农村环境质量综合评价技术体系区域适用性验证

长期以来,中国农村环境保护工作基础相对薄弱,国家环保部门于2014年出台《农村环境质量综合评价技术规定(试行)》。研究利用2015—2016年安徽省域的农村环境监测数据,将安徽省重点生态功能区考核县域的数据与其他县域监测数据进行分类整理,采用该技术规定开展农村环境质量综合评价,对评价体系的3个级别指标层面的评价结果进行对比,并通过2组数据的差异性分析,深度剖析评价体系各级指数的结果合理性,验证该评价技术规定的区域适用性;同时,根据各级指标对比中发现的问题,对评价体系的相关指标提出修改完善建议。     

1986~2015年中国东南沿海致灾气旋#br# 及其直接经济损失变化特征

将造成经济损失的热带气旋定义为致灾气旋。基于1986~2015年浙江、福建和广东省180个致灾气旋路径、灾情以及气象数据,研究致灾气旋发生的频次、经标准化处理的经济损失及风雨的时空变化特征。（1）1986~2015年东南沿海地区致灾气旋频数整体呈上升趋势。广东省致灾气旋发生频次最多,浙江省相对较小,但强度高于台风的致灾气旋发生频次增加显著。（2）浙江、福建和广东省致灾气旋造成的经济损失呈上升趋势,但占各省当年GDP的比重均有所减少,广东省比重下降最为显著;浙江省受致灾气旋经济影响最严重,损失较高的致灾气旋发生概率最大,福建省受致灾气旋影响相对较小。（3）降水量及风速是造成致灾气旋直接经济损失的重要因素,风速是影响广东省经济损失的主要因子,浙江省受降水量变化影响显著,而福建省受降水量及风速影响相对较小。浙江省东部和南部、福建省东北部以及广东省东部和西南部致灾气旋发生频次高,引起风速大、降水多,造成直接经济损失最严重。研究结果有利于深化对东南沿海地区热带气旋基本特征及损失的认识,为中国东南沿海热带气旋防灾减灾政策提供了参考。     

SFLA-Verhulst组合模型预测矿井瓦斯涌出量

针对矿井瓦斯涌出量的时变性、波动性、非线性以及不确定性等特征,提出了SFLA-Verhulst组合预测模型,用于对具有非线性动态特征的瓦斯涌出量进行预测。该模型通过蛙跳算法对Verhulst模型的背景值参数寻优,并引入一次指数平滑法对原始数据进行优化处理,建立了基于混合蛙跳算法的SFLA-Verhulst组合预测模型;结果使模型在原始数据不准确或存在误差干扰的情况下仍能进行精度较高的预测。将新模型应用于某矿瓦斯涌出量预测,并对模型的预测结果进行检验分析,结果表明:该模型在结合蛙跳算法的全局寻优特点后预测精度较传统的GM(1,1)模型有明显的提高,适用性更强。     

Spatial and temporal variation of soil organic carbon in the North China Plain

The organic carbon, permeability test, grain size, chemical composition, and mineral composition were analyzed for 147 samples collected from the Luan River catchment, Hebei province, China, to quantitatively characterize the effects of land use, climate change, sedimentary environment, mineral composition, and chemical composition on the spatial and temporal variation of soil organic carbon (SOC). The results indicate that there was higher SOC content and stronger variation in the south plain than in the northern low mountain. The effects of land use, climate change, and sedimentary environment on SOC distribution were greater than the effects of mineral composition and chemical composition. The cropping systems in the Luan River catchment resulted in significant difference in SOC concentration between the south plain and north mountain. The precipitation mainly transmitted its effects through the sedimentary environment to SOC, which caused the stronger temporal variation in SOC from June to October in the south plain. The north mountain did not have significant temporal variation because of the lower hydraulic conductivity of the sedimentary sequence. The spatial variation of SOC was correlated with land use, and their temporal variation was attributed to climate change and sedimentary environment. Apart from land use, the decision maker can also affect the organic carbon mineral and sequence through the sedimentary environment.     

