Evaluation of Deposited Sediment and Macroinvertebrate Metrics Used to Quantify Biological Response to Excessive Sedimentation in Agricultural Streams

The objective of this study was to evaluate which macroinvertebrate and deposited sediment metrics are best for determining effects of excessive sedimentation on stream integrity. Fifteen instream sediment metrics, with the strongest relationship to land cover, were compared to riffle macroinvertebrate metrics in streams ranging across a gradient of land disturbance. Six deposited sediment metrics were strongly related to the relative abundance of Ephemeroptera, Plecoptera and Trichoptera and six were strongly related to the modified family biotic index (MFBI). Few functional feeding groups and habit groups were significantly related to deposited sediment, and this may be related to the focus on riffle, rather than reach-wide macroinvertebrates, as reach-wide sediment metrics were more closely related to human land use. Our results suggest that the coarse-level deposited sediment metric, visual estimate of fines, and the coarse-level biological index, MFBI, may be useful in biomonitoring efforts aimed at determining the impact of anthropogenic sedimentation on stream biotic integrity.     

Compliance with Wetland Mitigation Standards in the Upper Peninsula of Michigan, USA

The United States has lost about half its wetland acreage since European settlement, and the effectiveness of current wetland mitigation policies is often questioned. In most states, federal wetland laws are overseen by the U.S. Army Corps of Engineers, but Michigan administers these laws through the state's Department of Environmental Quality (MDEQ). Our research provides insight into the effectiveness of the state's implementation of these laws. We examined wetland mitigation permit files issued in Michigan's Upper Peninsula between 2003 and 2006 to assess compliance with key MDEQ policies. Forty-six percent of files were out of compliance with monitoring report requirements, and forty-nine percent lacked required conservation easement documents. We also conducted site assessments of select compensatory wetland projects to determine compliance with MDEQ invasive plant species performance standards. Fifty-five percent were out of compliance. We found no relationship between invasive species noncompliance and past site monitoring, age of mitigation site, or proximity to roads. However, we found wetland restoration projects far more likely to be compliant with performance standards than wetland creation projects. We suggest policy changes and agency actions that could increase compliance with wetland restoration and mitigation goals.     

The 2007‐2009 Drought in Athens,Georgia, United States: A Climatological Analysis and an Assessment of Future Water Availability1

Campana, Pete, John Knox, Andrew Grundstein, and John Dowd, 2012. The 2007‐2009 Drought in Athens, Georgia, United States: A Climatological Analysis and an Assessment of Future Water Availability. Journal of the American Water Resources Association (JAWRA) 48(2): 379‐390. DOI: 10.1111/j.1752‐1688.2011.00619.x Abstract: Population growth and development in many regions of the world increase the demand for water and vulnerability to water shortages. Our research provides a case study of how population growth can augment the severity of a drought. During 2007‐2009, a drought event that caused extreme societal impacts occurred in the Athens, Georgia region (defined as Clarke, Barrow, Oconee, and Jackson counties). An examination of drought indices and precipitation records indicates that conditions were severe, but not worse than during the 1925‐1927, 1954‐1956, and 1985‐1987 drought events. A drought of similar length to the 2007‐2009 drought would be expected to occur approximately every 25 years. Streamflow analysis shows that discharge levels in area streams were at a record low during 2007 before water restrictions were implemented, because of greater water usage caused by recent population increases. These population increases, combined with a lack of water conservation, led to severe water shortages in the Athens region during late 2007. Only after per capita usage decreased did water resources last despite continuing drought conditions through 2009. Retaining mitigation strategies and withdrawal levels such as seen during the height of the drought will be an essential strategy to prevent water shortages during future extreme drought events. The key mitigation strategy, independent local action to restrict water use in advance of state‐level restrictions, is now prohibited by Georgia State Law.     

Leaching of Cu and Zn from discarded boat paint particles into tap water and rain water

We studied the leaching of copper and zinc from particles of discarded boat paint added to tap water (pH 7.3) and rain water (pH = 4.7), simulating conditions encountered during the hosing or runoff of antifouling waste. Leaching rates appeared to be diffusion-controlled and were greater in rain water than in tap water and were greater for Zn than for Cu. After a period of 120 h, between about 0.5% and 3% of total Cu and 5-30% of total Zn had been released to the aqueous phase. These observations suggest that Cu and Zn mobilised from fine antifouling particulates during washdown or rainfall events may be important contaminants of runoff and soils in the vicinity of boat repair facilities.     

Leaching of zinc from tire wear particles under simulated estuarine conditions

Tire wear particles (TWP) abraded from end-of-life passenger car tires have been added at a concentration of 1 g L⁻¹ to river water, sea water and mixtures thereof in order to examine the chemical controls on the leaching of Zn from the rubber matrix. Results of time-dependent experiments conducted over a period of 5 days were consistent with a diffusion controlled leaching mechanism with rate constants of about 0.04 mg L⁻¹ h^−1/2 in river water and between about 0.02 and 0.03 mg L⁻¹ h^−1/2 in sea water. Additional experiments revealed a reduction in Zn dissolution with both increasing salinity and pH and enhancement of leaching in the presence of fluorescent light compared with dark conditions. In corresponding experiments conducted in the presence of a fixed quantity (0.8 g L⁻¹) of clean, fractionated estuarine sediment, aqueous Zn concentrations were reduced by at least an order of magnitude. Increasing the quantity of sediment resulted in a progressive reduction in Zn concentration until an apparent equilibrium was achieved, with partition coefficients defining the sediment-water distribution of Zn of about 550 mL g⁻¹ and 270 mL g⁻¹ in river water and sea water, respectively. Results are interpreted in terms of the dissolution of ZnO and other residual complexes from the matrix and the subsequent, rapid adsorption of Zn²⁺ ions to coexistent estuarine sediment. The findings of the study are discussed in terms of their implications for the transport, fate and effects of TWP Zn in aquatic environments that are likely to receive urban runoff.     

