
Fang H Tang FF Zhou W Cao ZY Wang DD Liu KL Wu XW Yu YL 《Journal of environmental science and health. Part. B》2012,47(2):104-110
The effects of repeated applications of the fungicide triadimefon in agricultural soil on the microbial functional diversity of the soil and on the persistence of the fungicide in the soil were investigated under laboratory conditions. The degradation half-lives of triadimefon at the recommended dosage, simulated by a first-order kinetic model, were 23.90, 22.95, and 21.52 days for the first, second, and third applications, respectively. Throughout this study, no significant inhibition of the Shannon-Wiener index (H') was observed. However, the Simpson index (1/D) and the McIntosh index (U) were obviously reduced (p ≤ 0.05) during the initial 3 days after the first triadimefon application and thereafter, gradually recovered to or exceeded the level of the control soil. A similar trend in variation but with a faster recovery in the 1/D and U was observed after the second and third triadimefon applications, respectively. Taken together, the above results indicate that the repeated application of triadimefon enhanced the degradation rate of the fungicide and the recovery rate of the soil microbial functional diversity. It is concluded that repeated triadimefon applications in soil have a transient or temporary inhibitory effect on soil microbial communities. 相似文献
725.
Jiang Y Xu H Zhang W Zhu M Al-Rasheid KA 《Environmental science and pollution research international》2012,19(5):1747-1754
Introduction
In order to reveal the potential relationships between body-size patterns of microzooplankton and environmental status, the spatial patterns in body-size spectra of ciliated zooplanktons were studied based on an annual dataset in a bay of the Yellow Sea, northern China.Materials and methods
A total of 120 samples were collected at a depth of 1?m from each of five sampling sites with a spatial gradient of environmental stress from June 2007 to May 2008. A range of physico-chemical variables were measured synchronously for comparison with biotic parameters.Results
The spatial body-size patterns of ciliated zooplankton represented significant differences among the five sites, and were significantly correlated with the changes of physico-chemical parameters, especially salinity, dissolved oxygen and nutrients. Two paired indices, the average body-size distinctness (AvBSD) and the variation in body-size distinctness (VarBSD), were proposed based on the trait resemblances among ciliate species in body-size pattern. The paired measures showed a clear decreasing trend of departure from the expected body-size spectra in response to water quality status.Conclusion
These results suggest that the body-size pattern of ciliated zooplankton might be used as a potential indicator of marine water quality. 相似文献726.
Li X Zhou Q Wei S Ren W 《Environmental science and pollution research international》2012,19(5):1773-1780
Purpose
Screening out cadmium (Cd) excluding cultivars of a crop in agricultural production is an effective way to prohibit Cd entering into food chain.Methods
A judging criterion for Cd-excluding cultivars based on food safety was suggested and used in the identification of Cd-excluding welsh onion (Allium fistulosum L.) cultivars. A pot culture experiment was carried out to screen out Cd-excluding cultivars, of which the results were confirmed by plot experiments. The relevant factors of Cd accumulation in the pseudostem were analyzed and used in the correlation analysis aiming to study the low Cd accumulation mechanisms.Results
The concentration of Cd in the pseudostem of welsh onions was 0.08?C0.20, 0.18?C0.41, and 0.26?C0.61?mg/kg fresh weight (FW) under three treatments (1.0, 2.5, and 5.0?mg/kg), respectively. The significant (p?0.05) difference in the concentration of Cd in the pseudostem was observed among 25 welsh onion cultivars, but Cd contamination in soil had little influence on biomass and the contents of soluble sugar, NO 3 ? ?CN, and eight other elements in the tested welsh onion cultivars. Two cultivars were identified as Cd-excluding cultivars, mainly because the accumulation of Cd in their pseudostem was only 0.041?±?0.003 and 0.046?±?0.002?mg/kg FW, and 0.054?±?0.001 and 0.066?±?0.011?mg/kg FW, when growing in plots with Cd concentration of 0.49 and 0.99?mg/kg, respectively.Conclusions
Ribentiegancongwang and Wuyeqi could be identified as Cd-excluding cultivars. Low bioaccumulation factor of the roots was the main mechanism of Cd-excluding welsh onion cultivars. 相似文献727.
