Although high concentrations of trace organic pollutants were recorded along the Egyptian Mediterranean Coast and its corresponding coastal wetlands, no published data are available for the levels of phenolic compounds. Thus, this work aimed to investigate the levels of phenolic compounds in sediments of a heavily polluted coastal wetland (Lake Maryut, Egypt). For that purpose, a method was optimized for the extraction and detection of chlorophenols, methylphenols, and nitrophenols in sediments using GC-MS. Sediments were extracted with 0.1 M NaOH/methanol by sonication. Cleanup of sediment extracts using liquid–liquid extraction and SPE was found important to remove most of the interfering co-extracts. The proposed analytical methodology was validated by analysis of matrix spikes. Detection limits were 0.063–0.694 μg/kg dw for sediments. Good recoveries (70–110%) and precision values (RSD?<?20%) were obtained from the fortification experiments at the parts per billion level in sediments. The method was applied to investigate the level of contamination with phenols in 19 sediment samples from Lake Maryut. Results revealed that higher concentrations were observed in the main basin (MB) of Lake Maryut affected by the discharge of effluents from a primary wastewater treatment plant, direct discharge of industrial effluents, domestic wastes, and agricultural effluents from Qalaa Drain (QD). Chlorophenols (CPs) were the major group detected in the lake sediments followed by methylphenols (MPs) and nitrophenols (NPs). CPs were dominated by 2-, 4-, and 3-chlorophenols. Concentrations of CPs were higher at the north and northwestern parts of the MB indicating the influence of industrial effluents discharged into the lake. On the other hand, higher concentrations of NPs were observed at the south and southwestern parts of the MB, which is subjected to the discharge of agricultural and domestic effluents via QD. Results of the risk assessment revealed that phenol, cresols, 2,4-dinitrophenol, 4-NP, 2-CP, 2,3,4,6-tetrachlorophenol and 2,4-dimethylphenol are contaminants of concern and that adverse ecological effects could possibly occur to benthic species from the exposure to these pollutants in Lake Maryut and thus phenols should be included in monitoring and pollution prevention programs in the Egyptian aquatic environment affected by anthropogenic activities. 相似文献
Various and diverse industrial safety areas were identified and grouped as under: general areas of safety, Special areas of safety and industry specific areas of safety.
General areas of safety are common to all industries and special areas of safety are relevant only if the selected industry has such nature of work or hazard and whereas the industry specific areas of safety refers to process safety of the industry. Three separate modules were prepared along with contents.
For conduction of the programme, the selected industry must be studied and the designed safety education programme modules have to be adapted by leaving irrelevant areas in special and industry specific areas of the designed safety modules. The implementation of safety education programme was carried out at Bharath Heavy Electricals Ltd, Trichy and Southern Railway workshop, Trichy, by adapting the designed modules to suit these industries as mentioned above.
Effectiveness is measured by the increase in safety awareness of the selected industrial workers (sample), who had already undergone such programmes with short falls conducted within the industry itself. Research Tool was prepared based on the contents of the adapted safety education modules and pre-test and post-test were conducted, data collected and analysed.
The results were statistically significant as confirmed by t-test analyses. 相似文献
/ This study aims to investigate the ISO 14001 implementation process and its implications for regional environmental management. The region of Central Japan (known as Chubu in Japanese, which literally means center) was chosen for this case study. The study focuses on selected issues such as the: (1) trends and motives of private firms in the implementation of an ISO 14001-based environmental management system (EMS); (2) obstacles during system implementation; (3) role of the system in enhancing environmental performance within the certified organization; and (4) relation between the major stakeholders, local citizens, governments, and firms after adopting the system. To achieve these objectives, a questionnaire survey was mailed to all certified firms in the region. A 58% response was achieved overall. The results show that the main aims behind the adoption of ISO 14001 by firms in the Chubu region are to improve the environmental aspects within the enterprises and to enhance the employees' environmental awareness and capacity. The results have also shown that the ISO 14001-based EMS has had a great effect on a firm's environmental status as certified firms have claimed that natural resources such as fuel, water, and paper consumption have been more efficiently managed after adopting the system. Implementation of the system causes the firms to consider the role of the local people and the government in more effectively involving the local people in the firm's daily environmental activities. It also helps to enhance the environmental awareness among the local people. Adopting the system also promotes a better relation within the enterprises affiliated to the same group, such as more attention given by the parent firms (head offices) towards other firms working for the same group, or branches-mainly small and medium sized enterprises (SMEs)-in the field of EMS. Finally, the results show that firms give serious consideration to their final products' impacts on the environment. In other words, attention is given to life cycle analysis (LCA) among certified firms. 相似文献
The objective of this paper is to synthesize the large literature recording changing patterns of precipitation in the observed data, thus indicating that climate change is already a reality. Such a synthesis is required not only for environmental researchers but also for policy makers. The key question is the broad picture at major regional and continental levels. Some interesting conclusions for this survey are emerging. For example, the review shows increased variance of precipitation everywhere. Consistent with this finding, we observe that wet areas become wetter, and dry and arid areas become more so. In addition, the following general changing pattern is emerging: (a) increased precipitation in high latitudes (Northern Hemisphere); (b) reductions in precipitation in China, Australia and the Small Island States in the Pacific; and (c) increased variance in equatorial regions. The changes in the major ocean currents also appear to be affecting precipitation patterns. For example, increased intensity and frequency of El Ni?o and ENSO seem associated with evidence of an observed "dipole" pattern affecting Africa and Asia, although this time series is too short so far. But the changing pattern calls for renewed efforts at adaptation to climate change, as the changing precipitation pattern will also affect the regional availability of food supply. 相似文献
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