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101.
102.
Hsi-Hsien Yang Sunil Kumar Gupt Narayan Babu Dhital Lin-Chi Wang Suresh Pandian Elumalai 《环境科学学报(英文版)》2020,32(6):245-255
Volatile organic compounds(VOCs) are the important precursors of the tropospheric ozone(O_3) and secondary organic aerosols(SOA),both of which are known to harm human health and disrupt the earth's climate system.In this study,VOC emission factors,O_3 and SOA formation potentials were estimated for two types of industrial boilers:coal-fired boilers(n=3) and oil-fired boilers(n=3).Results showed that EVOCs concentrations were more than nine times higher for oil-fire d boilers compared to those for coal-fired boilers.Emission factors of ΣVOCs were found to be higher for oil-fired boilers(9.26-32.83 mg-VOC/kg) than for coal-fired boilers(1.57-4.13 mg-VOC/kg).Alkanes and aromatics were obtained as the most abundant groups in coal-fired boilers,while oxygenated organics and aromatics were the most contributing groups in oil-fired boilers.Benzene,n-hexane and o-ethyl toluene were the abundant VOC species in coal-fired boiler emissions,whereas toluene was the most abundant VOC species emitted from oil-fired boilers.O_3 and SOA formation potentials were found 12 and 18 times,respectively,higher for oil-fired than for coal-fired boilers.Total OFP ranged from 3.99 to 11.39 mg-O_3/kg for coal-fired boilers.For oil-fired boilers,total OFP ranged from 36.16 to 131.93 mg-O_3/kg.Moreover,total secondary organic aerosol potential(SOAP) ranged from 65.4 to 122.5 mg-SOA/kg and 779.9 to 2252.5 mg-SOA/kg for the coal-fired and oil-fired boilers,respectively. 相似文献
103.
Ankita Bedi Braj Raj Singh Sunil K. Deshmukh Nisha Aggarwal Colin J. Barrow Alok Adholeya 《环境科学学报(英文版)》2018,30(5):356-367
In this study, an ecofriendly and economically viable waste management approach have been attempted towards the biosynthesis of agriculturally important nanoparticles from jarosite waste. Aspergillus terreus strain J4 isolated from jarosite(waste from Debari Zinc Smelter,Udaipur, India), showed good leaching efficiency along with nanoparticles(NPs) formation under ambient conditions. Fourier-transform infrared spectroscopy(FT-IR) and transmission electron microscopy(TEM) confirmed the formation of NPs. Energy dispersive X-ray spectroscopy(EDX analysis) showed strong signals for zinc, iron, calcium and magnesium,with these materials being leached out. TEM analysis and high resolution transmission electron microscopy(HRTEM) showed semi-quasi spherical particles having average size of 10‐50 nm. Thus, a novel biomethodology was developed using fungal cell-free extract for bioleaching and subsequently nanoconversion of the waste materials into nanostructured form. These biosynthesized nanoparticles were tested for their efficacy on seed emergence activity of wheat(Triticum aestivum) seeds and showed enhanced growth at concentration of 20 ppm. These nanomaterials are expected to enhance plant growth properties and being targeted as additives in soil fertility and crop productivity enhancement. 相似文献
104.
Sunil K. Chaudhary Reginald H. Mitchell Paul R. West Michael J. Ashwood-Smith 《Chemosphere》1985,14(1):27-40
Reductive degradation of the pesticide methoxychlor by photolysis in the presence of hydroquinone in dilute solutions of acetonitrile or 1:1 aqueous t-butanol leads to processes other than simple dechlorination. Direct radical coupling with hydroquinone forms a markedly estrogenic conjugate. A pH dependant molecular rearrangement gives pro-estrogenic 4,4′-dimethoxy-α,α′-dichlorostilbenes, and condensation with hydroquinone yields the chlorine free polycyclic aromatic, 12-hydroxy-3,6-dimethoxybenzo[b]phenanthro[9,10-d]furan. 相似文献
105.
Ammonia toxicity tests were performed with Labeo bata (bata) larvae of three different size groups. One hundred percent survival of larvae (500.0?±?4.0?mg) was recorded when exposed to ammonia concentrations of 1.0–13.56?mg?L?1 at 96?h of exposure. Bata larvae exposed to ammonia concentrations of 15.8–25?mg?L?1 showed 10–74% mortalities. The 96?h LC50 value for 200 (±5), 250 (±2) and 500 (±4) mg bata larvae were 11.5, 16.8 and 22.5?mg?L?1 un-ionised ammonia concentrations, respectively. When fish were exposed to different doses of ammonia, behavioural changes immediately occurred even at the lowest dose. At first, the fish became hyperexcitable, the skin darkened and they showed an increased ventilation frequency, fish behaviour became normal, 24?h after exposure. A 96?h LC50 value of un-ionised ammonia showed direct relationship with the increasing size of bata larvae. 相似文献
106.