Xu XY Feng LJ Zhu L Xu J Ding W Qi HY 《Environmental science and pollution research international》2012,19(5):1584-1593
Background, aim, and scope
The start-up pattern of biofilm remediation system affects the biofilm characteristics and operating performances. The objective of this study was to evaluate the performances of the contaminated source water remediation systems with different start-up patterns in view of the pollutants removal performances and microbial community succession.Methods
The operating performances of four lab-scale simulated river biofilm reactors were examined which employed different start-up methods (natural enrichment and artificial enhancement viadischarging sediment with influent velocity gradient increase) and different bio-fillers (Elastic filler and AquaMats? ecobase). At the same time, the microbial communities of the bioreactors in different phases were analyzed by polymerase chain reaction, denaturing gradient gel electrophoresis, and sequencing.Results and discussion
The pollutants removal performances became stable in the four reactors after 2 months?? operation, with ammonia nitrogen and permanganate index (CODMn) removal efficiencies of 84.41?C94.21% and 69.66?C76.60%, respectively. The biomass of mature biofilm was higher in the bioreactors by artificial enhancement than that by natural enrichment. Microbial community analysis indicated that elastic filler could enrich mature biofilm faster than AquaMats?. The heterotrophic bacteria diversity of biofilm decreased by artificial enhancement, which favored the ammonia-oxidizing bacteria (AOB) developing on the bio-fillers. Furthermore, Nitrosomonas- and Nitrosospira-like AOB coexisted in the biofilm, and Pseudomonas sp., Sphaerotilus sp., Janthinobacterium sp., Corynebacterium aurimucosum were dominant in the oligotrophic niche.Conclusion
Artificial enhancement via the combination of sediment discharging and influent velocity gradient increasing could enhance the biofilm formation and autotrophic AOB enrichment in oligotrophic niche. 相似文献728.
Anotai J Thuptimdang P Su CC Lu MC 《Environmental science and pollution research international》2012,19(1):169-176
Background, aim, and scope
The optimal conditions of o-toluidine degradation by fluidized-bed Fenton process were determined using Box–Behnken designs (BBD). The BBD can be used to find the optimal conditions in multivariable systems. The optimal conditions obtained by the design were further applied in the kinetic analysis of o-toluidine oxidation in fluidized-bed Fenton process. 相似文献729.
通过生物降解实验考察三氯乙烯(TCE)在苯酚驯化微生物中的共代谢降解性能,并进行动力学分析。结果表明,苯酚是TCE-苯酚共代谢过程必不可少的共代谢基质;TCE的共代谢降解与苯酚和TCE初始浓度有关。TCE在降解初期会出现一个短暂的迟滞期,TCE的大量降解要在苯酚被利用后才发生;高质量浓度TCE(>9mg/L)对共代谢降解有抑制作用。苯酚/TCE(质量比)在10~15以上时,苯酚菌对TCE的去除率较大。Haldane模型能够很好地拟合苯酚和TCE的比降解速率。动力学分析表明,微生物对苯酚的亲和力要大于TCE,苯酚对TCE共降解具有竞争性抑制作用,TCE对微生物存在毒性抑制作用;结果证实了生物降解实验的结论。 相似文献
730.
考察了不同粒径零价铁(ZVI),包括200目普通铁粉(200m-ZVI)、800目超细铁粉(800m-ZVI)和纳米铁粉(nZVI,粒径=20 nm),对污水污泥的硫化氢和甲烷释放速率的影响。研究发现:(1)在22 d内,添加0.1%的200m-ZVI使污泥的硫化氢释放速率提高48.0%,而添加0.1%的800-ZVI和nZVI,则使污泥的硫化氢释放速率分别降低33.1%和77.1%;(2)不同粒径ZVI均可以提高污泥沼气中的甲烷浓度,且依次为nZVI〉800m-ZVI〉200m-ZVI;(3)在23 d内,添加0.1%的200m-ZVI和nZVI使污泥的甲烷累计产生量分别提高了15.5%和40.6%,而添加0.1%800m-ZVI则使甲烷产生量降低了12.5%。nZVI可以有效控制污泥的硫化氢释放,并显著提升污泥在厌氧发酵过程的产甲烷速率。 相似文献