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151.
Suresh K. Aggarwal Xiao Fu Sameera Wijeyakulasuriya 《International Journal of Green Energy》2016,13(5):431-445
Recent strategies for simultaneously reducing NOx and soot emissions have focused on achieving nearly premixed, low-temperature combustion (LTC) in diesel engines. A promising approach in this regard is to vary fuel reactivity in order to control the ignition delay and optimize the level of premixing and reduce emissions. The present study examines such a strategy by performing 3-D simulations in a single-cylinder of a diesel engine. Simulations employ the state-of-the-art two-phase models and a validated semi-detailed reaction mechanism. The fuel reactivity is varied by using a blend of n-heptane and iso-octane, which represent surrogates for gasoline and diesel fuels, respectively. Results indicate that the fuel reactivity strongly influences ignition delay and combustion phasing, whereas the start of injection (SOI) affects combustion phasing. As fuel reactivity is reduced, the ignition delay is increased and the combustion phasing is retarded. The longer ignition delay provides additional time for mixing, and reduces equivalence ratio stratification. Consequently, the premixed combustion is enhanced relative to diffusion combustion, and thus the soot emission is reduced. NOx emission is also reduced due to reduced diffusion combustion and lower peak temperatures caused by delayed combustion phasing. An operability range is observed in terms of fuel reactivity and SOI, beyond which the mixture may not be sufficiently well mixed, or compression ignited. The study demonstrates the possibility of finding an optimum range of fuel reactivity, SOI, and EGR for significantly reducing engine out emissions for a given load and speed. 相似文献
152.
P. Suresh S. Ramabalan U. Natarajan 《International Journal of Sustainable Engineering》2016,9(2):107-118
The recent developments in manufacturing organizations recognize sustainability as an important value addition for survival in the competitive scenario. The design engineers are in search of approaches for creating environmental conscious products. The purpose of this paper is to report a research carried out for ensuring sustainable product design by the integration of Design for Environment (DFE) and Design for Manufacture and Assembly (DFMA) methodologies. In this context, this paper reports a case study carried out in an automotive component. The candidate product is the charge alternator pulley. The existing pulley has been created using Computer Aided Design. Then sustainability analysis was conducted on the existing component for determining environmental impact. This is followed by the engineering analysis of the component using ANSYS. Then conceptual design changes were developed in the proposed product using DFMA concept. Then the environmental impact has been evaluated in terms of carbon footprint, energy consumption and air/water impacts on proposed product. It has been found that the optimized pulley design possesses minimal environmental impact. The result of the case study indicated that the integration of DFE and DFMA concept could initiate new developments in sustainable designs with minimal impact to the environment and it also reduces the product cost. 相似文献
153.
Aditi Kundu Najam Akhtar Shakil Dinesh B. Saxena Pankaj Jitendra Kumar Suresh Walia 《Journal of environmental science and health. Part. B》2013,48(5):428-434
Twelve new ortho-Hydroxyketimines were synthesized by conventional as well as microwave method and evaluated for their antinemic activity against Meloidogyne incognita [(Kofoid and White) Chitwood]. Conventional methods for synthesis of Schiff bases require refluxing at 140°C of the reactants in different solvents for at least 24 h or more, where as the microwave-assisted synthesis has brought down the reaction time from 24 h to 1 minute. The procedure reported is simple as it does not require any organic solvents and the time has been reduced to only 1 minute. Comparative yields of all compounds by different methods revealed that the yield was low in conventional method (79–87%) as compared to microwave assisted synthesis (94–97%). The bioassay revealed that all the test compounds exhibited promising nematicidal activity; N-propyl-2-hydroxypropiophenonimine being the most effective with LC50 value of 74.46 mgL?1 followed by N-hexyl-2-hydroxyacetophenonimine with LC50 value of 99.60 mgL?1 after 72 h of exposure. The results obtained from bioassay indicated that this class of compounds has not only given a lead with regard to potential of Schiff bases in pest control, but has suggested that a carbon chain length of 6 atoms in the side chain is optimum on the basis of structure activity relationship (SAR). 相似文献
154.