Strong links between metal contamination, habitat modification and estuarine larval fish distributions

Changes to larval fish assemblages may have far reaching ecological impacts. Correlations between habitat modification, contamination and marine larval fish communities have rarely been assessed in situ. We investigated links between the large-scale distribution of stressors and larval fish assemblages in estuarine environments. Larval fish communities were sampled using a benthic sled within the inner and outer zones of three heavily modified and three relatively unmodified estuaries. Larval abundances were significantly greater in modified estuaries, and there were trends towards greater diversity in these systems. Differences in larval community composition were strongly related to sediment metal levels and reduced seagrass cover. The differences observed were driven by two abundant species, Paedogobius kimurai and Ambassis jacksoniensis, which occurred in large numbers almost exclusively in highly contaminated and pristine locations respectively. These findings suggest that contamination and habitat alteration manifest in substantial differences in the composition of estuarine larval fish assemblages.     

How seasonality affects the flow of estrogens and their conjugates in one of Japan's most populous catchments

A detailed study of the free and conjugated estrogen load discharged by the eight major sewage treatment plants into the Yodo River basin, Japan was carried out. Sampling campaigns were focused on the winter and autumn seasons from 2005 to 2008 and the free estrogens estrone(E1), 17β-estradiol(E2), estriol(E3), 17α-ethynylestradiol(EE2) as well as their conjugated (sulfate and glucuronide) forms. For both sewage effluent and river water E2 and E1 concentrations were greatest during the winter period (December-March). This coincides with the period of lowest rainfall and lowest temperatures in Japan. E1 was the dominant estrogenic component in effluent (means of 10-50 ng/L) followed by E2 (means of 0.5-3 ng/L). The estrogen sulfate conjugates were found intermittently in the 0.5-1.7 ng/L concentration range in the sewage effluents. The greatest estrogen exposure was found to be in the Katsura River tributary which exceeded 1 ng/L E2-equivalents during the winter period.     

Impact of local traffic exclusion on near-road air quality: findings from the New York City "Summer Streets" campaign

We monitored curbside airborne particulate matter (PM) concentrations and its proinflammatory capacity during 3 weekends when vehicle traffic was excluded from Park. Ave., New York City. Fine PM concentration peaked in the morning regardless of traffic while ultrafine PM was 58% lower during mornings without traffic. Ultrafine PM concentration varied linearly with traffic flow, while fine PM spiked sharply in response to random traffic events that were weakly correlated with the traffic signal cycle. Ultrafine PM concentrations decayed exponentially with distance from a cross street with unrestricted traffic flow, reaching background levels within 100 m of the source. IL-6 induction was typically highest on Friday afternoons but showed no clear relationship to the presence of traffic. The coarse fraction (>2.5 μm) had the greatest intrinsic inflammatory capacity, suggesting that coarse PM still warrants attention even as the research focus is shifting to nano-particles.     

Improvements to standard methodologies for the analytical determination of metals in stationary-source emissions samples

Deficiencies with the current European reference method for the analysis using inductively couple plasma-mass spectrometry of metals in samples from stationary emissions sources are presented based on experimental data obtained from real samples. The effect of these deficiencies on the quality and accuracy of data is highlighted with biases of up to 40% being observed in real samples. Suggestions to improve the performance of the standard method are presented. In particular, the beneficial effect of using a drift correction procedure to account for the decrease in instrument sensitivity observed during an analytical measurement series is demonstrated. It is shown that this corrective procedure results in substantial improvements to the accuracy of data produced.     

How interdisciplinary is sustainability research? Analyzing the structure of an emerging scientific field

Sustainability research is expected to incorporate concepts, methods, and data from a diverse array of academic disciplines. We investigate the extent to which sustainability research lives up to this ideal of an interdisciplinary field. Using bibliometric data, we orient our study around the “tripartite model” of sustainability, which suggests that sustainability research should draw from the three “pillars” of the environmental, economic, and social sciences. We ask three questions: (i) is sustainability research truly more interdisciplinary than research generally, (ii) to what extent does research grounded in one pillar draw on research from the other two, and (iii) if certain disciplines or pillars are more interdisciplinary than others, then what explains this variation? Our results indicate that sustainability science, while more interdisciplinary than other scientific fields, falls short of the expectations inherent in the tripartite model. The pillar with the fewest articles published on sustainability—economics—is also the most integrative, while the pillar with the most articles—environmental sciences—draws the least from outside disciplines. But interdisciplinarity comes at a cost: sustainability research in economics and the social sciences is centered around a relatively small number of interdisciplinary journals, which may be becoming less valued over time. These findings suggest that, if sustainability research is to live up to its interdisciplinary ideals, researchers must be provided with greater incentives to draw from fields other than their own.