Freshwater catfish, Heteropneustes fossilis, were subjected to 42 mg L?1 of azadirachtin for short-term exposure (96 h) and to 10.5 mg L?1 for long-term exposure (28 days). Six fishes were sacrificed on each time interval from control and experimental groups after 24, 48, 72, and 96 h in the short-term exposure and after 7, 14, 21, and 28 days in the long-term experiment. The calcium regulating endocrine gland, viz. the ultimobranchial gland, was fixed for histological studies. Up to 72 h of azadirachtin treatment, there was no histological alteration in the UBG (ultimobranchial gland) of H. fossilis. After 96 h exposure, the ultimobranchial cells stain feebly and the nuclear volume of these cells were slightly decreased. No histological alterations have been observed in the UBG cells up to 14 days following azadirachtin exposure. After 21 days, the cytoplasm of ultimobranchial cells was feebly stained and the nuclear volume exhibits a decrease. The nuclear volume of these cells was further decreased and the gland shows vacuolization and degeneration at certain places after 28 days azadirachtin treatment. Hence, it can be concluded that azadirachtin severely affects the physiology of calcium homeostasis in H. fossilis. Therefore, the botanical pesticides should be used carefully near aquatic reservoirs. 相似文献
107.
Akhilesh Kumar Yadav Sunil Kumar Sahoo Swagatika Mahapatra A. Vinod Kumar Govind Pandey Pradyumna Lenka 《毒物与环境化学》2013,95(2):192-200
The present work deals with the determination of uranium concentrations in drinking and ground water samples by laser fluorimetry and calculation of cumulative, age-dependent radiation doses to humans. The concentrations were found to be between 0.20 ± 0.03 and 64.0 ± 3.6 μg L?1, with an average of 11.1 ± 1.5 μg L?1, well within the drinking water limit of regulatory bodies. The concentrations of uranium increase with depth of water samples collection. The estimated annual ingestion dose due to the intake of uranium through drinking water for all age groups varied between 0.2 and 137 μSv a?1, with an average of 17.3 μSv a?1. The mean annual ingestion dose is 5% of the global average ingestion dose, for infants, marginally higher than for other age group. Most effective dose values were less than 20 μSv a?1. 相似文献
108.
Deepmala Joshi Deepak Kumar Mittal Ranjit Kumar Ajai Kumar Srivastav Sunil Kumar Srivastav 《毒物与环境化学》2013,95(9):1581-1588
Mercury (Hg) is a potent nephrotoxin. The aim of this study was to investigate the protective role of Curcuma longa extract and curcumin against HgCl2-induced nephrotoxicity. Male Sprague Dawley rats were administered HgCl2 (12 μmol kg?1, ip; once only) followed by treatment of Curcuma longa extract (200 mg kg?1, po) and curcumin (80 mg kg?1, po) for three days after 24 h of HgCl2 administration. The present results showed that mercuric chloride administration caused an impairment of renal function system which was evident from significant increase in urea, creatinine, uric acid, and blood urea nitrogen concentration in serum. In addition, the swelling in glomerulus and degenerated renal tubules with obstructed lumen was also observed by acute mercuric chloride administration. Treatment with Curcuma longa extract and curcumin was effective in restoring all variables of kidney functions near to control group, which was consistent with kidney histoarchitecture. In conclusion, these results suggest that Curcuma longa extract and curcumin protect against HgCl2-induced nephrotoxicity. This study could be important for the further understanding of mercury toxicity in renal tissues and in the development of better treatments for people and/or animals exposed to the metal. 相似文献
109.
L.S. Rawat R.K. Maikhuri Vikram S. Negi Abhay Bahuguna K.S. Rao Sunil K. Agarwal 《国际发展与全球生态学杂志》2013,20(5):423-430
Traditional Central Himalaya societies face a range of socio-economic and environmental problems. The potential of science and technology has not yet been adequately and appropriately harnessed to overcome the development constraints posed by the fragile Himalayan environment. Thus there is a need for large-scale establishment of technology resource centers. The Garhwal Unit of GB Pant Institute of Himalayan Environment and Development established rural technology demonstration and training centers in three different agroecological zones between 550 and 2200 m asl and in 13–15 locations, with suitable technologies based on appropriate use and management of locally available bio-resources that ensure people participation. About 35 on-site training courses were organised for about 2329 participants. The participants were given on-site demonstrations, training and technical know-how on various technologies, to enable farmers to better understand problems faced during implementation of new technologies for sustainable management of natural resources. An action research framework and training manuals were also developed in consideration of local socio-economic condition. The documentation and analysis of research (quantitative and qualitative) and data related to cost–benefit analysis of the technologies adopted by farmers generated through this study has created wider sharing of farmer training outputs, at farm level, amongst the scientific communities and with policy planners. 相似文献
110.
Sunil D. Santha 《Natural resources forum》2007,31(1):61-70
This article attempts to analyse the social interface between formal institutions and local fishing communities along the Pamba‐Achankovil River Basin in Kerala, India. It examines primarily the nature of the relationship between state agencies and traditional fishing communities in the context of (i) enforcing certain formal regulations of resource use and (ii) implementing resource enhancement programmes. The article also analyses the nature of social interfaces that emerge when local level formal organizations, such as cooperatives and gram panchayats, take up resource management or community welfare schemes on behalf of the traditional fisherfolk in the study region. Social interfaces can be understood in terms of social processes, such as cooperation, accommodation and conflicts between various actors involved in fisheries management. The article is based on ethnographic fieldwork. Interview guides and focus group discussions were the primary tools of data collection. The findings show that the relationships between formal institutions and traditional riverine fishing communities lack mutual trust. Conflicts between fishing communities and state agencies emerge when the formal institutions threaten or contradict those elements of local culture that sustain livelihood needs. Conflicts and discontent with a particular formal institution can also lead to the modification or violation of coexisting institutional arrangements. 相似文献