Jitendra Kumar Keyath Nisar N. A. Shakil Suresh Walia Rajender Parsad 《Journal of environmental science and health. Part. B》2013,48(4):330-335
Controlled release (CR) formulations of metribuzin in Polyvinyl chloride [(PVC) (emulsion)], carboxy methyl cellulose (CMC), and carboxy methyl cellulose-kaolinite composite (CMC-KAO), are reported. Kinetics of its release in water and soil was studied in comparison with the commercial formulation (75 DF). Metribuzin from the commercial formulation became non-detectable after 35 days whereas it attained maxima between 35–49 days and became non-detectable after 63 days in the developed products. Amongst the CR formulations, the release in both water and soil was the fastest in CMC and slowest in PVC. The CMC-KAO composite reduced the rate of release as compared to CMC alone. The diffusion exponent (n value) of metribuzin in water and soil ranged from 0.515 to 0.745 and 0.662 to 1.296, respectively in the various formulations. The release was diffusion controlled with half release time (t1/2) from different controlled release matrices of 12.98 to 47.63 days in water and 16.90 to 51.79 days in soil. It was 3.25 and 4.66 days, respectively in the commercial formulation. The period of optimum availability of metribuzin in water and soil from controlled released formulations ranged from 15.09 to 31.68 and 17.99 to 34.72 days as against 5.03 and 8.80 days in the commercial formulation. 相似文献
155.
Kumar KS Suvardhan K Rekha D Kiran K Rao GC Jayaraj B Janardhanam K Chiranjeevi P 《Environmental monitoring and assessment》2007,129(1-3):271-276
Facile, selective and sensitive spectrophotometric method has been developed for the determination of carbosulfan in insecticidal
formulations, fortified water, food grains, agriculture wastewater and soil samples with newly synthesized reagents. The method
was based on acid and alkaline hydrolysis of the carbosulfan pesticide, and the resultant hydrolysis product of carbosulfan
was coupled with 2,6-dibromo-4-methylaniline to give a yellow color product with λ
max of 464 nm or interaction with 2,6-dibromo-4-nitroaniline to produce yellow colored product with λ
max of 408 nm or coupling with 2,4,6-tribromoaniline to form red colored product has a λ
max of 471 nm. Under optimal conditions, Beer’s law range for 2,6-dibromo-4-methylaniline (DBMA) was found to be 0.2–12.0 μg
ml−1, 0.6–16.0 μg ml−1 for 2,6-dibromo-4-nitroaniline (DBNA) and 0.4–15.0 μg ml−1 for 2,4,6-tribromoaniline (TBA). The molar absorptivity of the color systems were found to be 3.112 × 104 l mol−1 cm−1 for DBMA, 3.214 × 104 l mol−1 cm−1 for DBNA and 3.881 × 104 l mol−1 cm−1 for TBA. Sandell’s of the color reactions are 0.013 μg cm−2 (DBMA), 0.012 μg cm−2 (DBNA) and 0.011 μg cm−2 (TBA) respectively. The effect of the non-target species on the determination of carbosulfan was studied to enhance the selectivity
of the proposed methods. The formation of colored derivatives with the coupling agents is instantaneous and stable for 28,
30, and 26 h. Performance of the proposed methods were compared statistically in terms Student’s F and t-tests with the reported methods.
An erratum to this article can be found at 相似文献
156.
Chenniappan Maheswari Suresh Ramya Rajoo Baskar Nachimuthu Selvakumar Rajaram Rishab Govind Malaichamy Vasanth 《Environmental science and pollution research international》2022,29(44):66068-66084
Environmental Science and Pollution Research - The major emission sources of NOX are from automobiles, trucks, and various non-road vehicles, power plants, coal fired boilers, cement kilns,... 相似文献
157.
Lawrence Jino Mohanadhas Berlin Narayanan Natarajan Kumar Alagarsamy Vanav Mangottiri Vasudevan Govindarajan Suresh Kumar 《Environmental science and pollution research international》2022,29(57):85922-85944
Environmental Science and Pollution Research - Subsurface contamination is a frequent occurrence in fractured porous systems, posing a potential threat for the groundwater contamination. Tracking... 相似文献
158.
Cuprys Agnieszka Thomson Paisley Suresh Gayatri Roussi Tarek Brar Satinder Kaur Drogui Patrick 《Environmental science and pollution research international》2022,29(7):10112-10121
Environmental Science and Pollution Research - Ciprofloxacin (CIP), a widely used antibiotic, is frequently detected in the environment due to insufficient wastewater and water treatment. Hence,... 相似文献
159.
Antil Monika Singh Surinder Bhagat Mamta Vilvas Vishal Sundaramurthy Suresh 《Environmental science and pollution research international》2022,29(48):72279-72293
Environmental Science and Pollution Research - The objective of this study deals with column optimization of adsorption-based on removal of arsenite ion using rice husk. The parameters affecting... 相似文献