基于混合生命周期方法的私人电动汽车温室气体排放研究

近年来,电动汽车因其在行驶过程中无任何尾气排放,被各国政府视为推动交通部门清洁、低碳发展的重要途径,主要发达国家纷纷推出了各自的电动汽车发展战略。但是,由于电力属于二次能源,其上游电力生产阶段的能源消费是否清洁将对电动汽车的减排效果产生重要影响。考虑到目前中国绝大部分电力源于煤炭,电动汽车是否真正有益于减排还有待进一步验证。目前一些专家和学者基于传统的过程生命周期评价方法对电动汽车的能源消费、温室气体排放做了一些研究,但研究结果差异较大。为了对电动汽车的减排效果进行更精确的研究,本文采用混合生命周期方法对电动汽车的能源消费、温室气体排放进行了计算。同时,在考虑电动汽车的燃料生命周期、车辆制造生命周期的基础上,将相关配套充电设施建设生命周期纳入到电动汽车的全生命周期系统边界内,以使对电动汽车全生命周期的研究结果更加完整、精确。研究结果显示,纯电动汽车并非是"零排放"的,在燃料周期,虽然纯电动汽车的单位里程能源消费强度较小,约为传统汽油车的94.6%,但以煤为主的高碳电力结构导致目前纯电动汽车燃料周期的单位里程温室气体排放强度约为传统汽油车的1.12倍;车辆周期内,纯电动汽车的能源消费和温室气体排放量也略高于传统汽油车;此外,配套充电设施的建设也将增加纯电动汽车全生命周期的能源消费和温室气体排放量。综合燃料、车辆及充电设备的全生命周期,在当前的电源结构及技术条件下,电动汽车虽然具有较高的能源效率和较好的石油替代效果,但其全生命周期内的煤炭消费较高,导致其温室气体排放量高于传统汽油车,在当前的情况下大规模发展电动汽车并不利于温室气体减排。     

1996~2013年长江经济带工业发展过程中的大气环境污染效应

大气污染物排放及影响因素研究,是引导区域减排实现可持续发展的重要依据。利用Tapio脱钩模型测度了1996~2013年长江经济带11个省区工业经济增长与工业废气、工业二氧化硫、工业烟粉尘3个指标之间的脱钩程度,并利用LMDI分解模型对大气污染物排放变化特征进行了影响因素分解。结果表明：（1）长江经济带11个省（市）的工业废气排放量呈持续上升的趋势,且工业废气排放量的“热”点区域主要集中在东部地区,工业二氧化硫和烟粉尘两种大气污染物排放量总体呈现“先增加后减少”的趋势,状况有所改善。（2）长江经济带工业废气排放整体经历了从扩张性负脱钩到相对脱钩发展的趋势,表明经济发展的同时带来工业废气排放的污染同步增长。经济发展效应和能源效率效应是促使工业废气排放的主要因素。（3）长江经济带的工业二氧化硫和烟粉尘排放整体上经历了从相对脱钩向绝对脱钩发展的趋势,经济发展均是造成各地区两种污染物排放量增加的主要原因,技术效应和能源效率是各地区两种污染物减排的重要影响因素。未来,在大气污染物的减排控制过程中,需加强产业结构、能源结构的调整,也需坚定依靠技术进步推动能源使用效率的提高,并且注重各省市间的减排差异和防范污染产业的区域转移。关键词： 长江经济带;经济增长;大气环境;脱钩分析模型;LMDI分解模型     

有色冶金区土壤-蔬菜系统重金属污染特征及健康风险分析

采用对应采样方法研究大冶有色冶炼厂周围地区土壤、蔬菜中Cd、Cu、Pb和As的含量,并对蔬菜重金属污染状况、富集能力及健康风险进行了分析。结果表明,研究区土壤重金属污染严重,Cd、Cu、Pb和As平均含量分别达5.28、193.37、93.83和36.56 mg/kg,分别为湖北省对应元素土壤背景值的31.06、6.30、3.51和2.97倍,表现为以Cd为主的多种重金属共同污染。与《食品中污染物限量》(GB2762-2012)标准比较,蔬菜中Cd和Cu含量的样本超标率分别为68%和6%,而As、Pb的含量均不超标。蔬菜中重金属富集能力的排序为:CdCuAsPb,叶菜类蔬菜对Cd、Cu、Pb和As的富集系数均高于非叶菜类蔬菜。土壤和蔬菜重金属综合质量指数达10.07,为重度污染。研究区人群通过蔬菜摄入As、Cd的目标危险系数均大于1,存在As、Cd暴露的健康风险;成人和儿童食用蔬菜而摄入重金属的TTHQ分别为2.11~5.06和2.78~6.64,儿童比成人遭受的健康风险更大,并且距离冶炼厂越近,所遭受的健康风险越大。蔬菜中重金属的复合污染已使大冶有色冶炼厂周围居民面临潜在的健康风险。     

Solar-induced generation of singlet oxygen and hydroxyl radical in sewage wastewaters

Singlet oxygen (¹O₂) and hydroxyl radical (·OH) play an important role in the degradation of pollutants in surface waters. However, the mechanism underlying the photochemical generation of ¹O₂ and ·OH in wastewaters is poorly known. Here we studied the photo-induced generation of ¹O₂ and ·OH in different sewage treatment plant units. The correlation between the generation of ¹O₂ and ·OH and the water constituents was discussed. Our results show that in sewage units the ¹O₂ formation rate ranges from 2.19 × 10^?8 to 6.74 × 10^?8 mol L^?1 s^?1, and the ·OH formation rate ranges from 1.7 × 10^?11 to 3.06 × 10^?10 mol L^?1 s^?1. The average ¹O₂ formation rates in the various sewage units are similar to those in wetland and estuarine waters containing rich dissolved organic matter and 2–4 times higher than those in lake and seawater samples. The average ·OH formation rates of the sewage units are 5–50 times higher than for other water samples reported. The ·OH generation rate increased with the iron content with a correlation coefficient of 0.85, which indicates that the photo-Fenton reaction plays a dominant role in ·OH generation in sewage wastewater.     

Large eddy simulation of flow and scalar transport in a vegetated channel

Predicting flow and mass transport in vegetated regions has a broad range of applications in ecology and engineering practice. This paper presents large eddy simulation (LES) of turbulent flow and scalar transport within a fully developed open-channel with submerged vegetation. To properly represent the scalar transport, an additional diffusivity was introduced within the canopy to account for the contribution of stem wakes, which were not resolved by the LES, to turbulent diffusion. The LES produced good agreement with the velocity and concentration fields measured in a flume experiment. The simulation revealed a secondary flow distributed symmetrically about the channel centerline, which differed significantly from the circulation in a bare channel. The secondary circulation accelerated the vertical spread of the plume both within and above the canopy layer. Quadrant analysis was used to identify the form and shape of canopy-scale turbulent structures within and above the vegetation canopy. Within the canopy, sweep events contributed more to momentum transfer than ejection events, whereas the opposite occurred above the canopy. The coherent structures were similar to those observed in terrestrial canopies, but smaller in scale due to the constraint of the water surface.     

Occurrence and human dietary assessment of sulfonamide antibiotics in cultured fish around Tai Lake,China

As the most important fishery medicines, sulfonamides are widely used to prevent diseases caused by pathogens in aquaculture. However, relatively little is known about the residues and dietary risks associated with cultured fish around Tai Lake. In the present study, a sampling strategy for a complete aquaculture period was conducted. Specifically, 12 selected sulfonamide antibiotics were measured among 116 fish samples recruited from four sampling periods, four species, four areas, and 18 fish ponds. All 12 antibiotics were detected at detection frequencies of 4.31–28.45%. Total sulfonamides were detected in 77.59% of the fish samples, with 57.76% of fish samples containing from 0.1 to 10 μg kg^?1. Sulfadiazine (SDZ), sulfamethoxazole (SMZ), sulfamethazine (SDD), and sulfamonomethoxine (SMM) were the main types of antibiotics used, and these were present at high concentrations (>100 μg kg^?1) with high occurrences, especially in the middle of the aquaculture season. Dietary assessment showed that residual antibiotics in all fish that were being sent to market were far below the maximum residue limit (MRL) of total sulfonamides and that there was almost no risk associated with fish consumption. The results of the present study will facilitate development of effective measures to produce safe aquatic products and meaningful suggestions for consuming aquatic products.